Abstract:
An object of the present invention is to provide a method for producing a reflective layer having an excellent diffuse reflectivity and a wide reflection wavelength range. Another object of the present invention is to provide a reflective layer having an excellent diffuse reflectivity and a wide reflection wavelength range. The method for producing a reflective layer of the present invention includes: a step 1 of applying a composition selected from the group consisting of the following composition X and the following composition Y onto a substrate to form a composition layer; a step 2 of heating the composition layer to align a liquid crystal compound in the composition layer into a cholesteric liquid crystalline phase state; a step 3 of cooling or heating the composition layer in a cholesteric liquid crystalline phase state to reduce a helical pitch; and a step 4 of irradiating at least a partial region of the composition layer with light, between the step 1 and the step 2, between the step 2 and the step 3, or after the step 3, to photosensitize a chiral agent A or a chiral agent C in the composition layer. Composition X: a composition including a liquid crystal compound, a chiral agent A whose helical twisting power is changed upon light irradiation, and a chiral agent B whose helical twisting power is increased upon cooling or heating. Composition Y: a composition including a liquid crystal compound and a chiral agent C whose helical twisting power is changed upon light irradiation and whose helical twisting power is increased upon cooling or heating.
Abstract:
Provided are a curable composition including an amide compound that is represented by Formula (1) below and of which a density of sulfonic acid is 3.9 milliequivalent/g or greater. m represents an integer of 1 or greater, n represents an integer of 2 or greater, L1 represents a m+1-valent linking group, and L2 represents an n-valent linking group. R1 represents a hydrogen atom or an alkyl group, and R2 represents —SO3−M+ or —SO3R3 (R3 represents an alkyl group or an aryl group). Here, in a case where there are plural R2's, not all of the R2's are —SO3R3. M+ represents a hydrogen ion, an inorganic ion, or an organic ion.
Abstract:
A gas separation composite membrane, containing a gas permeable supporting layer, and a gas separating layer containing a crosslinked polyimide resin above the gas permeable supporting layer, in which the crosslinked polyimide resin has a structure in which 2 to 4 molecules of a polyimide compound is coordinated with a divalent to tetravalent central metal via an oxygen atom or a sulfur atom, and when the crosslinked polyimide resin has plural central metals, the plural central metals are linked via the polyimide chain of the polyimide compound; and a gas separating module, a gas separation apparatus and a gas separation method utilizing this gas separation composite membrane.
Abstract:
A gas separation composite membrane, containing a gas-permeable supporting layer and a gas separating layer containing a crosslinked organic-inorganic hybrid resin over the gas-permeable supporting layer, in which the crosslinked organic-inorganic hybrid resin has a structure in which a polymer incorporating therein an oxanthrene unit, or a polyimide compound has been crosslinked via a specific crosslinking chain.
Abstract:
An object of the present invention is to provide a method for producing a cholesteric liquid crystal layer, which is capable of freely controlling a tilt angle of an arrangement direction of bright portion and dark portion derived from a cholesteric liquid crystalline phase with respect to a normal line of a main surface of the cholesteric liquid crystal layer; a cholesteric liquid crystal layer; an optically anisotropic body; and a reflective film. The method for producing a cholesteric liquid crystal layer according to the present invention includes a step X of forming a cholesteric liquid crystal layer A in which a liquid crystal compound is aligned into a state of a cholesteric liquid crystalline phase, satisfying all of the conditions 1 to 3, and a step Y of carrying out a treatment to increase or decrease a helical pitch of the cholesteric liquid crystalline phase in the cholesteric liquid crystal layer A obtained by the step X to increase or decrease a tilt angle of an arrangement direction of bright portion and dark portion derived from the cholesteric liquid crystalline phase, as observed in a cross-section perpendicular to a main surface of the cholesteric liquid crystal layer A, with respect to a normal direction of the main surface of the cholesteric liquid crystal layer A.
Abstract:
Provided is an optically anisotropic layer formed of a liquid crystal compound, which includes first and second layers in direct contact along a thickness direction, an alignment state of the liquid crystal compound in the first layer is different from the second layer, and the optically anisotropic layer satisfies a relationship of Expression (2A) Xmax/Xmin
Abstract:
The present invention provides a compound having an excellent amount of change in HTP and an excellent HTP saturation rate during exposure, and a liquid crystal composition including the compound. The compound of the present invention is a compound represented by General Formula (A).
(Y)n-G-(X)m (A)
G represents a group represented by General Formula (B-1) or a group represented by General Formula (B-2), * represents a bonding position, and X and Y represent a predetermined group.
Abstract:
A compound having an excellent rate of change in HTP caused by exposure is achieved and is represented by General Formula (1). In addition, a composition is formed of the compound, and a cured product, an optically anisotropic body, or a reflective film is obtained by curing the composition.
Abstract:
An optically anisotropic film is formed of a liquid crystal composition including a liquid crystal compound and has a liquid crystal alignment pattern in which a direction of an optical axis derived from the liquid crystal compound changes while continuously rotating in at least one in-plane direction of the optically anisotropic film, and the optically anisotropic film satisfies predetermined requirements.
Abstract:
Provided is a liquid crystal composition capable of forming an optically anisotropic layer, and method thereof, in which a variation in a twisted angle of liquid crystal compound in an in-plane direction is suppressed an optical film, and a circularly polarizing plate for an organic EL display. The liquid crystal composition contains a liquid crystal, optically active compound A which is a photosensitive optically active compound whose helical twisting power changes upon irradiation with light and has a molar absorption coefficient of 5,000 M−1·cm−1 or more with respect to light having a wavelength of 365 nm, and an optically active compound B having a molar absorption coefficient with respect to light having a wavelength of 365 nm smaller than the molar absorption coefficient of the optically active compound A, in which a mass content ratio of the optically active compound A to the liquid crystal compound is less than 0.01.