摘要:
New fluoroelastomers are described, having iodine atoms in terminal position and monomeric units in the chain deriving from an iodinated olefin of formula:CHR.dbd.CH--Z--CH.sub.2 CHR--I (I)wherein: R is --H or --CH.sub.3 ; Z is a (per)fluoroalkylene radical C.sub.1 -C.sub.18, linear or branched, optionally containing one or more ether oxygen atoms, or a (per)fluoropolyoxyalkylene radical.These products, upon peroxide curing, require extremely short post-curing treatments (around 30-60 minutes at 180.degree.-230.degree. C.) and are characterized by compression set values lower than 25% (measured on O-rings at 200.degree. C. for 70 hours according to ASTM Standard D395 Method B).
摘要:
Fluorinated thermoplastic elastomers comprising monomeric units deriving from a bis-olefin having general formula: ##STR1## wherein: R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, equal or different from each other, are H or alkyls C.sub.1 -C.sub.5 ; Z is an alkylene or cycloalkylene radical C.sub.1 -C.sub.18, linear or branched, optionally containing oxygen atoms, preferably at least partially fluorinated, or a (per)fluoropolyoxyalkylene radical.
摘要:
Fluorinated thermoplastic elastomers comprising monomeric units deriving from at least an iodinated olefin of formula:CX.sub.2 .dbd.CX--R.sub.f --CHR--I (I)wherein:X is --H, --F, or --CH.sub.3 ; R is --H or --CH.sub.3 ; R.sub.f is a (per) fluoroalkylene radical, linear or branched, optionally containing one or more ether oxygen atoms, or a (per) fluoropolyoxyalkylene radical.
摘要:
Fluoroelastomeric copolymers, vulcanizable by ionic methods, suitable for the manufacture of "shaft seals" and "fuel hoses", comprising by weight:______________________________________ VDF 30-47% HFP 20-40% PAVE 3-20% TFE 10-30% ______________________________________
摘要:
Covulcanizable compositions comprising (A) 55-100% by weight of an elastomeric copolymer of vinylidene fluoride with perfluoropropene optionally tetrafluoroethylene and containing from 0.001 to 2% by weight of bromine; (B) 0-45% by weight of a tetrafluoroethylene and propylene copolymer; (C) 0.7-2.5 parts for 100 parts of mix (A)+(B) of a bisphenol compound; (D) 0.3-1.5 parts for 100 parts of mix (A)+(B) of an organic guaternary compound of ammonium, phosphonium or aminophosphonium; (E) 0.4-5 parts for 100 parts of mix (A)+(B) of an organic peroxide; (F) 1-5% by weight of (A)+(B) of a peroxide cross-linking coagent.
摘要:
VDF polymerization process, optionally modified with small amounts of one or more fluoro-containing comonomers, carried out in the presence of a microemulsion comprising a (per) fluoropolyether having neutral end groups, having number average molecular weight between 400 and 3000, and a surfactant based on perfluoropolyethers with salified acid end groups, said surfactant having a number molecular weight Mn comprised between 400–600 and having a distribution of molecular weights such that fractions having a number average molecular weight higher than 700 are not present, or are in amount less than 5% by weight.
摘要:
Object of the present invention is a process for preparing vinylidenefluoride (VDF) polymers which comprises polymerizing VDF, optionally in association with other fluorinated oiefins in an aqueous medium in the presence of a radical initiator and of 1,1,1-trifluoro-2,2-dichloroethane (HCFC-123) as chain transfer agent.A final product with very good colour characteristics (appearance), substantially devoid of discoloration effects at high temperatures, is so obtained.
摘要:
The invention relates to new fluoroelastomeric copolymers endowed with resistance to bases and suitable in particular for preparing O-rings, comprising:______________________________________ (I) VDF 47-80 mols % HFP and/or PAVE 16-30 mols % hydrogenated olefin containing 2-25 mols % 2-4 C or (II) VDF 42-80 mols % PAVE 16-30 mols % hydrogenated olefin containing 2-30 mols % 2-4 C ______________________________________ The invention relates to new fluoroplastomeric copolymers endowed with resistance to bases, comprising:______________________________________ (III) VDF 70-99 mols % HFP and/or PAVE 0-16 mols % hydrogenated olefin containing 1-30 mols % 2-4 C ______________________________________ A further object of the invention is a process for preparing the abovesaid fluoroelastomeric and fluoroplastomeric copolymers.
摘要:
The invention relates to new fluoroelastomers endowed with a low Tg and a low compression set at low temperature, characterized by the following monomeric composition:______________________________________ vinylidene fluoride: 60.5-64% by weight hexafluoropropene: 30-33% by weight tetrafluoroethylene: 5-8% by weight. ______________________________________
摘要:
Copolymers formed by TFE and FMVE containing FMVE in percent by moles from 2.5% to 8%; the % TFE moles being the complement to 100% of the FMVE moles.