Method for the production of 4,4′-[1-trifluoromethyl)alkylidene]-bis-(2,6-diphenylphenols)
    12.
    发明授权
    Method for the production of 4,4′-[1-trifluoromethyl)alkylidene]-bis-(2,6-diphenylphenols) 有权
    制备4,4' - [1-三氟甲基)亚烷基] - 双(2,6-二苯基苯酚)

    公开(公告)号:US08212084B2

    公开(公告)日:2012-07-03

    申请号:US12808865

    申请日:2008-12-17

    IPC分类号: C07C39/16 C07C39/12

    摘要: The present invention relates to a process for preparing 4,4′-[1-(trifluoromethyl)alkylidene]bis(2,6-diphenylphenols), in particular for preparing 4,4′-[1-(trifluoromethyl)ethylidene]bis(2,6-diphenylphenol), which comprises the self-condensation of cyclohexanone in the presence of a basic catalyst to form tricyclic condensation products, dehydrogenation of the resulting tricyclic condensation products in the presence of a supported transition metal catalyst in the condensed phase to form 2,6-diphenylphenol and reaction of the 2,6-diphenylphenol with a trifluoromethyl ketone. The invention further provides an improved process for preparing 2,6-diphenylphenol by aldol self-condensation of cyclohexanone.

    摘要翻译: 本发明涉及一种制备4,4' - [1-(三氟甲基)亚烷基]双(2,6-二苯基苯酚)的方法,特别是制备4,4' - [1-(三氟甲基)亚乙基]双( 2,6-二苯基苯酚),其包括环己酮在碱性催化剂存在下的自缩合以形成三环缩合产物,所得三环缩合产物在冷凝相中负载的过渡金属催化剂存在下脱氢形成 2,6-二苯基苯酚和2,6-二苯基苯酚与三氟甲基酮的反应。 本发明还提供了通过环己酮的醛醇自缩合制备2,6-二苯基苯酚的改进方法。

    PROCESS FOR THE PREPARATION OF ETHYLGERANONITRILE
    14.
    发明申请
    PROCESS FOR THE PREPARATION OF ETHYLGERANONITRILE 审中-公开
    乙酰胆碱酯酶的制备方法

    公开(公告)号:US20100204083A1

    公开(公告)日:2010-08-12

    申请号:US12670689

    申请日:2008-07-16

    IPC分类号: C07C253/30 A61K8/40

    摘要: The present invention relates to a method of producing ethylgeranonitrile through reaction of ethylheptenone with a deprotonated nitrile and, if appropriate, subsequent saponification and decarboxylation. Moreover, the invention relates to mixtures comprising 3,7-dimethyl-2,6-nonadienenitrile and at least one compound selected from the group of compounds 3,7-dimethyl-3,6-nonadienenitrile and 3-methylene-7-methyl-6-nonenenitrile, and to fragrance compositions comprising these.

    摘要翻译: 本发明涉及通过乙基庚烯酮与去质子化腈的反应以及如果合适的话随后皂化和脱羧反应生产乙腈的方法。 此外,本发明涉及包含3,7-二甲基-2,6-壬二腈和至少一种选自化合物3,7-二甲基-3,6-壬二腈和3-亚甲基-7-甲基 - 6-壬烯腈,以及包含它们的香料组合物。

    Process for the preparation of &agr;-diketones from ketols or ketals from ketols
    16.
    发明授权
    Process for the preparation of &agr;-diketones from ketols or ketals from ketols 失效
    从酮基酮或酮缩酮制备α-二酮的方法

    公开(公告)号:US06242653B1

    公开(公告)日:2001-06-05

    申请号:US09377732

    申请日:1999-08-19

    IPC分类号: C07C4529

    摘要: The process for the preparation of carbonyl compounds of the formula I where R1 and R2 are a hydrocarbon radical, or R1 and R2 together are an unsubstituted or substituted alkylene group, and X is=O or two alkoxy groups, comprises oxidizing alcohols of the formula II where R1 to R2 and X are as defined above, with oxygen in the gaseous phase a) at temperatures of from 270 to 600° C. on silver coated catalysts which comprise an abrasion-resistant coating of metallic silver on a core of inert support material, or b) at temperatures of from 450 to 750° C. on silver crystals and/or copper crystals having a particle size of from 0.1 to 2.5 mm for a residence time of at most 0.1 second. Also claimed is an advantageous overall process for the preparation of &agr;-diketones, preferably diacetal, from the corresponding ketone, in particular methyl ethyl ketone, via the carbonyl compounds of the formula I where X is two alkoxy groups.

