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    Process for the production of polyurethanes using cyclic N-hydroxyalkyl-substituted compounds containing amidine groups as catalysts
    11.
    发明授权
    Process for the production of polyurethanes using cyclic N-hydroxyalkyl-substituted compounds containing amidine groups as catalysts 失效
    使用含有脒基作为催化剂的环状N-羟基烷基取代的化合物生产聚氨酯的方法

    公开(公告)号：US4368278A

    公开(公告)日：1983-01-11

    申请号：US251011

    申请日：1981-04-03

    申请人： Werner Rasshofer ,  Gerhard Grogler ,  Kurt Findeisen

    发明人： Werner Rasshofer ,  Gerhard Grogler ,  Kurt Findeisen

    IPC分类号： C08G18/00 ,  C08G18/18 ,  C08G18/20 ,  C08G18/14

    CPC分类号： C08G18/2009

    摘要： A polyurethane is made by reacting a polyisocyanate with a compound having at least two isocyanate-reactive hydrogen atoms and having a molecular weight of from 400 to 10,000 in the presence of a catalyst. The catalyst employed is a cyclic N-hydroxyalkyl-substituted compound containing an amidine group. Polyurethanes made in accordance with this process are useful as shoe soles, upholstery material, sound insulating materials, coating compositions, packaging materials and mattresses.

    摘要翻译： 通过使多异氰酸酯与具有至少两个异氰酸酯反应性氢原子且在催化剂存在下的分子量为400至10,000的化合物反应制备聚氨酯。 所使用的催化剂是含有脒基的环状N-羟烷基取代的化合物。 根据该方法制备的聚氨酯可用作鞋底，装饰材料，隔音材料，涂料组合物，包装材料和床垫。

    Hydrolysis process for polyamines
    12.
    发明授权
    Hydrolysis process for polyamines 失效
    多胺的水解过程

    公开(公告)号：US5283364A

    公开(公告)日：1994-02-01

    申请号：US4808

    申请日：1993-01-15

    申请人： Werner Rasshofer ,  Klaus Konig ,  Hans-Joachim Meiners ,  Gerhard Grogler

    发明人： Werner Rasshofer ,  Klaus Konig ,  Hans-Joachim Meiners ,  Gerhard Grogler

    IPC分类号： C08G18/10 ,  C08G18/46 ,  C08G18/50 ,  C07C85/00

    CPC分类号： C08G18/5048 ,  C08G18/10 ,  C08G18/4623

    摘要： Polyamines containing primary amino groups are made by hydrolyzing an isocyanate with water in the presence of a solvent which is a carboxylic acid amide. The solvent must be used in a quantity of at least 10% by weight solvent based on 100% by weight of isocyanate. The weight ratio of solvent to water must be from 3 to 200. A homogeneous phase is maintained during the hydrolysis which is carried out at temperatures of from 20.degree. to 210.degree. C. A not incorporable basic and/or metal catalyst particularly alkali metal hydroxides may be employed. The polyamines produced by this process are particularly useful for the production of polyurethanes.

    摘要翻译： 含羧基酰胺的溶剂存在下，通过用水水解异氰酸酯制备含有伯氨基的多胺。 溶剂必须使用至少10重量％的溶剂，基于100重量％的异氰酸酯。 溶剂与水的重量比必须为3至200.在水解期间保持均相，其在20至210℃的温度下进行。不合并的碱性和/或金属催化剂，特别是碱金属氢氧化物 可以被雇用。 通过该方法生产的多胺特别可用于生产聚氨酯。

    Process for the preparation of polyamines from N-monoaryl-N',N'-dialkyl urea compounds and their use for the synthesis of polyurethanes
    13.
    发明授权
    Process for the preparation of polyamines from N-monoaryl-N',N'-dialkyl urea compounds and their use for the synthesis of polyurethanes 失效
    由N-单芳基-N'，N'-二烷基脲化合物制备多胺的方法及其在聚氨酯合成中的应用

    公开(公告)号：US4472568A

    公开(公告)日：1984-09-18

    申请号：US437398

    申请日：1982-10-28

    申请人： Werner Rasshofer ,  Gerhard Grogler

    发明人： Werner Rasshofer ,  Gerhard Grogler

    IPC分类号： C08G18/00 ,  C07C67/00 ,  C07C239/00 ,  C07C273/18 ,  C07C275/28 ,  C08G18/10 ,  C08G18/38 ,  C08G18/50 ,  C08G18/83 ,  C07C127/15 ,  C07C127/24

    CPC分类号： C08G18/83 ,  C07C273/1854 ,  C08G18/10 ,  C08G18/3819 ,  C08G18/5036

    摘要： This invention relates to an improved process for the preparation of aromatic polyamines containing urethane and/or biuret and/or urea and/or isocyanurate groups and preferably also ether groups by the hydrolysis of poly-N-monoaryl-N',N'-dialkyl urea compounds (1-aryl-3,3-dialkyl ureas). The ureas are obtained by the reaction of secondary aliphatic, cycloaliphatic or saturated heterocyclic amines with divalent to tetravalent isocyanate compounds containing isocyanate end groups attached to aromatic residues. The ureas correspond to the general formula: ##STR1## wherein R.sup.1, R.sup.2 denote alkyl or cycloalkyl groups, or together form a ring andA denotes a divalent to tetravalent residue attached to the ureas by aromatic groups.Hydrolysis is carried out in the presence of water and up to two equivalents of a base containing hydroxide ions and/or up to two equivalents of a compound containing tertiary amino groups, optionally in the presence of solvents. The use of the polyamines obtained by this process for the synthesis of polyurethanes is also described.

