公开(公告)号：US4069172A

公开(公告)日：1978-01-17

申请号：US667075

申请日：1976-03-15

申请人： Masazumi Kanaoka ,  Daisuke Ogawa ,  Kazuyoshi Iwayama ,  Makoto Kihara

发明人： Masazumi Kanaoka ,  Daisuke Ogawa ,  Kazuyoshi Iwayama ,  Makoto Kihara

IPC分类号： B01J20/18 ,  C07C1/00 ,  C07C7/13 ,  C07C15/08 ,  C07C67/00 ,  B01J29/06

CPC分类号： C07C7/13 ,  B01J20/186 ,  Y02P20/52

摘要： An adsorbent for separating para-isomers from C.sub.8 or C.sub.10 aromatic hydrocarbons, specifically, a faujasite zeolite wherein about 2.5 to 25 percent, based on the total exchangeable cation sites originally present within the faujasite zeolite, is decationized and metal ions at the residual cation sites are exchanged substantially with potassium and/or barium ions. The adsorbent is used in separating the para-isomer, which is isolated by desorbing from the adsorbent.

摘要翻译： 分离对数异构体与C8或C10芳族烃，特别是八面沸石的吸附剂，其中基于最初存在于八面沸石内的总可交换阳离子位点的约2.5至25％被除去，残余阳离子位置处的金属离子 基本上与钾离子和/或钡离子交换。 吸附剂用于分离对位异构体，其通过从吸附剂解吸而分离。

公开(公告)号：US07199070B2

公开(公告)日：2007-04-03

申请号：US10885314

申请日：2004-07-07

申请人： Kazuyoshi Iwayama ,  Hiroshi Konta ,  Masatoshi Watanabe

发明人： Kazuyoshi Iwayama ,  Hiroshi Konta ,  Masatoshi Watanabe

IPC分类号： B01J29/06 ,  B01J29/068

CPC分类号： C07C4/18 ,  B01J29/40 ,  B01J29/44 ,  B01J29/46 ,  B01J29/48 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/20 ,  B01J2229/42 ,  C07C5/2737 ,  C07C2521/04 ,  C07C2523/02 ,  C07C2523/36 ,  C07C2523/42 ,  C07C2523/50 ,  C07C2523/68 ,  C07C2523/755 ,  Y02P20/52 ,  C07C15/04 ,  C07C15/08

摘要： A catalyst in which X-ray diffraction intensity ratio of the crystal lattice plane spacing d-value of 0.196±0.002 nm to the crystal lattice plane spacing d-value of 0.386±0.008 nm is in a range from 7:100 to 35:100 and a process for making the catalyst to contact with ethylbenzene containing xylenes in the presence of hydrogen.

摘要翻译： 晶体平面间距d值为0.196±0.002nm，晶格间距d值为0.386±0.008nm的X射线衍射强度比为7：100〜35：100的催化剂 以及使催化剂在含氢存在下与含乙苯接触的方法。

公开(公告)号：US4511547A

公开(公告)日：1985-04-16

申请号：US564357

申请日：1983-12-22

申请人： Kazuyoshi Iwayama ,  Takao Kamano ,  Kuniyuki Tada ,  Takehisa Inoue

发明人： Kazuyoshi Iwayama ,  Takao Kamano ,  Kuniyuki Tada ,  Takehisa Inoue

IPC分类号： C07C5/27 ,  B01J29/00 ,  C01B39/02 ,  C01B39/04 ,  C01B39/36 ,  C01B39/40 ,  C07C1/00 ,  C07C15/067 ,  C07C15/08 ,  C07C67/00 ,  C01B33/28

CPC分类号： C01B39/02 ,  C01B33/2861 ,  Y10S423/34

摘要： A crystalline aluminosilicate zeolite is obtained by stirring under heating an aqueous reaction mixture containing a silica source, an alumina source, an alkali source and an organic carboxylic acid not containing an aromatic ring preferably having 3 to 6 carbon atoms and 1 to 3 carboxyl groups.

摘要翻译： 通过在加热下搅拌含有二氧化硅源，氧化铝源，碱源和不含优选具有3至6个碳原子和1至3个羧基的芳环的有机羧酸的水性反应混合物来获得结晶硅铝酸盐沸石。

公开(公告)号：US20050010074A1

公开(公告)日：2005-01-13

申请号：US10885314

申请日：2004-07-07

申请人： Kazuyoshi Iwayama ,  Hiroshi Konta ,  Masatoshi Watanabe

发明人： Kazuyoshi Iwayama ,  Hiroshi Konta ,  Masatoshi Watanabe

IPC分类号： B01J29/06 ,  B01J29/04 ,  B01J29/40 ,  B01J29/44 ,  B01J29/46 ,  B01J29/48 ,  B01J35/00 ,  B01J37/00 ,  B01J37/20 ,  C07C4/18 ,  C07C5/27

