公开(公告)号：US08551904B2

公开(公告)日：2013-10-08

申请号：US13049412

申请日：2011-03-16

Applicant: Felice DiMascio

Inventor： Felice DiMascio

IPC: B01J27/224 ,  B01J23/00 ,  C03C3/068

CPC classification number: B01J37/0009 ,  B01J35/08 ,  B01J37/0072 ,  B01J38/02 ,  C04B35/565 ,  C04B35/6303

Abstract: A process for making a ceramic catalyst material includes mixing a catalyst precursor material with a mineral particulate to form a mixture; adding a binder, silicon carbide, and a parting agent to the mixture to form unfired spheroids; and heating the unfired spheroids at a temperature effective to oxidize the silicon carbide and the catalyst precursor material to form the ceramic catalyst material. In another embodiment, the process includes the addition of a catalyst metal oxide salt to an aluminosilicate hydrogel aggregate mixture. Once the mixture sets, the set mixture is heated to a temperature to effective to produce a high surface area ceramic catalyst material.

Abstract translation: 制备陶瓷催化剂材料的方法包括将催化剂前体材料与矿物颗粒混合以形成混合物; 向混合物中加入粘合剂，碳化硅和脱模剂以形成未烧结的球体; 并在有效氧化碳化硅和催化剂前体材料的温度下加热未烧结的球体以形成陶瓷催化剂材料。 在另一个实施方案中，该方法包括向铝硅酸盐水凝胶骨料混合物中加入催化剂金属氧化物盐。 一旦混合物组合，将固化混合物加热到有效的温度以产生高表面积的陶瓷催化剂材料。

公开(公告)号：US20130206605A1

公开(公告)日：2013-08-15

申请号：US13838074

申请日：2013-03-15

Applicant: Felice DiMascio ,  Dennis R. Hardy ,  Heather D. Willauer ,  M. Kathleen Lewis ,  Frederick Williams

Inventor： Felice DiMascio ,  Dennis R. Hardy ,  Heather D. Willauer ,  M. Kathleen Lewis ,  Frederick Williams

IPC: C25B1/04

CPC classification number: C25B9/10 ,  C01B31/20 ,  C01B32/50 ,  C10G2/50 ,  C10G2300/42 ,  C10G2400/08 ,  C25B1/04 ,  C25B1/10 ,  C25B9/08 ,  C25B15/02 ,  C25B15/08 ,  Y02E60/366 ,  Y02W10/37

Abstract: Apparatus for seawater acidification including an ion exchange, cathode and anode electrode compartments and cation-permeable membranes that separate the electrode compartments from the ion exchange compartment. Means is provided for feeding seawater through the ion exchange compartment and for feeding a dissociable liquid media through the anode and cathode electrode compartments. A cathode is located in the cathode electrode compartment and an anode is located in the anode electrode compartment and a means for application of current to the cathode and anode is provided. A method for the acidification of seawater by subjecting the seawater to an ion exchange reaction to exchange H+ ions for Na+ ions. Carbon dioxide may be extracted from the acidified seawater. Optionally, the ion exchange reaction can be conducted under conditions which produce hydrogen as well as carbon dioxide. The carbon dioxide and hydrogen may be used to produce hydrocarbons.

Abstract translation: 用于海水酸化的装置，包括离子交换器，阴极和阳极电极隔室以及将电极隔室与离子交换隔室分离的阳离子可透过膜。 提供用于通过离子交换室供给海水并且用于通过阳极和阴极隔室供给可离解的液体介质的装置。 阴极位于阴极电极室中，并且阳极位于阳极电极室中，并且提供用于向阴极和阳极施加电流的装置。 通过使海水进行离子交换反应以交换Na +离子的H +离子来使海水酸化的方法。 可以从酸化的海水中提取二氧化碳。 任选地，离子交换反应可以在产生氢气以及二氧化碳的条件下进行。 二氧化碳和氢气可用于生产碳氢化合物。

公开(公告)号：US07179363B2

公开(公告)日：2007-02-20

申请号：US10604712

申请日：2003-08-12

Applicant: Felice DiMascio ,  Mike Hunter

Inventor： Felice DiMascio ,  Mike Hunter

IPC: C25B1/26

CPC classification number: C25B1/26

Abstract: An electrolytic process for generating chlorine dioxide. An aqueous feed stream of an alkali metal chlorite solution is treated with chlorine gas or a mixture of hydrogen chloride and hypochlorous acid formed in an anode compartment from, an aqueous alkali metal chloride solution and subsequently electrolyzed to form a chlorine dioxide effluent.