    摘要翻译： 本发明涉及一种改进的制备含氨基甲酸酯和/或缩二脲和/或脲和/或异氰脲酸酯基团的芳族多胺的方法，优选通过水解聚-N-单芳基-N'，N'-二烷基 脲化合物（1-芳基-3,3-二烷基脲）。 脲通过仲脂族，脂环族或饱和杂环胺与含有连接到芳族残基的异氰酸酯端基的二价至四价异氰酸酯化合物的反应获得。 脲对应于以下通式：其中R 1，R 2表示烷基或环烷基，或一起形成环，A表示通过芳族基团连接到脲上的二价至四价残基。 任选在溶剂存在下，在水的存在下和至多两当量的含氢氧根离子的碱和/或至多两当量的含有叔氨基的化合物进行水解。 还描述了通过该方法获得的用于合成聚氨酯的多胺的用途。

    Process for the preparation of polymer precursors containing oxazolin-2-one rings
    16.
    发明授权
    Process for the preparation of polymer precursors containing oxazolin-2-one rings 失效
    制备含恶唑啉-2-酮环的聚合物前体的方法

    公开(公告)号：US4350781A

    公开(公告)日：1982-09-21

    申请号：US286419

    申请日：1981-07-24

    申请人： Werner Rasshofer ,  Gerhard Grogler ,  Holger Meyborg

    发明人： Werner Rasshofer ,  Gerhard Grogler ,  Holger Meyborg

    IPC分类号： C07D263/62 ,  C08G18/10 ,  C08G18/38 ,  C08G18/80 ,  C08G18/32

    CPC分类号： C07D263/62 ,  C08G18/10 ,  C08G18/3844 ,  C08G18/80

    摘要： A polymer precursor containing an oxazolin-2-one ring is made by reacting (a) an amino-reactive group containing compound having at least two groups capable of entering into an addition or condensation reaction with primary or secondary aromatically-bound amino groups with (b) an aromatic amine having at least one primary or secondary aromatically-bound amino group and at least one condensed oxazolin-2-one ring. The reactants are used in quantities such that for each aromatically bound primary or secondary amino group there are from 0.95 to 5 groups present in the amino-reactive group containing compound which are capable of reacting with the amino group. These polymer precursors may be used to produce high molecular weight polymers useful in the production of solid molded products, adhesives, foam plastics and coatings.

    摘要翻译： 含有恶唑啉-2-酮环的聚合物前体是通过使（a）具有至少两个能够与伯或仲芳族结合的氨基进行加成或缩合反应的基团的含氨基反应性基团的化合物与（ b）具有至少一个伯或仲芳族结合的氨基和至少一个稠合的恶唑啉-2-酮的芳族胺。 反应物的用量使得对于每个芳香结合的伯或仲氨基，在含有氨基反应性基团的化合物中存在0.95至5个能够与氨基反应的基团。 这些聚合物前体可用于生产用于生产固体模制产品，粘合剂，泡沫塑料和涂料的高分子量聚合物。

    Process for the preparation of polyamines and their use for the preparation of polyurethanes
    17.
    发明授权
    Process for the preparation of polyamines and their use for the preparation of polyurethanes 失效
    制备多胺的方法及其用于制备聚氨酯的用途

    公开(公告)号：US4843107A

    公开(公告)日：1989-06-27

    申请号：US173204

    申请日：1988-03-24

    申请人： Andreas Ruckes ,  Werner Rasshofer ,  Klaus Konig ,  Richard Kopp

    发明人： Andreas Ruckes ,  Werner Rasshofer ,  Klaus Konig ,  Richard Kopp

    IPC分类号： C08G18/64 ,  C08G18/10 ,  C08G18/50 ,  C08G73/02

    CPC分类号： C08G18/5048 ,  C08G18/10

    摘要： Polyamines containing primary amino groups are made by a one-shot process for the hydrolysis of prepolymers containing isocyanate end groups and having an isocyanate content of from 0.5 to 40 weight % with 0.75 to 40 mol of water per equivalent of isocyanate groups in the presence of very small quantities of sodium hydroxide in certain organic, polar solvents. The compounds containing isocyanate groups used for this process are isocyanate prepolymers (preferably containing urethane groups). Hydrolysis according to this process leads directly to the polyamines with elimination of carbon dioxide. These polyamines may be isolated by the usual methods and the removal of the small quantities of catalyst may advantageously be omitted. These polyamines are useful for the preparation of polyurethane(urea)s.