CPC分类号： C07C4/18 ,  B01J29/40 ,  B01J29/44 ,  B01J29/46 ,  B01J29/48 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/20 ,  B01J2229/42 ,  C07C5/2737 ,  C07C2521/04 ,  C07C2523/02 ,  C07C2523/36 ,  C07C2523/42 ,  C07C2523/50 ,  C07C2523/68 ,  C07C2523/755 ,  Y02P20/52 ,  C07C15/04 ,  C07C15/08

摘要： A catalyst in which X-ray diffraction intensity ratio of the crystal lattice plane spacing d-value of 0.1196±0.002 mm to the crystal lattice plane spacing d-value of 0.386±0.008 nm is in a range from 100:7 to 100:35 and a process for making the catalyst to contact with ethylbenzene containing xylenes in the presence of hydrogen.

摘要翻译： 晶体平面间距d值为0.1196±0.002mm，晶格间距d值为0.386±0.008nm的X射线衍射强度比在100:7〜100:35的范围内的催化剂 以及使催化剂在含氢存在下与含乙苯接触的方法。

公开(公告)号：US06462248B1

公开(公告)日：2002-10-08

申请号：US09385270

申请日：1999-08-30

申请人： Jiro Nakatani ,  Eiichi Minomiya ,  Masahiro Inohara ,  Kazuyoshi Iwayama ,  Tetsuya Kato

发明人： Jiro Nakatani ,  Eiichi Minomiya ,  Masahiro Inohara ,  Kazuyoshi Iwayama ,  Tetsuya Kato

IPC分类号： C07C2508

CPC分类号： C07C17/358 ,  C07C5/2737 ,  C07C17/12 ,  C07C17/35 ,  C07C17/389 ,  C07C2529/08 ,  C07C15/02 ,  C07C25/02

摘要： Aromatic compounds having an alkyl group with at least 3 carbon atoms are produced in a process comprising at least one of the following steps: (1) a step of contacting a starting material that contains an aromatic compound having a branched alkyl group with at least 3 carbon atoms, with a zeolite-containing catalyst in a liquid phase in the presence of hydrogen therein, thereby changing the position of the carbon atoms of the alkyl group bonding to the aromatic ring of the compound; (2) a step of contacting a starting material that contains an aromatic compound having a branched alkyl group with at least 3 carbon atoms, with a catalyst containing zeolite and containing rhenium and/or silver, in a liquid phase, thereby changing the position of the carbon atoms of, the alkyl group bonding to the aromatic ring of the compound; (3) a step of contacting a halogenated aromatic compound having an alkyl group with at least 3 carbon atoms, with an acid-type catalyst, thereby isomerizing the compound; (4) a step of treating a mixture of isomers of an aromatic compound having an alkyl group with at least 3 carbon atoms, with a zeolite adsorbent that contains at least one exchangable cation selected from alkali metals, alkaline earth metals, lead, thallium and silver, thereby separating a specific isomer from the isomer mixture through adsorption.

摘要翻译： 具有至少3个碳原子的烷基的芳香族化合物是以至少一个以下步骤的方法生产的：（1）使包含具有支链烷基的芳族化合物的原料与至少3个 碳原子与含有沸石的催化剂在氢气存在下在液相中，从而改变与化合物的芳环键合的烷基的碳原子的位置;（2）使起始 含有具有至少3个碳原子的支链烷基的芳族化合物的物质，含有沸石的催化剂，含有铼和/或银的液相，从而改变了烷基键合的碳原子的位置 化合物的芳香环;（3）使具有至少3个碳原子的烷基的卤代芳族化合物与酸型催化剂接触的步骤，从而使组合物异构化 （4）将具有至少3个碳原子的具有烷基的芳族化合物的异构体的混合物与沸石吸附剂一起处理的步骤，所述沸石吸附剂含有至少一种选自碱金属，碱土金属，铅， 铊和银，从而通过吸附从异构体混合物中分离出特定异构体。

公开(公告)号：US06262322B1

公开(公告)日：2001-07-17

申请号：US09434891

申请日：1999-11-05

申请人： Masatoshi Watanabe ,  Masahito Yoshikawa ,  Kazuyoshi Iwayama

发明人： Masatoshi Watanabe ,  Masahito Yoshikawa ,  Kazuyoshi Iwayama

IPC分类号： C07C1738

CPC分类号： B01J20/186 ,  C07C17/389

摘要： An adsorbent which comprises a zeolite containing Cs and/or Rb, said zeolite being characterized by that the ratio of [the number of moles of Cs and/or R in the zeolite] to [the number of moles of Al in the zeolite] is 0.1 or less. This adsorbent permits efficient separation of an isomer from a mixture of aromatic isomers.

