Combating fungi with substituted 1-azolyl-butan-2-ones and -2-ols
    14.
    发明授权
    Combating fungi with substituted 1-azolyl-butan-2-ones and -2-ols 失效
    用真菌与取代的1-噻唑基 - 丁-2-酮和-2-ols进行灭菌

    公开(公告)号:US4549900A

    公开(公告)日:1985-10-29

    申请号:US481615

    申请日:1983-04-04

    摘要: Substituted 1-azolyl-but-2-ones and -2-ols of the formula ##STR1## in which B is --CO-- or --CH(OH)--Az represents a 1,2,4-triazol-1-yl or -4-yl or imidazol-1-yl radical,R.sup.1 represents a hydrogen atom, an alkyl, alkenyl, alkinyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, optionally substituted phenoxyalkyl or optionally substituted aralkyl radical,n is 0 or 1,R.sup.2 represents a cyano radical or a grouping of the general formula --X--R.sup.3 or --CO--NR.sup.4 R.sup.5, or, if n does not represent O at the same time as R.sup.1 represents a hydrogen atom and Az represents a 1,2,4-triazolyl radical,R.sup.2 also additionally represents an optionally substituted aryl or alkoxycarbonyl radical,and whereinX represents an oxygen or sulphur atom or an SO or SO.sub.2 group,R.sup.3 represents an alkyl, halogenoalkyl, optionally substituted aryl or optionally substituted aralkyl radical,R.sup.4 represents a hydrogen atom or an alkyl or optionally substituted aryl radical, andR.sup.5 represents a hydrogen atom or an alkyl radical, or acid addition salts or metal salt complexes thereof which possess fungicidal activity and plant growth regulatory and which can be reduced to the corresponding alcohols which are also fungicidally active.

    摘要翻译: 其中B为-CO-或-CH(OH)的取代的1-噻唑基 - 但-2-酮和2-取代的式“IMAGE”为Az代表1,2,4-三唑-1-基或 R 1表示氢原子,烷基,烯基,炔基,任选取代的环烷基,任选取代的环烷基烷基,任选取代的苯氧基烷基或任选取代的芳烷基,n为0或1,R 2表示 氰基或通式-X-R3或-CO-NR4R5的基团,或者如果在R1表示氢原子的同时不表示O,并且Az表示1,2,4-三唑基 R2还另外表示任选取代的芳基或烷氧基羰基,并且其中X表示氧或硫原子或SO或SO 2基团,R 3表示烷基,卤代烷基,任选取代的芳基或任选取代的芳烷基,R 4表示氢原子 或烷基或任选取代的芳基,R 5表示氢原子或 烷基或其酸加成盐或金属盐络合物,其具有杀真菌活性和植物生长调节,并且可以还原成也是杀真菌活性的相应的醇。

    Halogenated triazolylvinyl keto and carbinol compounds and plant growth
regulant and fungicidal compositions
    15.
    发明授权
    Halogenated triazolylvinyl keto and carbinol compounds and plant growth regulant and fungicidal compositions 失效
    卤代三唑基乙烯基酮和甲醇化合物和植物生长调节剂和杀真菌组合物

    公开(公告)号:US4729783A

    公开(公告)日:1988-03-08

    申请号:US715574

    申请日:1985-03-22

    摘要: Halogenated triazolylvinyl keto derivatives and carbinol derivatives of the general formula ##STR1## in which A represents a keto group or a CH(OH) grouping,X represents a hydrogen or halogen atom,Y represents a halogen atom,R represents a halogen atom, an alkyl, halogenoalkyl, halogenoalkoxy, alkoxy, alkylthio, halogenoalkylthio, alkylamino, dialkylamino, nitro, cyano, hydroxyl or alkylcarbonyloxy radical, an optionally substituted phenyl radical, an optionally substituted phenoxy radical or an optionally substituted benzyloxy radical andn is 0, 1, 2 or 3,and physiologically acceptable acid addition salts and metal salt complexes thereof are outstandingly effective as plant growth regulators and as fungicides. The inventive compounds can be prepared by reacting a triazolylketone with an aldehyde.

