Polymer Materials With Silane-Based Transfer Reagents

    公开(公告)号:US20190010172A1

    公开(公告)日:2019-01-10

    申请号:US16025287

    申请日:2018-07-02

    摘要: Radically polymerizable silane according to the general formula I in which R1 is a linear or branched aliphatic C1-C9-alkyl radical, phenyl or alkylated phenyl radical, R2, R3 independently of each other in each case are absent or are a linear or branched aliphatic C1-C20-alkylene radical, which can be interrupted by S or O atoms, R4, R5, R6 independently of each other in each case are —Cl, —O—CH3, —O—C2H5, —CH3 or —C2H5, X is CH2 or O, Y is absent, or is O or NR′, wherein R′ is H or a C1-5-alkyl radical, and Z is absent, or is O, NR″, —CO—O—, —CO—NR″—, —O—CO—O—, —O—CO—NR″—, or —NR″—CO—NR″—, wherein R″ is H or a C1-5-alkyl radical and wherein the radicals R2 and R3 cannot be absent at the same time and Z is absent if R2 or R3 is absent, polycondensates based thereon and fillers surface-modified therewith.

    LIGHT-CURING DENTAL COMPOSITES WITH INCREASING OPACITY

    公开(公告)号:US20170224591A1

    公开(公告)日:2017-08-10

    申请号:US15502568

    申请日:2015-08-19

    摘要: Radically polymerizable dental material which contains (a) at least one polyfunctional radically polymerizable monomer, (b) at least one further radically polymerizable monomer which can be monofunctional or polyfunctional, (c) at least one photoinitiator for the radical polymerization and (d) at least one filler. The material is characterized in that the mixture of the monomers (a) and (b) has a refractive index of from 1.50 to 1.70 and in that the refractive index of the monomer mixture before the curing corresponds to the refractive index of the filler used or is higher by up to 0.013 and after the curing is higher than the refractive index of the filler by at least 0.02.

    B-Ketophosphonic Acids And Dental Materials Based Thereon
    15.
    发明申请
    B-Ketophosphonic Acids And Dental Materials Based Thereon 有权
    B-酮膦酸及其牙科材料

    公开(公告)号:US20160145277A1

    公开(公告)日:2016-05-26

    申请号:US14898665

    申请日:2014-05-27

    IPC分类号: C07F9/38 A61K6/083 C08F222/38

    摘要: β-Ketophosphonic acid according to general formula I: in which A=an aliphatic C1-C18 radical which can be interrupted by —O—, —S—, —CO—O— or —O—CO—C—; n=1, 2, 3 or 4; m=1 or 2; X=absent or a C1-C10 radical which can be interrupted by —O—, —S—, —CO—C—, —O—CO—NH— or —CO—NR1—, wherein R1 is H or C1-C7-alkyl; and PG=a group which can undergo free radical polymerization. The β-ketophosphonic acids are suitable in particular for the preparation of dental materials.

    摘要翻译: 根据通式I的酮膦酸:其中A =可以被-O - , - S-,-CO-O-或-O-CO-C-间隔的脂族C1-C18基团; n = 1,2,3或4; m = 1或2; X =不存在或可以被-O - , - S - , - CO-C - , - O-CO-NH-或-CO-NR1-中断的C1-C10基团,其中R1是H或C1-C7 -烷基; PG =可进行自由基聚合的基团。 酮基膦酸特别适用于制备牙科材料。

    Dental restorative materials based on polymerizable azides and alkynes
    16.
    发明授权
    Dental restorative materials based on polymerizable azides and alkynes 有权
    基于可聚合叠氮化物和炔烃的牙齿修复材料