Abstract translation: 用于产生二氧化氯的电解方法。 碱金属亚氯酸盐溶液的含水进料流用氯气或在阳极室中形成的氯化氢和次氯酸的混合物从碱金属氯化物水溶液中处理，随后电解形成二氧化氯流出物。

公开(公告)号：US20060110311A1

公开(公告)日：2006-05-25

申请号：US11265032

申请日：2005-11-02

Applicant: Felice DiMascio

Inventor： Felice DiMascio

IPC: B01J23/40 ,  B01J31/00 ,  C01B11/02

CPC classification number: C01B11/024 ,  B01J31/08 ,  B01J35/0006 ,  B01J35/0013 ,  B01J35/023 ,  B01J37/0009 ,  B01J2231/32 ,  B01J2231/42 ,  B01J2231/52 ,  B01J2231/62 ,  C01B11/00

Abstract: A catalyst composite includes an agglomerate of a plurality of catalyst composite components and a binder. The catalyst composites may be useful as a catalyst in a variety of chemical processes including hydrogenation, dehydrogenation, hydrogenolysis, oxidation, reduction, alkylation, dealkylation, carbonylation, decarbonylation, coupling, isomerization, amination, deamination, or hydrodehalogenation.

Abstract translation: 催化剂复合物包括多个催化剂复合组分和粘合剂的附聚物。 催化剂复合物可用作各种化学方法中的催化剂，包括氢化，脱氢，氢解，氧化，还原，烷基化，脱烷基化，羰基化，脱羰基，偶联，异构化，胺化，脱氨基或加氢脱卤。

公开(公告)号：US20050079121A1

公开(公告)日：2005-04-14

申请号：US10683056

申请日：2003-10-10

Applicant: Felice DiMascio

Inventor： Felice DiMascio

IPC: C01B11/02 ,  C25B1/22 ,  C25C7/00 ,  C25D17/00

CPC classification number: C25B1/22 ,  C01B11/024

Abstract: Processes for generating chlorine dioxide generally include acidifying an alkali metal chlorite solution; and contacting the acidified alkali metal chlorite solution with a solid phase chlorine containing material to produce chlorine dioxide. An exemplary system for generating chlorine dioxide generally includes a water source in fluid communication with a conduit that is fluidly connected to a vessel, wherein the vessel comprises a housing, an inlet in fluid communication with the housing and the conduit, an outlet, and a solid phase chlorine containing material disposed within the housing; an acid source downstream from the water source in fluid communication with the conduit; and a chlorite ion source in fluid communication with the conduit downstream from the acid source. Various means are provided for the acid source.

Abstract translation: 产生二氧化氯的方法通常包括酸化碱金属亚氯酸盐溶液; 并将酸化的碱金属亚氯酸盐溶液与含固相氯的物质接触以产生二氧化氯。 用于产生二氧化氯的示例性系统通常包括与流体连接到容器的导管流体连通的水源，其中容器包括壳体，与壳体和导管流体连通的入口，出口和 设置在壳体内的固相含氯材料; 水源下游的酸源与导管流体连通; 以及与酸源下游的导管流体连通的亚氯酸盐离子源。 为酸源提供了各种方法。

公开(公告)号：US06514398B2

公开(公告)日：2003-02-04

申请号：US09875313

申请日：2001-06-05

Applicant: Felice DiMascio ,  Anil Jha ,  Gary C. Ganzi ,  Frederick Wilkins

Inventor： Felice DiMascio ,  Anil Jha ,  Gary C. Ganzi ,  Frederick Wilkins

IPC: C02F1469

CPC classification number: C02F1/4695 ,  B01D61/48 ,  B01J47/04 ,  B01J47/08 ,  C02F1/42 ,  C02F1/4693

Abstract: Electrodeionization apparatus and method. The electrodeionization apparatus includes an ion-depleting compartment in which alternating layers of an electroactive media are positioned. One of the alternating layers is doped to provide a more balanced current distribution through the apparatus. The method involves providing reducing the difference in conductivity between the alternating layers positioned in the ion-depleting compartment by adding a dopant material to one of the layers.

公开(公告)号：US06284124B1

公开(公告)日：2001-09-04

申请号：US09240420

申请日：1999-01-29

Applicant: Felice DiMascio ,  Anil Jha ,  Gary C. Ganzi ,  Frederick Wilkins

Inventor： Felice DiMascio ,  Anil Jha ,  Gary C. Ganzi ,  Frederick Wilkins

IPC: C02F1461

CPC classification number: C02F1/4695 ,  B01D61/48 ,  B01J47/04 ,  B01J47/08 ,  C02F1/42 ,  C02F1/4693

Abstract: Electrodeionization apparatus and method. The electrodeionization apparatus includes an ion-depleting compartment in which alternating layers of an electroactive media are positioned. One of the alternating layers is doped to provide a more balanced current distribution through the apparatus. The method involves reducing the difference in conductivity between the alternating layers positioned in the ion-depleting compartment by adding a dopant material to one of the layers.