    摘要翻译： 含有伯氨基的多胺通过一步法制备，用于水解包含异氰酸酯端基并且异氰酸酯含量为0.5至40重量％的预聚物，每当异氰酸酯基为0.75至40摩尔水时， 某些有机极性溶剂中极少量的氢氧化钠。 用于该方法的含有异氰酸酯基团的化合物是异氰酸酯预聚物（优选含有氨基甲酸酯基团）。 根据该方法的水解直接导致多胺消除二氧化碳。 这些多胺可以通过常规方法分离，并且可以有利地省略少量催化剂的去除。 这些多胺可用于制备聚氨酯（尿素）。

    Process for the production of polyamines
    19.
    发明授权
    Process for the production of polyamines 失效
    多胺生产工艺

    公开(公告)号：US4843108A

    公开(公告)日：1989-06-27

    申请号：US173350

    申请日：1988-03-24

    申请人： Andreas Ruckes ,  Werner Rasshofer ,  Klaus Konig ,  Richard Kopp

    发明人： Andreas Ruckes ,  Werner Rasshofer ,  Klaus Konig ,  Richard Kopp

    IPC分类号： C08G18/08 ,  C08G18/00 ,  C08G18/10 ,  C08G18/30 ,  C08G18/32 ,  C08G18/40 ,  C08G18/50 ,  C08G18/64

    CPC分类号： C08G18/5048 ,  C08G18/10

    摘要： Polyamines are produced by hydrolyzing isocyanate compounds having an NCO content of from 0.5 to 40 wt. % with from 0.75 to 40 moles of water per equivalent of NCO groups in the presence of from 0.021 to 0.099 wt. % sodium hydroxide and at least 10 wt. % water-miscible polar organic solvent containing nitrile, ketone, sulfoxide or ether groups having a boiling point of from 56.degree. to 250.degree. C. The reaction mixture is maintained in a homogeneous phase. The reaction is carried out at 40.degree. to 170.degree. C. These polyamines are useful in the production of polyurethane(urea)s.

    摘要翻译： 多胺通过水解NCO含量为0.5〜40重量％的异氰酸酯化合物来制造。 在0.021至0.099重量％的存在下，每当量NCO基团具有0.75至40摩尔水。 ％氢氧化钠和至少10wt。 含有沸点为56〜250℃的腈，酮，亚砜或醚基的％水混溶性极性有机溶剂。将反应混合物保持在均匀相中。 反应在40℃至170℃下进行。这些多胺可用于生产聚氨酯（尿素）。

    Polyurethane-based reactive mass and its use for the production of coatings
    20.
    发明授权
    Polyurethane-based reactive mass and its use for the production of coatings 失效
    聚氨酯类反应物质及其在涂料生产中的应用

    公开(公告)号：US4732957A

    公开(公告)日：1988-03-22

    申请号：US839940

    申请日：1986-03-17

    申请人： Peter Schuster ,  Rudolf Punessen ,  Karl Nutzel ,  Richard Kopp ,  Werner Rasshofer

    发明人： Peter Schuster ,  Rudolf Punessen ,  Karl Nutzel ,  Richard Kopp ,  Werner Rasshofer

    IPC分类号： C08G18/00 ,  C08G18/72 ,  C08G18/78 ,  C08G18/79 ,  C08G18/80 ,  C09D175/00 ,  C09D175/04 ,  C08G18/48

    CPC分类号： C08G18/798 ,  C08G18/7831 ,  C08G18/7887 ,  C08G18/792 ,  C08G18/8032

    摘要： A polyurethane-based reactive mass composed of(a) at least one organic compound in the molecular weight range of from 400 to 12000 containing isocyanate reactive groups and having a functionality from 2 to 8,(b) optionally an organic compound in the molecular weight range of from 62 to 399 containing isocyanate reactive groups and having a functionality from 2 to 8.(c) catalysts,(d) aliphatic isocyanate compounds and(e) optionally other auxiliary agents and additives known per se,characterized in that the aliphatic isocyanate compound used is one based on hexamethylene diisocyanate, hydrogenated diphenylmethane diisocyanate or isophorone diisocyanate containing isocyanurate and/or uretdione units and/or urethane and/or uretoneimine and/or oxadiazatrione groups is suitable for the production of lightfast coatings, including coatings in light colors, in particular for the formation of edgings round wooden panels without these panels having first to be dried down to the maximum dampness of 7% by weight.

    摘要翻译： 由（a）至少一种含有异氰酸酯反应性基团并且官能度为2至8的有机化合物，其分子量范围为400至12000，（b）任选的分子量有机化合物 （c）催化剂，（d）脂族异氰酸酯化合物和（e）任选的其它助剂和本身已知的添加剂，其特征在于脂族异氰酸酯 所使用的化合物是基于六亚甲基二异氰酸酯的化合物，含有异氰脲酸酯和/或脲二酮单元和/或氨基甲酸酯和/或脲酮亚胺和/或恶二唑二酮基团的氢化二苯基甲烷二异氰酸酯或异佛尔酮二异氰酸酯或异佛尔酮二异氰酸酯适用于生产包含浅色涂料的耐光涂层， 特别是用于形成圆形木板的边缘，而这些面板首先被干燥到最大潮湿 重量为7％。