    公开(公告)号:US09333150B2

    公开(公告)日:2016-05-10

    申请号:US14100207

    申请日:2013-12-09

    IPC分类号: A61K6/08 A61K6/087 C07D403/14

    CPC分类号: A61K6/087 C07D403/14

    摘要: The invention relates to a dental restorative material on the basis of at least one compound of Formula I A-[X-Q-(Y-CG)n]m   Formula I, wherein CG represents in each case independently an azide group N3 or an alkyne group selected from the group consisting of —CR1R2—C≡CH, with the proviso that the dental restorative material comprises at least one compound of Formula I comprising an azide group and at least one compound of Formula I comprising an alkyne group. The invention also relates to the use of the dental restorative materials according to the invention for preparing dental composites, preferably composite blanks, which are suitable in particular for mechanical processing by means of computer-aided processing techniques such as milling and grinding processes, and which are suitable above all for preparing dental restoration materials such as inlays, onlays, crowns, bridges or veneering materials.

    摘要翻译: 本发明涉及一种基于式IA- [XQ-(Y-CG)n] m式I的至少一种化合物的牙齿修复材料,其中,CG各自独立地表示叠氮基N 3或炔基 选自-CR1R2-C≡CH,条件是牙齿修复材料包含至少一种包含叠氮基的式I化合物和至少一种包含炔基的式I化合物。 本发明还涉及根据本发明的牙齿修复材料用于制备牙科复合材料,优选复合坯料的用途,其特别适用于通过计算机辅助加工技术如铣削和研磨工艺进行机械加工,以及哪些 首先适用于制备诸如镶嵌,镶嵌,冠,桥或镶嵌材料的牙修复材料。

    POLYMERIZABLE COMPOSITIONS WITH HIGH POLYMERIZATION DEPTH
    18.
    发明申请
    POLYMERIZABLE COMPOSITIONS WITH HIGH POLYMERIZATION DEPTH 有权
    具有高聚合深度的聚合物组合物

    公开(公告)号:US20150080490A1

    公开(公告)日:2015-03-19

    申请号:US14391759

    申请日:2013-04-11

    IPC分类号: A61K6/083

    CPC分类号: A61K6/0835 A61K6/0052

    摘要: The invention relates to a composition with at least one polymerizable binder, wherein the composition contains a photoinitiator mixture which contains (a) at least one diacylgermanium compound of general formula (I) in which R1, R2 independently of each other are a linear C1-4-alkyl, or C2-4-alkenyl radical, which can be substituted by one or more polymerizable groups; R3, R4 independently of each other are in each case H, halogen, a branched or linear C1-4-alkyl or —O—C1-4-alkyl radical; R5, R6, R7 independently of each other are in each case H, halogen, a linear C1-20-alkyl, -alkenyl, -alkoxy or -alkenoxy radical, which can be interrupted by one or more —O—, —S— or —NR8— radicals and substituted by one or more polymerizable groups; and R8 independently is in each case H, a C1-20-alkyl, -alkenyl, -alkoxy or -alkenoxy radical, (b) at least one α-diketone and (c) at least one accelerator, as well as the use of the composition for example for producing a filling composite.

    摘要翻译: 本发明涉及具有至少一种可聚合粘合剂的组合物,其中组合物含有光引发剂混合物,其含有(a)至少一种通式(I)的二酰基锗化合物,其中R 1,R 2彼此独立地为直链C1- 4-烷基或C 2-4 - 烯基,其可以被一个或多个可聚合基团取代; 在各种情况下,R 3,R 4彼此独立地为H,卤素,支链或直链C 1-4 - 烷基或-O-C 1-4 - 烷基; R 5,R 6,R 7彼此独立地为H,卤素,直链C 1-20 - 烷基, - 烯基, - 烷氧基或 - 烷氧基,其可以被一个或多个-O - , - S- 或-NR 8 - 基团,并被一个或多个可聚合基团取代; 和R8独立地为H,C 1-20烷基, - 烯基, - 烷氧基或 - 烷氧基,(b)至少一种α-二酮和(c)至少一种促进剂,以及使用 例如用于生产填充复合材料的组合物。