公开(公告)号：US20130023599A1

公开(公告)日：2013-01-24

申请号：US13627127

申请日：2012-09-26

申请人： Yu-Ling Hsiao ,  Richard G. Skorpenske ,  Bryan D. Kaushiva ,  Kenneth G. McDaniel ,  Jose F. Pazos ,  Stanley L. Hager ,  Karl W. Haider

发明人： Yu-Ling Hsiao ,  Richard G. Skorpenske ,  Bryan D. Kaushiva ,  Kenneth G. McDaniel ,  Jose F. Pazos ,  Stanley L. Hager ,  Karl W. Haider

IPC分类号： C07C51/367 ,  C08G18/68

CPC分类号： C08G18/4891 ,  C08G18/4866 ,  C08G2101/0008 ,  C08G2101/005

摘要： The present invention provides polyurethane foams and elastomers made with an alkoxylated vegetable oil hydroxylate replacing at least a portion of the typically used petroleum-based polyol(s). Also provided are processes for making the inventive foams and elastomers and for making alkoxylated vegetable oil hydroxylates. The alkoxylated vegetable oil hydroxylates are environmentally-friendly, bio-based polyols which advantageously also offer the potential of improved hydrophobicity in polyurethane foams and elastomers. The inventive polyurethane foams and elastomers may find use in a wide variety of products such as automobile interior parts, polyurethane structural foams, floor coatings and athletic running tracks.

摘要翻译： 本发明提供用烷氧基化植物油羟基化物制备的聚氨酯泡沫和弹性体，代替至少一部分通常使用的石油基多元醇。 还提供了制备本发明的泡沫和弹性体以及用于制备烷氧基化植物油羟基化物的方法。 烷氧基化植物油羟基化物是环境友好的基于生物的多元醇，其有利地还提供聚氨酯泡沫和弹性体中改善的疏水性的潜力。 本发明的聚氨酯泡沫和弹性体可以用于各种各样的产品，例如汽车内部部件，聚氨酯结构泡沫，地板涂料和运动跑道。

公开(公告)号：US5919988A

公开(公告)日：1999-07-06

申请号：US20464

申请日：1998-02-09

申请人： Jose F. Pazos ,  Veril C. Jividen

发明人： Jose F. Pazos ,  Veril C. Jividen

IPC分类号： C08G65/10 ,  C08G18/08 ,  C08G18/48 ,  C08G65/26 ,  C07C41/03

CPC分类号： C08G65/2663 ,  C08G18/14 ,  C08G18/4866 ,  C08G65/2696 ,  C08G2101/0008 ,  C08G2101/0083

摘要： Double metal cyanide-catalyzed polyols are made by an improved process in which a starter is continuously added during polymerization of the epoxide. The process includes a continuously added starter (S.sub.c), and optionally, an initially charged starter (S.sub.i). The continuously added starter comprises at least about 2 equivalent percent of the total starter used. The process enables the use of water and low molecular weight polyol starters in DMC-catalyzed polyol synthesis. In addition, the process gives polyether polyols having reduced levels of high molecular weight polyol tail, which can adversely affect polyurethane foam processing.

摘要翻译： 双金属氰化物催化的多元醇通过改进的方法制备，其中在环氧化物的聚合期间连续加入起始物。 该方法包括连续添加的起动器（Sc），以及可选的初始充电起动器（Si）。 连续添加的起动器包括使用的总起动器的至少约2当量％。 该方法能够在DMC催化的多元醇合成中使用水和低分子量多元醇起始物。 此外，该方法提供具有降低水平的高分子量多元醇尾巴的聚醚多元醇，其可能不利地影响聚氨酯泡沫处理。

公开(公告)号：US5689012A

公开(公告)日：1997-11-18

申请号：US683356

申请日：1996-07-18

申请人： Jose F. Pazos ,  T. Thomas Shih

发明人： Jose F. Pazos ,  T. Thomas Shih

IPC分类号： C08G65/10 ,  C08G65/26 ,  C07C43/11

CPC分类号： C08G65/2663 ,  C08G65/2696

摘要： A continuous process for the preparation of polyoxyalkylene polyethers using DMC catalysts as the polyoxyalkylation catalyst employs continuous addition of alkylene oxide in conjunction with continuous addition of starter and catalyst to a continuous oxyalkylation reactor. Despite the continuous introduction of starter, the molecular weight distribution of the polyether product is quite narrow, as indicated by the exceptionally low polydispersity of the product. The presence of low molecular weight species during the majority of the polyoxyalkylation also substantially eliminates extremely high molecular weight fractions having molecular weights greater than 100,000 Da, again without appreciably broadening molecular weight distribution. By withdrawing intermediate molecular weight polyether product or diverting a portion of the end product to prepare a catalyst/starter mixture, rapid and sustained reaction rates can be achieved while employing low molecular weight starters. Continuous build ratios in excess of 0.98 can be achieved.

