Abstract:
A method of forming a phosphor composition is disclosed. The method includes mixing co-precipitated yttrium-europium oxalate with an inorganic flux material to form an oxalate-flux mixture; and heating the oxalate-flux mixture at a temperature in a range from about 800° C. to about 1400° C., to form the phosphor composition. The phosphor has a general formula of (Y1-x-yAyEux)2O3 with 0
Abstract:
A lighting apparatus that includes a light source and a phosphor composition radiationally coupled to the light source is presented. The phosphor composition includes a first phosphor that includes a phase of general formula (I): L3ZO4(Br2-nXn):Eu2+ wherein 0≦n≦1; L is Zn, Mg, Ca, Sr, Ba, or combinations thereof; Z is Si, Ge, or a combination thereof; and X is F, Cl, I, or combinations thereof.
Abstract:
A method includes mixing a first fluoride phosphor powder that is doped with tetravalent manganese with a treatment solution for a designated period of time, stopping the mixing to allow the fluoride phosphor powder to settle, removing at least some liquid that has separated from the first fluoride phosphor powder, repeating (a) the mixing, (b) the stopping of the mixing, and (c) removing at least some of the liquid during one or more additional cycles, and obtaining a second fluoride phosphor powder following the repeating of the mixing, the stopping of the mixing, and the removing of at least some of the liquid. The second fluoride phosphor powder includes a reduced amount of the manganese relative to the first fluoride phosphor powder.
Abstract:
Coating systems suitable for use in generating fluorescent visible light, and lamps provided with such coating systems. The coating systems includes a phosphor-containing coating that contains at least a first phosphor that is predominantly excited by ultraviolet radiation of a first wavelength to emit visible light and absorbs but is less efficiently excited by ultraviolet radiation of a second wavelength. The coating system further includes a second phosphor that absorbs the ultraviolet radiation of the second wavelength and little if any of the ultraviolet radiation of the first wavelength.
Abstract:
Coating systems suitable for use in fluorescent lamps, particularly as scattering agents within a UV-reflecting coating for the purpose of improving fluorescent lamp luminosity. Such a coating system is provided on a transparent or translucent substrate and includes a phosphor coating and a scattering agent that scatters UV rays. The scattering agent includes an inorganic powder present in a separate UV-reflecting layer adjacent the phosphor coating and/or dispersed in the phosphor coating so that the scattered UV rays are absorbed by the phosphor coating and cause the phosphor coating to emit visible light. The inorganic powder exhibits low or no absorption to UV rays having wavelengths of 185 nm and 254 nm and is not reactive with mercury.
Abstract:
A process for preparing a Mn+4 doped phosphor of formula I Ax[MFy]:Mn+4 I includes gradually adding a first solution to a second solution and periodically discharging the product liquor from the reactor while volume of the product liquor in the reactor remains constant; wherein A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; y is 5, 6 or 7. The first solution includes a source of M and HF and the second solution includes a source of Mn to a reactor in the presence of a source of A.
Abstract:
Described are methods and apparatus for providing fluorescent lamps having a two-layer phosphor coating that includes a base coating and a top coating that economically provides a high color rendering index (CRI) of at least 87 with improved brightness. In an embodiment, a low-pressure discharge lamp includes a light transmissive envelope having a basecoat phosphor layer disposed on an inner surface, wherein the basecoat phosphor layer includes less than ten percent weight of a rare earth phosphor. Also included is a topcoat phosphor layer on a surface of the base coat phosphor layer that includes a blend of at least red, green, green-blue and blue emitting rare earth phosphors, and a fill gas composition within the light transmissive envelope.
Abstract:
A fluorescent lamp includes a phosphor composition comprising: Y2O3:Eu3+ (YEO); at least one of LaPO4:Ce3+, Tb3+ (LAP), MgAl11O19:Ce3+, Tb3+ (CAT) or GdMgB5O10:Ce3+, Tb3+ (CBT); a special BAMn phosphor, (Ba,Sr,Ca)(Mg1-xMnx)Al10O17:Eu2+, with a specific amount of Mn (x) as disclosed herein, and optionally halophosphor, with the proviso that there is no BaMgAl10O17:Eu2+ (BAM).
Abstract translation:荧光灯包括荧光体组合物,其包含:Y 2 O 3:Eu 3+(YEO); LaPO4:Ce3 +,Tb3 +(LAP),MgAl11O19:Ce3 +,Tb3 +(CAT)或GdMgB5O10:Ce3 +,Tb3 +(CBT)中的至少一种; 具有本文公开的特定量的Mn(x)的特定BAMn荧光体(Ba,Sr,Ca)(Mg1-xMnx)Al10O17:Eu2 +,以及任选的卤代荧光体,条件是不存在BaMgAl 10 O 17:Eu 2+(BAM )。
Abstract:
A process for preparing a Mn+4 doped phosphor of formula I Ax[MFy|:Mn+4 I includes gradually adding a first solution to a second solution and periodically discharging the product liquor from the reactor while volume of the product liquor in the reactor remains constant; wherein A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; and y is 5, 6 or 7. The first solution includes a source of M and HF and the second solution includes a source of Mn to a reactor in the presence of a source of A.
Abstract:
Blue and green-emitting Eu2+-activated oxyhalide phosphors of formula A-E may be used in devices for lighting or display applications: A. M3SiO3X4:Eu2+; B. M5Si3O9X4:Eu2+; C. M1.64Si0.82O3.1X0.36:Eu2+; D. M10Si3O9X14:Eu2+; E. M2SiO3X2:Eu2+; and wherein M is Ba, Ca, Sr, or a mixture thereof; X is Cl or Br, or a mixture thereof.