摘要:
Disclosed are stabilizer mixtures comprising at least a) one alkanolamine or one reaction product of a monofunctional or polyfunctional epoxide and ammonia or a monofunctional or polyfunctional dialkyl(aryl)amine or monoalkyl(aryl)amine, and b) one uracil or one initial product and an optional perchlorate salt.
摘要:
The invention relates to a mixture of stabilisers for the stabilisation of chlorinated polymers, comprising at least a) a sulphate ester salt and/or a sulphonate salt of formula (I): [R(O)aSO3]1M and b) an alkanolamine of formula (II), where M=alkali, earth alkali, lanthanide (Cer) or aluminium cation, t=metal cation valence of 1, 2 or 3; s=0 or 1, R=C1-C22 a phenyl, C7-C10 phenylalkyl, C7 -C24 alkylphenyl, x=1, 2 or 3: y=1, 2, 3, 4, 5 or 6; n=1-10. R1, R2 independently=H. C1-C22 alkyl, —[—(CHR3a)y—CHR3b—O—]a—H, —[—(CHR3a)y—CHR3b—O-]n-CO—R4, C2-C20 alkenyl, C2-C18 acyl, C4-C8 cycloalkyl, optionally substituted at the B-position by OH, C6-C10 aryl, C7-C10 alkaryl or C7-C10 aralkyl, or when x=1, R1 and R2 together with the N can form a closed 4-10 membered ring of carbon atoms with optionally up to 2 heteroatoms, or when x=2, R1 also=C2-C18 alkylene, optionally substituted at both B-carbon atoms with OH and/or interrupted by 1 or more O atoms and/or 1 or more NR2 groups, or dihydroxysubstituted tetrahydrodicyclopentadienylene, dihydroxysubstituted ethylcyclohexanylene, dihydroyxsubstituted 4,4′-bisphenol-A-dipropylether)ylene, isophoronylene, dimethylcyclohexanylene, dicyclohoxylmethanylene or 3,3′-dimethyldicyclohexylmethanylene and when x=3, R1 also=trihydroxysubstituted (tri-N-propylisocyanurate)triyl, R3a, R3b independently=C1-C22 alkyl, C2-C6 alkenyl) C6-C10 aryl, H or CH2—X—R5, where X═O, S, —O—CO— or —CO—O—; R4═C1-C18 alkyl/alkenyl or phenyl and R5═H, C1-C22 alkyl, C2-C22 alkenyl or C6-C10 aryl.
摘要:
Halogen-containing polymers or the recyclates thereof are stabilized by the addition of (a) a halogen-containing polymer or a recyclate thereof; (b) at least one zeolite in the form of sodium, potasssium and/or lithium, in particular at least one zeolite of formula M2O.Al2O3.x SiO2.y H2O (I), wherein M is Na, K or Li, x is 2 to 12, and y is 1 to 15, with the exception of zeolite A, Na12Al12Si12O48.27 H2O and clinoptilolite Na6Al6Si30O72.2 H2O, (c) at least one organic zinc, aluminium or rare earth compound, and/or (d) at least one organotin compound, as described in more detail in claim 1.
摘要:
A description is given of compositions comprising a chlorine-containing polymer and at least one compound of the general formula I where x is oxygen or sulfur, and R is C2-C22-acyloxyalkyl or C1-C12-alkyl which may be interrupted by 1 to 3 oxygen atoms and/or substituted by 1 to 3 OH groups, or is C3-C8-alkenyl, C7-C10-phenylalkyl, C5-C8-cycloalkyl, C7-C10-alkylphenyl, phenyl or naphthyl, where the aromatic radical in each case may be substituted by —OH, C1-C12-alkyl and/or OC1-C4-alkyl, and R1 is hydrogen or is as defined for R.
摘要:
A stabiliser combination, mainly for PVC, is described, comprising A) at least one compound of formula I wherein R*1 and R*2 are each independently of the other C1-C12alkyl, C3-C6lkenyl, C5-C8cycloalkyl that is unsubstituted or substituted by from 1 to 3 C1-C4alkyl, C1-C4alkoxy, C5-C8cycloalkyl or by hydroxy groups or by chlorine atoms, or C7-C9phenylalkyl that is unsubstituted or substituted at the phenyl ring by from 1 to 3 C1-C4alkyl, C1-C4alkoxy, C5-C8cycloalkyl or by hydroxy groups or chlorine atoms, and R*1 and R*2 may additionally be hydrogen and C1-C12alkyl, and Y is S or O, and B) at least one compound from the following groups: B1) perchlorate compounds, B2) glycidyl compounds, B3) beta-diketones and beta-keto esters, B4) dihydropyridines and polydihydropyridines, B5) polyols and disaccharide alcohols, B6) sterically hindered amines (tetraalkylpiperidine compounds), B7) alkali aluminosilicates (zeolites), B8) hydrotalcites, B9) alkali aluminocarbonates (dawsonites), B10) alkali- (or alkaline earth-) carboxylates,-(bi)carbonates or -hydroxides, B11) antioxidants and lubricants and B12) organotin stabilisers.
摘要:
The invention relates to a PVC composition comprising a stabilizer combination of (b) polyDHP of the formula I ##STR1## where the radicals T, L, R, R', R" are as defined in claim 1, (c) a subtance from the group consisting of crystalline hydrotalcites,crystalline or amorphous zeolites,crystalline or amorphous dawsonites, magadiites or kenyaites, disaccharide alcohols and sterically hindered amines containing the structural unit ##STR2## in which R.sup.0 is hydrogen or methyl, and (d) at least one zinc, aluminium or lanthanoid compound.
摘要:
Complexes composed of alkylphosphines or of alkylphosphonium chlorides and tin tetrachloride are good catalysts for the preparation of dimethyl-tin dichloride from tin and methyl chloride in the presence of sulphones and carbonates as solvents.
摘要:
The present invention relates to flame retardant compositions comprising (a) at least one triazine-intercalated metal phosphate with open framework structure with at least one monomer unit of the following general formula (I): (A-H)a(+)[Mbm+(H2PO4)x1(−)(HPO4)x22(−)(PO4)x33(−)(PO3)y(−)](a−)*pH2O (I) and (b) at least one flame retardant component other than (a). The invention further relates to the use thereof, the specific compounds of the general formula (I) and to the preparation thereof.
摘要:
The present invention relates to phosphorus-containing triazine compounds of the formula (I) and (III) and to the polymers obtainable from the water-eliminating polycondensation of a compound of the formula (II), and to the use thereof as flame retardants. [(A-H)+]m[Mm+(HPO42−)m] (III-1), [(A-H)+]m[Mm+(P2O74−)m/2] (III-2).
摘要翻译:本发明涉及式(I)和(III)的含磷三嗪化合物和由式(II)化合物的除水缩聚得到的聚合物及其作为阻燃剂的用途。 [(A-H)+] m [Mm +(HPO42-)m](III-1),[(A-H)+] m [Mm +(P2O74-)m / 2](III-2)。