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公开(公告)号：US08377624B2
公开(公告)日：2013-02-19
申请号：US12412400
申请日：2009-03-27
Applicant: Mathias Jarek , Domenico Balbinot
Inventor： Mathias Jarek , Domenico Balbinot
CPC classification number: B41C1/1025 , B41C2201/04 , B41C2201/14 , B41C2210/04 , B41C2210/06 , B41C2210/22 , B41C2210/24 , B41C2210/26 , B41C2210/264 , B41C2210/266 , B41M5/366
Abstract: Negative-working imageable elements have a hydrophilic substrate and a single thermally-sensitive imageable layer. This layer can include an infrared radiation absorbing compound and polymeric particles that coalesce upon thermal imaging. These coalesceable polymeric particles comprise a thermoplastic polymer and a colorant to provide improved visible contrast between exposed and non-exposed regions in the imaged element, such as lithographic printing plates.
Abstract translation: 负性可成像元件具有亲水基材和单一的热敏可成像层。 该层可以包括红外辐射吸收化合物和在热成像时聚结的聚合物颗粒。 这些可聚结聚合物颗粒包括热塑性聚合物和着色剂，以在成像元件（例如平版印刷版）中的曝光区域和非曝光区域之间提供改善的可见对比度。
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公开(公告)号：US20100310840A1
公开(公告)日：2010-12-09
申请号：US12477226
申请日：2009-06-03
Applicant: Domenico Balbinot , Mathias Jarek
Inventor： Domenico Balbinot , Mathias Jarek
CPC classification number: B41C1/1025 , B41C2201/04 , B41C2201/14 , B41C2210/04 , B41C2210/08 , B41C2210/24 , B41C2210/26 , B41C2210/264 , B41C2210/266 , Y10T428/24917
Abstract: Images can be provided using a method comprising thermally imaging a negative-working imageable element to provide an imaged element with exposed regions and non-exposed regions, the exposed regions consisting essentially of coalesced core-shell particles, and developing the imaged element on-press to remove only the non-exposed regions using a lithographic printing ink, fountain solution, or both. The imageable element comprises a single thermally-sensitive imageable layer consisting essentially of an infrared radiation absorbing compound and core-shell particles that coalesce upon thermal imaging. The core of the core-shell particles is composed of a hydrophobic thermoplastic polymer, the shell of the core-shell particles is composed of a hydrophilic polymer that is covalently bonded to the core hydrophobic thermoplastic polymer, and the thermally-sensitive imageable layer comprises less than 10 weight % of free polymer.
Abstract translation: 可以使用包括热成像负性可成像元件以提供具有暴露区域和非曝光区域的成像元件的方法来提供图像，所述暴露区域基本上由聚结的核 - 壳颗粒组成，并且将成像元件在印刷机上显影 以使用平版印刷油墨，润版液或两者仅去除非曝光区域。 可成像元件包括基本上由红外辐射吸收化合物和在热成像时聚结的核 - 壳颗粒组成的单一热敏可成像层。 核 - 壳颗粒的核心由疏水性热塑性聚合物组成，核 - 壳颗粒的壳由共价结合到芯疏水性热塑性聚合物上的亲水性聚合物组成，热敏可成像层包含较少 超过10重量％的游离聚合物。
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公开(公告)号：US09029063B2
公开(公告)日：2015-05-12
申请号：US13239435
申请日：2011-09-22
Applicant: Domenico Balbinot , Harald Baumann , Udo Dwars , Mathias Jarek , Christopher D. Simpson
Inventor： Domenico Balbinot , Harald Baumann , Udo Dwars , Mathias Jarek , Christopher D. Simpson
CPC classification number: G03F7/029 , B41C1/1008 , B41C2210/04 , B41C2210/06 , B41C2210/08 , B41C2210/22 , B41C2210/24 , B41C2210/266 , G03F7/031
Abstract: A lithographic printing plate precursor comprises an imagable layer comprising a free radically polymerizable component, an initiator composition capable of generating free radicals upon exposure to imaging infrared radiation, an infrared radiation absorbing dye comprising an infrared radiation absorbing cation and a counter anion, and a polymeric binder. The salt formed between the infrared radiation absorbing cation and a tetraphenyl borate has solubility in 2-methoxy propanol at 20° C. that is greater than or equal to 3.5 g/l. The use of these infrared radiation absorbing dyes in the imagable layers provides a reduced tendency of these dyes to crystallize in the presence of tetraaryl borate counter anions.
