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18 条记录 (耗时 0.045 秒)

    Process for removing fluorine from olefin oligomers
    13.
    发明授权
    Process for removing fluorine from olefin oligomers 失效
    从烯烃低聚物中除去氟的方法

    公开(公告)号：US4417091A

    公开(公告)日：1983-11-22

    申请号：US373182

    申请日：1982-04-29

    申请人： Jean Gaillard

    发明人： Jean Gaillard

    IPC分类号： C07C2/08 ,  B01J31/00 ,  C07C1/00 ,  C07C7/12 ,  C07C11/02 ,  C07C67/00

    CPC分类号： C07C11/02 ,  C07C7/12

    摘要： Fluorinated impurities are removed from olefin oligomers by extraction with a solid adsorbent; the oligomers have been obtained from monoolefins having 2-4 carbon atoms, in the presence of a catalyst obtained by contacting a bivalent nickel compound with a hydrocarbyl aluminum halide and a trifluoroacetic acid.

    摘要翻译： 通过用固体吸附剂萃取从烯烃低聚物中除去氟化杂质; 在通过使二价镍化合物与烃基铝卤化物和三氟乙酸接触而获得的催化剂的存在下，低聚物由具有2-4个碳原子的单烯烃获得。

    Process for oligomerizing olefins
    15.
    发明授权
    Process for oligomerizing olefins 失效
    烯烃低聚方法

    公开(公告)号：US4387262A

    公开(公告)日：1983-06-07

    申请号：US228309

    申请日：1981-01-22

    申请人： Yves Chauvin ,  Domonique Commereuc ,  Jean Gaillard ,  Gerard Leger ,  Nhu H. Phung

    发明人： Yves Chauvin ,  Domonique Commereuc ,  Jean Gaillard ,  Gerard Leger ,  Nhu H. Phung

    IPC分类号： C08F4/00 ,  B01J31/04 ,  B01J31/14 ,  C07B61/00 ,  C07C1/00 ,  C07C2/30 ,  C07C11/02 ,  C07C67/00 ,  C08F4/60 ,  C07C2/02

    CPC分类号： C07C2/30 ,  B01J31/0231 ,  B01J31/04 ,  B01J31/143 ,  B01J2231/20 ,  C07C2531/04 ,  C07C2531/14

    摘要： A process for oligomerizing olefins uses a catalyst composition obtained by contacting (a) bivalent nickel compound with (b) a hydrocarbylaluminum compound of the formula Al R.sub.x X.sub.y where R is a monovalent hydrocarbon radical, X is halogen, x is from 1 to 1.5, y is from 1.5 to 2, x+y being equal to 3, and (c) a Bronsted acid consisting preferably of a halogenocarboxylic acid of the formula R.sub.1 COOH in which R.sub.1 is a halogenoalkyl radical of the formula C.sub.m H.sub.p X.sub.q X being halogen, m an integer from 1 to 3, p being zero or an integer and q being an integer, the condition p+q=2m+1 being fulfilled. A preferred Bronsted acid is of the formula R.sub.2 COOH in which R.sub.2 is a halogenomethyl group of the formula CX.sub.n H.sub.3-n, X being halogen and n an integer from 1 to 3.

    摘要翻译： 使烯烃低聚的方法使用通过使（a）二价镍化合物与（b）式Al RxXy的烃基铝化合物接触而获得的催化剂组合物，其中R是一价烃基，X是卤素，x是1至1.5，y 为1.5〜2，x + y为3，（c）优选由式R 1 COOH的卤代羧酸组成的布朗斯台德酸，其中R1为式CmHpXq + L的卤代烷基，X为卤素， m为1〜3的整数，p为0或整数，q为整数，满足条件p + q = 2m + 1。 优选的布朗斯台德酸是式R 2 COOH，其中R 2是式CX n H 3-n的卤代甲基，X是卤素，n是1至3的整数。

    Process for producing gasoline of high octane number, in particular lead-free gasoline
    17.
    发明授权
    Process for producing gasoline of high octane number, in particular lead-free gasoline 失效
    生产高辛烷值汽油的方法，特别是无铅汽油

    公开(公告)号：US4270929A

    公开(公告)日：1981-06-02

    申请号：US71503

    申请日：1979-08-31

    申请人： Quang Dang Vu ,  Yves Chauvin ,  Jean Gaillard ,  Bernard Torck ,  Michel Hellin

    发明人： Quang Dang Vu ,  Yves Chauvin ,  Jean Gaillard ,  Bernard Torck ,  Michel Hellin

    IPC分类号： C10G3/00 ,  C07C2/30 ,  C10L1/02

    CPC分类号： C07C2/30 ,  C10L1/023 ,  C07C2527/1206 ,  C07C2531/14 ,  Y02P30/20

    摘要： Process for producing gasoline of high octane number from C.sub.3 and C.sub.4 olefinic cuts, such as those obtained by fractional distillation of a C.sub.3 / C.sub.4 catalytic cracking cut, comprising the steps of:(a) oligomerizing propylene of the C.sub.3 cut to obtain a first gasoline fraction,(b) reacting the isobutene of the C.sub.4 cut with methanol to produce methyl tert.-butyl ether which is separated from the unreacted C.sub.4 hydrocarbons to form a second gasoline fraction,(c) alkylating said unreacted C.sub.4 hydrocarbons with isobutane in the presence of an alkylation catalyst such as hydrofluoric acid, to form a third gasoline fraction, and(d) admixing, at least partially, said first, second and third gasoline fractions, so as to obtain gasoline of high octane number.

    摘要翻译： 用于从C3和C4烯烃切割生产高辛烷值的汽油的方法，例如通过C3 / C4催化裂化馏分的分馏获得的那些，包括以下步骤：（a）将C3馏分的丙烯低聚得到第一种汽油 馏分，（b）使C4馏分的异丁烯与甲醇反应，生成与未反应的C4烃分离的甲基叔丁基醚形成第二汽油馏分，（c）在存在的情况下用异丁烷烷基化所述未反应的C4烃 的烷基化催化剂如氢氟酸，以形成第三汽油馏分，和（d）至少部分地混合所述第一，第二和第三汽油馏分，以获得高辛烷值的汽油。