摘要翻译： 一种吸附剂，其包含含有Cs和/或Rb的沸石，所述沸石的特征在于：[沸石中Cs和/或R的摩尔数]与[沸石中Al的摩尔数]之比为 0.1以下。 该吸附剂允许从芳族异构体的混合物有效分离异构体。

公开(公告)号：US4861928A

公开(公告)日：1989-08-29

申请号：US152406

申请日：1988-02-04

申请人： Kazuyoshi Iwayama ,  Yasuhiro Magatani ,  Kuniyuki Tada

发明人： Kazuyoshi Iwayama ,  Yasuhiro Magatani ,  Kuniyuki Tada

IPC分类号： B01J29/06 ,  B01J29/00 ,  B01J29/26 ,  B01J29/78 ,  C07B61/00 ,  C07C17/00 ,  C07C17/358 ,  C07C25/02 ,  C07C67/00

CPC分类号： C07C17/358

摘要： By using a catalyst containing an acid type zeolite and at least one component of metal selected from the group consisting of rhenium, nickel and silver and isomerizing a mixture of the isomers of dichlorotoluene in the presence of hydrogen, the concentration of at least one or more components of the isomers of dichlorotoluene can be increased. According to this method, there is provided a process for isomerization of DCT which exhibits a high isomerization capacity not degraded with reaction time.

公开(公告)号：US4581216A

公开(公告)日：1986-04-08

申请号：US692999

申请日：1985-01-22

申请人： Kazuyoshi Iwayama ,  Takao Kamano ,  Kuniyuki Tada ,  Takehisa Inoue

发明人： Kazuyoshi Iwayama ,  Takao Kamano ,  Kuniyuki Tada ,  Takehisa Inoue

IPC分类号： C07C5/27 ,  B01J29/00 ,  C01B39/02 ,  C01B39/04 ,  C01B39/36 ,  C01B39/40 ,  C07C1/00 ,  C07C15/067 ,  C07C15/08 ,  C07C67/00 ,  C01B33/28

CPC分类号： C01B39/02 ,  C01B33/2861 ,  Y10S423/34

摘要： A crystalline aluminosilicate zeolite is obtained by stirring under heating an aqueous reaction mixture containing a silica source, an alumina source, an alkali source and an organic carboxylic acid.

公开(公告)号：US4572779A

公开(公告)日：1986-02-25

申请号：US579171

申请日：1984-02-10

申请人： Kazuyoshi Iwayama ,  Takehisa Inoue ,  Kimio Sato ,  Norio Hayakawa ,  Masaki Fujii

发明人： Kazuyoshi Iwayama ,  Takehisa Inoue ,  Kimio Sato ,  Norio Hayakawa ,  Masaki Fujii

IPC分类号： C10G73/02 ,  B01J29/40 ,  B01J29/70 ,  C01B39/38 ,  C10G45/64

CPC分类号： C10G45/64 ,  B01J29/40 ,  B01J29/70 ,  C01B39/38 ,  B01J2229/26 ,  B01J2229/42

摘要： A process for improving the fluidity of hydrocarbon fractions by dewaxing thereof. In the present process, hydrocarbon fractions are contacted with hydrogen in the presence of a specific type of catalyst, thereby lowering the pour point of the hydrocarbon fraction. The catalyst comprises a specific type of zeolite which is defined by a specific X-ray diffraction pattern and which has a predetermined range of mesitylene adsorption of not less than 1.6 wt %. The zeolite catalyst is obtained by providing an aqueous reaction mixture of SiO.sub.2, Al.sub.2 O.sub.3, an alkaline source as OH.sup.-, and a carboxyl group-containing organic compound having the following composition:______________________________________ SiO.sub.2 /Al.sub.2 O.sub.3 20-60 H.sub.2 O/SiO.sub.2 5-100 OH.sup.- /SiO.sub.2 0.1-0.35 ______________________________________ and reacting the mixture until crystals are produced. Advantageously, the ratio of the carboxyl group-containing organic compound to aluminum oxide is about 1.0 to 100.

摘要翻译： 通过脱蜡改善烃馏分的流动性的方法。 在本方法中，在特定催化剂存在下，使烃馏分与氢接触，从而降低烃馏分的倾点。 该催化剂包括由特定的X射线衍射图定义并且具有不小于1.6重量％的均三甲苯吸附的预定范围的特定类型的沸石。 沸石催化剂通过提供SiO 2，Al 2 O 3，碱性源作为OH-的含水反应混合物和具有以下组成的含羧基的有机化合物获得：-SiO 2 / Al 2 O 3 20-60 -H 2 O / SiO 2 5-100 -OH- / SiO 2 0.1-0.35 - 并使混合物反应直至产生晶体。 有利地，含羧基的有机化合物与氧化铝的比例为约1.0至100。