Abstract translation: 平版印刷版前体包括可成像层，其包含可自由基聚合的组分，在暴露于成像红外辐射时能够产生自由基的引发剂组合物，包含红外辐射吸收阳离子和抗衡阴离子的红外辐射吸收染料，以及聚合物 粘合剂 在红外辐射吸收阳离子和四苯基硼酸盐之间形成的盐在20℃下在2-甲氧基丙醇中具有大于或等于3.5g / l的溶解度。 在可成像层中使用这些红外辐射吸收染料提供这些染料在硼酸四芳基酯阴离子存在下结晶的趋势。
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公开(公告)号：US08329382B2
公开(公告)日：2012-12-11
申请号：US12552362
申请日：2009-09-02
Applicant: Mathias Jarek , Domenico Balbinot
Inventor： Mathias Jarek , Domenico Balbinot
CPC classification number: B41C1/1025 , B41C2201/04 , B41C2201/14 , B41C2210/04 , B41C2210/06 , B41C2210/08 , B41C2210/22 , B41C2210/24 , B41N3/08
Abstract: Imageable elements can be imaged and then processed using a solution containing core-shell particles that are designed to complex with non-coalesced particles in the non-exposed regions of imaged element. A separate development step is not needed, but the non-coalesced particles and complexed core-shell particles can be removed from the resulting printing plate before using the resulting lithographic printing plate for printing.
Abstract translation: 可成像元件可以成像，然后使用含有核 - 壳颗粒的溶液进行成像，该溶液设计成与成像元件的非曝光区域中的非聚结颗粒复合。 不需要单独的显影步骤，但是在使用所得的平版印刷版进行印刷之前，可以从得到的印刷版中除去非聚结颗粒和络合的核 - 壳颗粒。
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公开(公告)号：US20120141942A1
公开(公告)日：2012-06-07
申请号：US12959432
申请日：2010-12-03
Applicant: Domenico Balbinot , Mathias Jarek , Jianbing Huang , Ting Tao , Christopher D. Simpson
Inventor： Domenico Balbinot , Mathias Jarek , Jianbing Huang , Ting Tao , Christopher D. Simpson
IPC: G03F7/20
CPC classification number: G03F7/322 , B41C1/1008 , B41C1/1016 , B41C2201/02 , B41C2201/14 , B41C2210/04 , B41C2210/06 , B41C2210/10 , B41C2210/12 , B41C2210/22 , B41C2210/24 , B41C2210/266 , G03F7/033 , G03F7/035
Abstract: Lithographic printing plates are prepared by imaging and developing negative-working lithographic printing plate precursors that include certain particulate polymeric binders in the photosensitive imageable layer. Such particulate polymeric binders are poly(urethane-acrylic) hybrids. Development is carried out using a working strength developer that includes one or more organic solvents in a total amount of at least 7 weight % and an anionic surfactant in an amount of at least 5 weight %.