Abstract translation: 电离电离装置及方法。 电去离子装置包括其中定位有电活性介质的交替层的离子消耗室。 交替层之一被掺杂以提供通过该装置的更平衡的电流分布。 该方法涉及通过向其中一层添加掺杂剂材料来减少位于离子消耗隔间中的交替层之间的导电性差异。

公开(公告)号：US09303323B2

公开(公告)日：2016-04-05

申请号：US13838074

申请日：2013-03-15

Applicant: Felice DiMascio ,  Dennis R Hardy ,  M. Kathleen Lewis ,  Heather D. Willauer ,  Frederick Williams

Inventor： Felice DiMascio ,  Dennis R Hardy ,  M. Kathleen Lewis ,  Heather D. Willauer ,  Frederick Williams

IPC: C25B1/10 ,  C10G2/00 ,  C25B1/04 ,  C25B9/08

CPC classification number: C25B9/10 ,  C01B31/20 ,  C01B32/50 ,  C10G2/50 ,  C10G2300/42 ,  C10G2400/08 ,  C25B1/04 ,  C25B1/10 ,  C25B9/08 ,  C25B15/02 ,  C25B15/08 ,  Y02E60/366 ,  Y02W10/37

Abstract: Apparatus for seawater acidification including an ion exchange, cathode and anode electrode compartments and cation-permeable membranes that separate the electrode compartments from the ion exchange compartment. Means is provided for feeding seawater through the ion exchange compartment and for feeding a dissociable liquid media through the anode and cathode electrode compartments. A cathode is located in the cathode electrode compartment and an anode is located in the anode electrode compartment and a means for application of current to the cathode and anode is provided. A method for the acidification of seawater by subjecting the seawater to an ion exchange reaction to exchange H+ ions for Na+ ions. Carbon dioxide may be extracted from the acidified seawater. Optionally, the ion exchange reaction can be conducted under conditions which produce hydrogen as well as carbon dioxide. The carbon dioxide and hydrogen may be used to produce hydrocarbons.

Abstract translation: 用于海水酸化的装置，包括离子交换器，阴极和阳极电极隔室以及将电极隔室与离子交换隔室分离的阳离子可透过膜。 提供用于通过离子交换室供给海水并且用于通过阳极和阴极隔室供给可离解的液体介质的装置。 阴极位于阴极电极室中，并且阳极位于阳极电极室中，并且提供用于向阴极和阳极施加电流的装置。 通过使海水进行离子交换反应以交换Na +离子的H +离子来使海水酸化的方法。 可以从酸化的海水中提取二氧化碳。 任选地，离子交换反应可以在产生氢气以及二氧化碳的条件下进行。 二氧化碳和氢气可用于生产碳氢化合物。

公开(公告)号：US20130039837A1

公开(公告)日：2013-02-14

申请号：US13571383

申请日：2012-08-10

Applicant: Heather D. Willauer ,  John Barile ,  Felice DiMascio ,  Dennis R. Hardy ,  Frederick Williams

Inventor： Heather D. Willauer ,  John Barile ,  Felice DiMascio ,  Dennis R. Hardy ,  Frederick Williams

IPC: C01B31/20

CPC classification number: C02F1/20 ,  B01D19/0031 ,  B01D61/00 ,  B01D63/02 ,  B01D2311/13 ,  B01D2311/18 ,  C01B32/50 ,  C02F1/44 ,  C02F1/66 ,  C02F2103/08 ,  C02F2209/06 ,  C02F2301/063 ,  Y02C10/10

Abstract: A method for recovering carbon dioxide from acidified seawater using a membrane contactor and passing seawater with a pH less than or equal to 6 over the outside of a hollow fiber membrane tube while applying vacuum or a hydrogen sweep gas to the inside of the hollow fiber membrane tube, wherein up to 92% of the re-equilibrated [CO2]T is removed from the natural seawater.

Abstract translation: 一种使用膜接触器从酸化海水中回收二氧化碳的方法，并且在中空纤维膜管的外侧通过pH小于或等于6的海水，同时向中空纤维膜的内部施加真空或氢气吹扫气体 管，其中至多92％的再平衡的[CO 2] T从天然海水中除去。

公开(公告)号：US20120305494A1

公开(公告)日：2012-12-06

申请号：US13153656

申请日：2011-06-06

Applicant: Felice DiMascio

Inventor： Felice DiMascio

IPC: C25B1/26 ,  C02F1/76

CPC classification number: C02F1/4695 ,  C02F1/4678 ,  C25B1/26 ,  Y02W10/37

Abstract: The invention is directed to an apparatus and methods of its use to generate chlorine dioxide. The apparatus comprises three cation exchange resin chambers in fluidic communication to convert chlorite salt into chlorine dioxide. Unlike previous converters, the invention utilizes an novel method of acidifying some of the chlorite to produce a more effective process. The invention can achieve a 100% theoretical yield which is s significant improvement over the 80% theoretical yield in previous attempts using non-acidifying chemistry. The method also avoids the need for expensive catalysts.

Abstract translation: 本发明涉及一种用于产生二氧化氯的装置及其方法。 该装置包括流体连通的三个阳离子交换树脂室，以将亚氯酸盐转化为二氧化氯。 不同于以前的转换器，本发明利用一种酸化一些亚氯酸盐以产生更有效的方法的新方法。 本发明可以实现100％的理论产率，这在以前使用非酸化化学的尝试中比80％的理论产量显着改善。 该方法也避免了昂贵的催化剂的需要。