摘要:
A substituted azolylvinyl ketone or carbinol of the formula ##STR1## in which R.sup.1 represents optionally substituted cycloalkyl with 3 to 5 carbon atoms, substituted cyclohexyl or the grouping ##STR2## wherein R.sup.3 represents optionally substituted phenyl, alkenyl, alkinyl, cyano or the grouping --Z--R.sup.4,whereinR.sup.4 represents alkyl, halogenoalkyl, optionally substituted phenyl or optionally substituted phenylalkyl andZ represents O, S, SO or SO.sub.2,n represents a number from 0 to 2,R.sup.2 represents alkyl, alkenyl, alkinyl, in each case optionally substituted phenyl or phenylalkyl, or in each case optionally substituted cycloalkyl, cycloalkylalkyl, cycloalkenyl, cycloalkenylalkyl, bicycloalkyl or bicycloalkenyl, but R.sup.2 does not represent optionally substituted phenyl at the same time as R.sup.1 represents optionally substituted cycloalkyl with 3 to 5 carbon atoms or substituted cyclohexyl or R.sup.3 represents optionally substituted phenyl,X represents the CO or CH(OH) group andY represents a nitrogen atom or the CH group,or an addition product thereof with an acid or metal salt.The products are active in combating fungi and in regulating the growth of plants.
摘要:
A substituted azolylvinyl ketone or carbinol of the formula ##STR1## in which R.sup.1 represents optionally substituted cycloalkyl with 3 to 5 carbon atoms, substituted cyclohexyl or the grouping ##STR2## wherein R.sup.3 represents optionally substituted phenyl, alkenyl, alkinyl, cyano or the grouping --Z--R.sup.4,whereinR.sup.4 represents alkyl, halogenoalkyl, optionally substituted phenyl or optionally substituted phenylalkyl andZ represents O, S, SO or SO.sub.2,n represents a number from 0 to 2,R.sup.2 represents alkyl, alkenyl, alkinyl, in each case optionally substituted phenyl or phenylalkyl, or in each case optionally substituted cycloalkyl, cycloalkylalkyl, cycloalkenyl, cycloalkenylalkyl, bicycloalkyl or bicycloalkenyl, but R.sup.2 does not represent optionally substituted phenyl at the same time as R.sup.1 represents optionally substituted cycloalkyl with 3 to 5 carbon atoms or substituted cyclohexyl or R.sup.3 represents optionally substituted phenyl,X represents the CO or CH(OH) group andY represents a nitrogen atom or the CH group,or an addition product thereof with an acid or metal salt. The products are active in combating fungi and in regulating the growth of plants.
摘要:
Substituted azolylcyclopropyl-azolylmethyl-carbinol derivatives of the formula ##STR1## in which Ar is optionally substituted aryl or optionally substituted heteroaryl,R is hydrogen, alkyl, alkenyl, alkinyl, trialkylsilyl, optionally substituted phenylalkyl or an acyl radical, andX and Y each independently is a nitrogen atom or a CH group,and addition products thereof with acids and metal salts are effective in regulating plant growth and combating fungi. New intermediates are described, some of which are themselves active.
摘要:
Substituted azoyl-ketones and -alcohols of the formula ##STR1## in which A is a nitrogen atom or the CH group,B is CO or CH(OH),R.sup.1 is alkyl, alkenyl, alkinyl, optionally substituted phenylalkyl, optionally substituted cycloalkyl or optionally substituted cycloalkylalkyl,R.sup.2 is optionally substituted cycloalkyl or the grouping --C(CH.sub.3).sub.2 R.sup.3, andR.sup.3 is alkyl having more than 2 carbon atoms, alkenyl, alkinyl or the --CH.dbd.O group or a derivative thereof,or addition products thereof with acids or metal salts, exhibit plant growth regulating and fungicidal properties, several intermediates therefor are new.
摘要:
1-Azolyl-2-oximinobutane derivatives of the formula ##STR1## in which A is nitrogen or CH,R.sup.1 is hydrogen, alkyl, halogenoalkyl, alkenyl, alkinyl, or optionally substituted benzyl, phenyl, cycloalkyl, cycloalkylalkyl or cycloalkenyl, andR.sup.2 is optionally substituted phenyl, phenoxy, phenylthio, phenylsulphinyl or phenylsulphonyl,or physiologically acceptable addition products thereof with acids or metal salts, which possess fungicidal and plant growth-regulating activities.