Abstract translation: 通过成像和显影在光敏可成像层中包含某些颗粒聚合物粘合剂的负性平版印刷版前体制备平版印刷版。 这种颗粒聚合物粘合剂是聚（氨基甲酸酯 - 丙烯酸）混合物。 使用包含总量至少7重量％的一种或多种有机溶剂和至少5重量％的阴离子表面活性剂的工作强度显影剂进行显影。
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Patent Agency Ranking
公开(公告)号：US20100248097A1
公开(公告)日：2010-09-30
申请号：US12412400
申请日：2009-03-27
Applicant: Mathias Jarek , Domenico Balbinot
Inventor： Mathias Jarek , Domenico Balbinot
CPC classification number: B41C1/1025 , B41C2201/04 , B41C2201/14 , B41C2210/04 , B41C2210/06 , B41C2210/22 , B41C2210/24 , B41C2210/26 , B41C2210/264 , B41C2210/266 , B41M5/366
Abstract: Negative-working imageable elements have a hydrophilic substrate and a single thermally-sensitive imageable layer. This layer can include an infrared radiation absorbing compound and polymeric particles that coalesce upon thermal imaging. These coalesceable polymeric particles comprise a thermoplastic polymer and a colorant to provide improved visible contrast between exposed and non-exposed regions in the imaged element, such as lithographic printing plates.
Abstract translation: 负性可成像元件具有亲水基材和单一的热敏可成像层。 该层可以包括红外辐射吸收化合物和在热成像时聚结的聚合物颗粒。 这些可聚结聚合物颗粒包括热塑性聚合物和着色剂，以在成像元件（例如平版印刷版）中的曝光区域和非曝光区域之间提供改善的可见对比度。
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公开(公告)号：US08632941B2
公开(公告)日：2014-01-21
申请号：US13239442
申请日：2011-09-22
Applicant: Domenico Balbinot , Harald Baumann , Udo Dwars , Mathias Jarek , James R. Matz , Christopher D. Simpson
Inventor： Domenico Balbinot , Harald Baumann , Udo Dwars , Mathias Jarek , James R. Matz , Christopher D. Simpson
CPC classification number: B41C1/10 , B41C1/1008 , B41C2210/04 , B41C2210/06 , B41C2210/22 , G03F7/004 , G03F7/027 , G03F7/029 , G03F7/031 , G03F7/033 , G03F7/3035
Abstract: A lithographic printing plate precursor comprises an imageable layer comprising a free radically polymerizable component, an initiator composition capable of generating free radicals upon exposure to imaging infrared radiation, an infrared radiation absorbing dye that is defined by Structure (I) shown in the disclosure, which dyes comprise one or more ethylenically unsaturated polymerizable groups in an organic group that is attached to the methine chain. These infrared radiation absorbing dyes exhibit a reduced tendency to crystallize in the imageable layers in the presence of tetraaryl borate counter anions and therefore provide improved shelf life.
Abstract translation: 平版印刷版前体包含可成像层，其包含可自由基聚合的组分，在暴露于成像红外辐射时能够产生自由基的引发剂组合物，由本公开中所示的结构（I）定义的红外辐射吸收染料， 染料在与次甲基链连接的有机基团中包含一个或多个烯键式不饱和可聚合基团。 这些红外辐射吸收染料在硼酸四芳基酯阴离子存在下，在可成像层中显示出降低的结晶倾向，因此提供了更好的保质期。
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公开(公告)号：US20120141941A1
公开(公告)日：2012-06-07
申请号：US12959424
申请日：2010-12-03
Applicant: Mathias Jarek , Domenico Balbinot , Harald Baumann
Inventor： Mathias Jarek , Domenico Balbinot , Harald Baumann
CPC classification number: G03F7/3071 , G03F7/322
Abstract: Imaged lithographic printing plates are processed using a developer that is replenished with only water, but replenishment is at a rate to allow developer volume to slowly decrease from a developer reservoir. This allows for a longer processing cycle especially when the developer is supplied from a container having a defined amount and applied using spray devices where water evaporation from the developer can be significant. Water lost by evaporation is replenished while water carried out by lithographic printing plates is not replenished.