    摘要翻译: 卤代三唑基乙烯基酮衍生物和通式为其中A表示酮基或CH(OH)基的通式为(I)的甲醇衍生物,X表示氢或卤素原子,Y表示卤素原子,R表示卤素 烷氧基,烷硫基,卤代烷硫基,烷基氨基,二烷基氨基,硝基,氰基,羟基或烷基羰基氧基,任意取代的苯基,任意取代的苯氧基或任意取代的苄氧基,n为0, 1,2或3,其生理上可接受的酸加成盐和金属盐络合物作为植物生长调节剂和杀真菌剂是非常有效的。 本发明化合物可以通过使三唑基酮与醛反应来制备。

    Novel substituted azolylvinyl ketones and carbinols as fungicides and
plant growth regulators
    16.
    发明授权
    Novel substituted azolylvinyl ketones and carbinols as fungicides and plant growth regulators 失效
    新型取代的唑基乙烯基酮和甲醇作为杀真菌剂和植物生长调节剂

    公开(公告)号:US4728356A

    公开(公告)日:1988-03-01

    申请号:US754788

    申请日:1985-07-12

    摘要: A substituted azolylvinyl ketone or carbinol of the formula ##STR1## in which R.sup.1 represents optionally substituted cycloalkyl with 3 to 5 carbon atoms, substituted cyclohexyl or the grouping ##STR2## wherein R.sup.3 represents optionally substituted phenyl, alkenyl, alkinyl, cyano or the grouping --Z--R.sup.4,whereinR.sup.4 represents alkyl, halogenoalkyl, optionally substituted phenyl or optionally substituted phenylalkyl andZ represents O, S, SO or SO.sub.2,n represents a number from 0 to 2,R.sup.2 represents alkyl, alkenyl, alkinyl, in each case optionally substituted phenyl or phenylalkyl, or in each case optionally substituted cycloalkyl, cycloalkylalkyl, cycloalkenyl, cycloalkenylalkyl, bicycloalkyl or bicycloalkenyl, but R.sup.2 does not represent optionally substituted phenyl at the same time as R.sup.1 represents optionally substituted cycloalkyl with 3 to 5 carbon atoms or substituted cyclohexyl or R.sup.3 represents optionally substituted phenyl,X represents the CO or CH(OH) group andY represents a nitrogen atom or the CH group,or an addition product thereof with an acid or metal salt.The products are active in combating fungi and in regulating the growth of plants.

    摘要翻译: 其中R 1表示任选取代的具有3至5个碳原子的环烷基,取代的环己基或基团,其中R 3表示任选取代的苯基,烯基,炔基,氰基或基团 - Z-R4,其中R4代表烷基,卤代烷基,任选取代的苯基或任选取代的苯基烷基,Z代表O,S,SO或SO 2,n代表0至2的数,R 2代表烷基,烯基,炔基, 取代的苯基或苯基烷基,或者在每种情况下都是任选取代的环烷基,环烷基烷基,环烯基,环烯基烷基,双环烷基或双环烯基,但R 2不同时代表任选取代的苯基,其中R 1表示任选取代的具有3至5个碳原子的环烷基或取代的环己基 或R 3表示任选取代的苯基,X表示CO或CH(OH)基团,Y表示氮气 m或CH基团,或其与酸或金属盐的加成产物。 该产品在防治真菌和调节植物生长方面发挥积极作用。

    Oxirane compounds
    20.
    发明授权
    Oxirane compounds 失效
    环氧乙烷化合物

    公开(公告)号:US4532341A

    公开(公告)日:1985-07-30

    申请号:US499679

    申请日:1983-06-06

    摘要: Oxirane compounds of the formula ##STR1## in which R represents tert-butyl, iso-propyl radical, cyclopropyl, substituted cyclopropyl, cyclopentyl or substituted cyclopentyl, cyclohexyl or substituted cyclohexyl, in each case the substituent being selected from methyl, or phenyl which is optionally mono or di-substituted by identical or different substituents selected from fluorine, chlorine, methyl and trifluoromethyl,Y represents a grouping --OCH.sub.2 --, each Z is individually selected from the group consisting of a fluorine, chlorine or bromine atom, methyl, tert-butyl, cyclohexyl, methoxy, methylthio, trifluoromethyl, trifluoromethoxy, trifluoromethylthio, phenyl, phenoxy, benzyl and benzyloxy, said phenyl, phenoxy, benzyl and benzyloxy being optionally mono or di-substituted by identical or different substituents selected from fluorine, chlorine and methyl,m is 0, 1, 2 or 3; these compounds are particularly useful as intermediates for compounds used in agricultural compositions as plant growth regulants.

    摘要翻译: 式(II)的环氧乙烷化合物,其中R代表叔丁基,异丙基,环丙基,取代的环丙基,环戊基或取代的环戊基,环己基或取代的环己基,在各种情况下,取代基选自甲基或 苯基,其任选被选自氟,氯,甲基和三氟甲基的相同或不同的取代基单取代或二取代,Y表示分组-OCH 2 - ,各Z独立地选自氟,氯或溴原子, 甲基,叔丁基,环己基,甲氧基,甲硫基,三氟甲基,三氟甲氧基,三氟甲硫基,苯基,苯氧基,苄基和苄氧基,所述苯基,苯氧基,苄基和苄氧基任选被相同或不同的选自氟, 氯和甲基,m为0,1,2或3; 这些化合物特别可用作农业组合物中用作植物生长调节剂的化合物的中间体。