摘要:
The present invention relates to a poly(arylene sulfide) composition including a combination of a limited amount of an antioxidant compound and of an epoxy-functional polyorganosiloxane polymer, possessing improved mechanical performances and outstanding thermal ageing resistance, to a process for its manufacturing, as well as to an article, part or composite material comprising said composition, and to the use of this composition for the manufacture of 3D objects
摘要:
Provided is a block copolymer comprising a polymer block (A) which comprises repeating units of formula (I) and a polymer block (B) which comprises repeating units of formula (II),
wherein R1 is methyl or ethyl, and R2 represents a group —CH2—CH2-phenyl. The copolymer of the present invention allows a rapid thermoresponsive inverse gelation to be achieved, yielding a hydrogel with viscoelastic solid-like properties, as well as shear thinning, rapid structure recovery and good strain resistance properties. The hydrogel can be favorably used in 3D printing applications.
摘要:
A polymerizable liquid useful for the production of a three-dimensional object comprised of silicone, or a copolymer thereof, which includes at least one constituent selected from the group consisting of (i) a blocked or reactive blocked siloxane-containing prepolymer, (ii) a blocked or reactive blocked siloxane-containing polyisocyanate, and (iii) a blocked or reactive blocked siloxane-containing polyisocyanate chain extender. Methods of using the same in additive manufacturing processes such as continuous liquid interface production are also described.
摘要:
An organic microgel system as support material for 3D printing of soft materials such as silicone and methods for manufacturing and using the organic microgel system are disclosed. In some embodiments, the organic microgel system comprises a plurality of microgel particles formed by blending a di-block copolymer and a tri-block copolymer in an organic solvent. The organic microgel system may allow high precision 3D printing of silicone objects with complex shapes.
摘要:
Polymerizable liquids are described herein which, in some embodiments, can produce 3D printed articles of high resolution and desirable mechanical properties. In one aspect, a polymerizable liquid comprises an acrylate component, a polymeric additive, and a monomeric curing agent, wherein the acrylate component and monomeric curing agent are copolymerizable upon exposure to light. In being copolymerizable, the acrylate component and monomeric curing agent can form a copolymer. As described father herein, the monomeric curing agent can enable further reaction of the copolymer with one or more crosslinking species to link the copolymer with one more polymeric networks.
摘要:
Disclosed herein are a molded body having a continuous phase (A) containing a first polyolefin resin and a second polyolefin resin and a dispersed phase (B) containing a polyamide resin and a modified elastomer, wherein the dispersed phase (B) is composed of a melt-kneaded product of the polyamide resin and the modified elastomer, and wherein when a total of the continuous phase (A) and the dispersed phase (B) is 100% by mass, a content of the dispersed phase (B) is 70% by mass or less, and when a total of the first polyolefin resin and the second polyolefin resin is 100% by mass, a content of the second polyolefin resin is 70% by mass or less, and a method including the steps of: obtaining a molded body raw material by mixing a first polyolefin resin and an impact-resistant resin obtained by melt-kneading a second polyolefin resin and a melt-kneaded product of a polyamide resin and a modified elastomer; and obtaining a molded body.
摘要:
Disclosed herein is a film comprising a polymer blend, the polymer blend comprising a first polyolefin elastomer having a weight average molecular weight of 120,000 to 350,000 grams per mole; and a second polyolefin elastomer having a weight average molecular weight of 15,000 to 75,000 grams per mole; wherein the overall melt index of the polymer blend is less than 8 g/10 minutes when measured as per ASTM D1238 at 2.16 kilograms at 190° C. Disclosed herein too is a method of manufacturing a film comprising blending a first polyolefin elastomer having a weight average molecular weight of 120,000 to 350,000 grams per mole; and a second polyolefin elastomer having a weight average molecular weight of 15,000 to 75,000 grams per mole to form a polymer blend; wherein the overall melt index of the polymer blend is less than 8 g/10 minutes when measured as per ASTM D1238 at 2.16 kilograms at 190° C.; and forming the polymer blend into a film.
摘要:
The present invention relates to a method for interconnecting components of a sporting good, in particular a sports shoe, and a sports shoe manufactured with such a method. The method may include (a.) forming a pattern element having at least one removable at least partially non-transparent or non-reflective portion, (b.) irradiating at least one of the first and the second component via the pattern element with heat radiation and (c.) interconnecting the irradiated first and second component.
摘要:
Directionally oriented block copolymer films and zone annealing processes for producing directionally oriented block films are provided. The zone annealing processes include methods of inducing horizontally oriented block copolymers through a soft sheer process and methods of inducing vertically oriented block copolymers via sharp dynamic zone annealing. The zone annealing processes are capable of both small and large scale production of directionally oriented block films. The cold zone annealing processes are also capable of being combined with graphoepitaxy methods.
摘要:
Methods are disclosed for a novel and useful single pass extrusion process for the reactive extrusion and compounding of polymers. Traditional extruders utilized in reactive processes are of length to diameter ratios ranging from 30 to 1 to as high as 56 to 1. The process disclosed uses a series of sequential, very closely-coupled, independently driven screw extruders having a total effective length to diameter ratio much greater than 70 to 1 and as high as 132 to 1 or greater, and providing greatly extended reaction times, separate and multiple introductions of reactive and non-reactive agents and mechanical connections allowing for convenient screw changes and differential thermal expansion. The assembly is employed to economically produce grafted polyolefins, produce ionomers without employing the use of strong caustic agents, remove large volumes of unwanted polymer processing solvents and produce other reacted polymer species in one continuous pass.