Abstract translation: 使用仅补充水的显影剂对成像的平版印刷版进行处理，但补充量使得显影剂体积从显影剂储存器缓慢降低。 这特别是当显影剂从具有限定量的容器供应并且使用喷雾装置施加显影剂时，可以延长处理周期，其中来自显影剂的水蒸发可能是显着的。 补充水蒸气损失的水分，而平版印刷版的水不补充。
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公开(公告)号：US20110311916A1
公开(公告)日：2011-12-22
申请号：US12818441
申请日：2010-06-18
Applicant: Mathias Jarek , Domenico Balbinot
Inventor： Mathias Jarek , Domenico Balbinot
CPC classification number: B41C1/1016 , B41C2201/04 , B41C2201/10 , B41C2210/02 , B41C2210/08 , B41C2210/14 , B41C2210/20 , B41C2210/24 , B41C2210/262 , G03F7/0047 , G03F7/202
Abstract: A lithographic printing plate precursor can be used to prepare a printing plate using thermal ablation. The precursor has a non-thermally ablatable first layer on a substrate. Over the first layer is a thermally ablatable outer layer that includes an IR absorbing compound in an ablatable polymeric binder. The first layer includes a sol gel as a continuous inorganic matrix and a discontinuous inorganic phase (inorganic particles) dispersed therein.
Abstract translation: 可以使用平版印刷版原版来制备使用热消融的印版。 前体在基底上具有不可热烧蚀的第一层。 在第一层上是可热烧的外层，其包括可消融的聚合物粘合剂中的IR吸收化合物。 第一层包括作为连续无机基质的溶胶凝胶和分散在其中的不连续无机相（无机颗粒）。
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公开(公告)号：US07060415B2
公开(公告)日：2006-06-13
申请号：US11130797
申请日：2005-05-17
Applicant: Anthony P. Kitson , Kevin B. Ray , Joanne Ray , Mathias Jarek , Celin Savariar-Hauck
Inventor： Anthony P. Kitson , Kevin B. Ray , Joanne Ray , Mathias Jarek , Celin Savariar-Hauck
CPC classification number: B41C1/1016 , B41C2210/02 , B41C2210/06 , B41C2210/14 , B41C2210/22 , B41C2210/24 , B41C2210/262 , Y10S430/111 , Y10S430/165
Abstract: The present invention provides a positive-working, thermally imageable element generally comprising a multi-layered imageable coating. The invention provides an imageable element comprising a substrate, an ink-receptive top layer, and an underlayer, the underlayer including a specific copolymer described herein. The copolymer can be a polymer comprising constitutional units derived from: a) a monomer having a cyclic urea group; b) a monomer comprising an N-substituted maleimide; c) a (meth)acrylamide or (meth)acrylate monomer; and d) a (meth)acrylic acid or vinyl benzoic acid monomer. In another embodiment, the copolymer can be a polymer comprising constitutional units derived from: a) a monomer having a cyclic urea group; b) a (meth)acrylic acid or vinyl benzoic acid monomer; c) and a (meth)acrylonitrile monomer. The imageable element may be used to prepare a lithographic printing plate that is resistant to press chemistry and can optionally be baked to increase press runlength.
Abstract translation: 本发明提供了通常包括多层可成像涂层的正性加工的可热成像元件。 本发明提供了一种可成像元件，其包括基底，油墨接受顶层和底层，底层包括本文所述的特定共聚物。 共聚物可以是包含衍生自以下的结构单元的聚合物：a）具有环状脲基团的单体; b）包含N-取代的马来酰亚胺的单体; c）（甲基）丙烯酰胺或（甲基）丙烯酸酯单体; 和d）（甲基）丙烯酸或乙烯基苯甲酸单体。 在另一个实施方案中，共聚物可以是包含衍生自以下的结构单元的聚合物：a）具有环状脲基团的单体; b）（甲基）丙烯酸或乙烯基苯甲酸单体; c）和（甲基）丙烯腈单体。 可成像元件可以用于制备耐压制化学的平版印刷版，并且可以任选地烘烤以增加压制长度。
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