摘要:
A substituted azolyl-phenoxy derivative of the formula ##STR1## in which A is a nitrogen atom or a CH group,B is a keto group or a CH(OH) grouping,R.sup.1 is an alkyl or halogenoalkyl group of an optionally substituted aryl group,R.sup.2 is a hydrogen atom, an alkyl group or an optionally substituted phenyl group,R.sup.3 is a hydrogen atom, an alkyl, alkenyl or alkinyl group,m is 1 or 2,X is a halogen atom, or an alkyl, alkoxy, alkylthio, halogenoalkyl, halogenoalkoxy or halogenoalkylthio group, andn is 0, 1 or 2,or an addition product thereof with an acid or metal salt, which possesses fungicidal activity particularly for combating cereal diseases as well as rust and scab diseases.
摘要:
Fungicidal 1,4-disubstituted 1-azolyl-3,3-dimethylbutane derivatives of the formula ##STR1## in which R.sup.1 represents hydrogen or halogen,R.sup.2 represents hydrogen or halogen,R.sup.3 represents hydrogen, halogen or trifluoromethoxy,R.sup.4 represents halogen, trifluoromethoxy, trifluoromethylthio, trifluoromethylsulphinyl, trifluoromethylsulphonyl, difluoromethoxy, difluorochloromethoxy, trifluorochloroethoxy, tetrafluoroethoxy, trifluoroethoxy, difluoromethylthio, trifluorochloroethylthio, tetrafuoroethylthio, difluoromethylsulphinyl, difluorochloromethylsulphinyl, trifluorochloroethylsulphinyl, tetrafluoroethylsulphinyl, difluoromethylsulphonyl, difluorochloromethylsulphonyl, trifluorochloroethylsulphonyl, tetrafluoroethylsulphonyl, difluorobromomethylthio, difluorobromomethylsulphinyl, difluorobromomethylsulphonyl or difluorochloromethylthio orR.sup.3 and R.sup.4 together represent alkylenedioxy substituted by halogen,R.sup.5 represents hydrogen or halogen,A represents a keto group or a CH(OH) grouping,Z represents a nitrogen atom or the CH group andR.sup.6 and R.sup.7 identical or different and independently of one another represent hydrogen, alkyl, alkenyl, alkynyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl or optionally substituted phenylalkyl, whereR.sup.3 represents trifluoromethoxy whenR.sup.4 represents halogen,and addition products thereof with acids and metal salts.
摘要:
Azolyl-tetrahydrofuran-2-ylidene-methanes of the formula ##STR1## in which A represents a nitrogen atom or the CH group,R represents alkyl, alkenyl, alkynyl, alkoxyalkyl, alkylthioalkyl, halogenoalkyl, halogenoalkoxyalkyl, halogenoalkylthioalkyl, halogenoalkenyl, optionally substituted aralkyl, optionally substituted aryloxyalkyl, optionally substituted arylthioalkyl, optionally substituted cycloalkyl or optionally substituted cycloalkylalkyl,R.sup.1 to R.sup.6 are identical or different and represent hydrogen, alkyl, halogenoalkyl or halogen, up to at most 3 of the substituents representing halogen or halogenoalkyl, orR.sup.1 and R.sup.2, together with the carbon atom to which they are bonded, represent optionally substituted cycloalkyl, orR.sup.2 and R.sup.3, together with the carbon atoms to which they are bonded, represent optionally substituted cycloalkyl,or addition products thereof with acids or metal salts. Some new intermediates are also shown.
摘要:
Azolyl-tetrahydrofuran-2-ylidene-methanes of the formula ##STR1## in which A represents a nitrogen atom or the CH group;X represents oxygen, sulphur or the SO or SO.sub.2 group;R represents optionally substituted aryl;R.sup.1 and R.sup.6 are identical or different and represent hydrogen, alkyl, halogenoalkyl or halogen, a maximum of up to 3 substituents representing halogen or halogenoalkyl, with the proviso that R.sup.1 and R.sup.2 are not at the same time methyl if X represents oxygen;R.sup.1 and R.sup.2, together with the carbon atom to which they are bonded, represent optionally substituted cycloalkyl orR.sup.2 and R.sup.3, together with the carbon atoms to which they are bonded, represent optionally substituted cycloalkyl,or addition products thereof with acids or metal salts. Some new intermediates are also shown. The end products are fungicides.
摘要:
A fungicidal composition comprising a fungicidally effective amount of a 1,3-diazolyl-2-propanol of the formula ##STR1## in which Alk.sup.1 is alkyl, andAlk.sup.2 is alkyl, orAlk.sup.1 and Alk.sup.2 together complete a cycloaliphatic ring,X is a nitrogen atom or the CH group,Y is a nitrogen atom or the CH group, andR is optionally substituted phenyl, phenylalkyl, phenoxy, phenylthio, phenoxyalkyl, phenylthioalkyl, benzyloxy or benzylthio,or a physiologically acceptable product thereof with an acid or metal salt in admixture with a diluent.