    摘要翻译: 制备式I的羰基化合物的方法,其中R 1和R 2是烃基,或者R 1和R 2一起是未取代或取代的亚烷基,并且X是= O或两个烷氧基,包括氧化式II的醇,其中R 1 在含有惰性载体材料芯上的金属银的耐磨涂层的银涂覆的催化剂上,在温度为270-600℃的温度下,R2和X如上定义,在气相中为氧) 在450至750℃的温度下,在银晶体和/或具有0.1至2.5mm的粒度的铜晶体上,停留时间至多为0.1秒。还要求保护的是制备α 二酮,优选二缩醛,通过其中X是两个烷氧基的式I的羰基化合物从相应的酮,特别是甲基乙基酮中获得。

    Regulating valve
    17.
    发明授权
    Regulating valve 失效
    调节阀

    公开(公告)号:US5893392A

    公开(公告)日:1999-04-13

    申请号:US748039

    申请日:1996-11-12

    摘要: A regulating valve comprising a housing having a cylindrical valve chamber, the valve chamber being provided with at least one inlet and at least two outlets, the inlet and the outlets being at least partially closeable as needed by a common valve body arranged in the valve chamber and rotatable around an axis, the valve body being operable by an actuator, the inlet and/or at least one of the outlets being surrounded by a sealing device on the side of the housing facing the valve body and the sealing device being able to be brought into sealing engagement with the valve body under elastic preload. The valve body is designed having the shape of the segment of a cylinder and is bounded on the peripheral side by two boundary surfaces which each have an edge on the side facing the housing, the edge overtravelling the inlet during its opening being designed as an efflux edge and having an elliptically shaped recess extending in axial direction. Configured in the valve body is a duct-shaped opening which extends between the boundary surfaces and penetrates them.

    摘要翻译: 一种调节阀,包括具有圆柱形阀室的壳体,所述阀室设置有至少一个入口和至少两个出口,所述入口和所述出口根据需要至少部分地可关闭,所述公共阀体布置在所述阀室中 并且可围绕轴线旋转,所述阀体可由致动器操作,所述入口和/或所述至少一个出口被所述壳体面向所述阀体的侧面上的密封装置包围,并且所述密封装置能够 在弹性预载下与阀体密封接合。 阀体被设计成具有圆柱形部分的形状并且在周边侧边界由两个边界面,每个边界面在面向壳体的一侧上具有边缘,在其开口期间过度进入入口的边缘被设计为外流 并且具有沿轴向方向延伸的椭圆形凹部。 在阀体中配置的是在边界表面之间延伸并穿透其的管状开口。

    Gas-liquid separator
    19.
    发明授权
    Gas-liquid separator 失效
    气液分离器

    公开(公告)号:US5536289A

    公开(公告)日:1996-07-16

    申请号:US388001

    申请日:1995-02-13

    CPC分类号: F01M13/023 F01M13/04 F02B1/04

    摘要: A liquid separator for the separation of liquids from gases is disclosed. The separator has an inlet orifice for receiving a flow of the gas laden with liquid, a first outlet for the liquid and a second outlet for the gas liberated from the liquid, and an adjusting mechanism for varying the available cross-sectional area arranged in the inlet orifice. The inlet orifice has a tubular passage cross-section and is bounded along its entire length by a dimensionally fixed wall. The adjusting mechanism has a pressure control assembly having a pneumatically operable control element which is arranged within the inlet orifice in a manner allowing relative movement therewith.

    摘要翻译: 公开了一种用于从气体中分离液体的液体分离器。 分离器具有用于接收装载有液体的气体流的入口孔,用于液体的第一出口和用于从液体释放的气体的第二出口,以及用于改变布置在液体中的可用横截面积的调节机构 入口孔。 入口孔具有管状通道横截面并且通过尺寸固定的壁沿其整个长度界定。 调节机构具有压力控制组件,其具有气动操作的控制元件,该控制元件以允许与其相对运动的方式布置在入口孔内。

    Hydraulic valve play equalization element
    20.
    发明授权
    Hydraulic valve play equalization element 失效
    液压阀打均衡元件

    公开(公告)号:US5295460A

    公开(公告)日:1994-03-22

    申请号:US012687

    申请日:1993-02-03

    IPC分类号: F01L1/24 F01L1/25

    CPC分类号: F01L1/25 Y10T74/2107

    摘要: A hydraulic valve play equalization element for the valve drive of an internal combustion engine is disclosed. The equalization element comprises an inner tappet and an outer tappet arranged to move relative to one another in the axial direction. The outside tappet is formed by an essentially cup-shaped housing with a level bottom and the inside tappet and the outside tappet delimit an oil-filled storage space which is sealed towards the outside and which can change in volume. A displacement element to equalize volume changes is enclosed in the storage space. The outside tappet is formed by an essentially tube-shaped mantle of thermoplastic material, which has slide surfaces radially inside and outside. The mantle is closed off with a fluid seal, by a disk structured as an expeller, in the direction of a cam shaft that is used. The inside slide surface encloses the inside tappet, resting against its circumference, and forming a fluid seal.

    摘要翻译: 公开了一种用于内燃机的阀驱动的液压阀游隙均衡元件。 均衡元件包括内部挺杆和外部挺杆,其布置成在轴向方向上相对于彼此移动。 外部挺杆由基本上具有水平底部的杯形壳体形成,并且内部挺杆和外部挺杆限定了向外部密封并且可能改变体积的充满油的储存空间。 用于均衡音量变化的位移元件包含在存储空间中。 外部挺杆由基本上管状的热塑性材料罩形成,其具有径向内部和外部的滑动表面。 通过使用的凸轮轴的方向,通过作为推进器构成的盘形的流体密封封闭地幔。 内部滑动表面包围内部挺杆,靠在其周边上,并形成流体密封。