摘要翻译： 使用DMC催化剂作为聚氧化烷基化催化剂制备聚氧化烯聚醚的连续方法是连续加入环氧烷，连续加入引发剂和催化剂至连续的烷氧基化反应器。 尽管连续引入起始物，但聚醚产物的分子量分布相当窄，如产物的多分散性极差。 在大部分聚氧化烷基化期间低分子量物质的存在也基本上消除了分子量大于100,000Da的极高分子量级分，同时又没有明显地扩大分子量分布。 通过取出中间分子量聚醚产物或转移一部分最终产物以制备催化剂/起始混合物，可以在使用低分子量起始剂的同时实现快速和持续的反应速率。 连续建造率可以达到0.98以上。

公开(公告)号：US5491210A

公开(公告)日：1996-02-13

申请号：US341513

申请日：1989-04-21

申请人： Fidelis C. Onwumere ,  Jose F. Pazos

发明人： Fidelis C. Onwumere ,  Jose F. Pazos

IPC分类号： C08G18/10 ,  C08G18/50 ,  C08G18/61

CPC分类号： C08G18/61 ,  C08G18/10 ,  C08G18/5024

摘要： The invention provides a polymer adapted for use in melt processes, the polymer having a thermally reversible bond which is adapted to evanesce at an elevated temperature and revert to a thermally reversible bond upon cooling to ambient temperature so that the polymer is adapted, upon being heated to the elevated temperature, to dissociate into melt processable polymeric fragments and, upon being cooled to ambient temperature, to re-associate. The thermally reversible bond is a bond that is capable of evanescing at a temperature which is lower than the degradation temperature of the polymer fragments. The thermally reversible bond may be, for example, a thermally reversible aromatic urethane bond.

摘要翻译： 本发明提供了一种适用于熔体工艺的聚合物，该聚合物具有热可逆键，该热可逆键适于在升高的温度下消失，并在冷却至环境温度时回复为热可逆键，使得聚合物在加热时适应 到升高的温度，以解离成可熔融加工的聚合物碎片，并且在冷却至环境温度时重新结合。 热可逆键是能够在低于聚合物碎片的降解温度的温度下消失的键。 热可逆键可以是例如热可逆的芳族氨基甲酸酯键。

公开(公告)号：US4725628A

公开(公告)日：1988-02-16

申请号：US888545

申请日：1986-07-18

申请人： Chad E. Garvey ,  Jose F. Pazos ,  Gerard J. F. Ring

发明人： Chad E. Garvey ,  Jose F. Pazos ,  Gerard J. F. Ring

IPC分类号： A61L15/60 ,  C08F299/06 ,  C08G18/48 ,  C08G18/67 ,  C08L75/00 ,  C08G18/10

CPC分类号： C08G18/675 ,  A61L15/60 ,  C08F299/06 ,  C08G18/4833 ,  C08G18/671 ,  C08G2101/0083 ,  C08G2270/00 ,  Y10S521/905

摘要： A superabsorbent polyurethane foam which contains a plurality of polycarbonyl moieties covalently attached to the polyurethane through at least one urethane, thiourethane, or urea linkage. The carbonyl portions of such polycarbonyl moieties can be carbamoyl, substituted carbamoyl, or carboxy or the alkali metal or ammonium salts thereof. The foam can be prepared by mixing an isocyanate-terminated prepolymer with a first compound having at least one isocyanate-reactive group and at least one carbon-carbon double bond, allowing the mixture to react, and then mixing with the resulting product an aqueous solution of a carboxylate-containing second compound having at least one carbon-carbon double bond. A thermally activated free radical initiator is present in the final reaction mixture.Preferably, the polyurethane is derived from an isocyanate-terminated poly(oxyalkylene) polyol having an isocyanate functionality greater than two and the polycarbonyl moieties are derived from second compounds which typically are acrylate or methacrylate salts, i.e., alkali metal or ammonium salts of acrylic or methacrylic acid. The first compound usually is the 2-hydroxyethyl ester of acrylic or methacrylic acid.Such superabsorbent polyurethane foam is useful in the manufacture of absorbent articles, especially disposable absorbent articles such as diapers, sanitary napkins, bedpads, incontinent pads, and the like.

摘要翻译： 一种超吸收性聚氨酯泡沫，其包含通过至少一种氨基甲酸酯，硫代氨基甲酸酯或脲键共价连接到聚氨酯上的多个聚羰基部分。 这种多羰基部分的羰基部分可以是氨基甲酰基，取代的氨基甲酰基或羧基或其碱金属或铵盐。 泡沫可以通过将异氰酸酯封端的预聚物与具有至少一个异氰酸酯反应性基团和至少一个碳 - 碳双键的第一化合物混合来制备，使混合物反应，然后与所得产物混合水溶液 的具有至少一个碳 - 碳双键的含羧酸盐的第二化合物。 在最终的反应混合物中存在热活化的自由基引发剂。 优选地，聚氨酯衍生自具有大于2的异氰酸酯官能度的异氰酸酯封端的聚（氧化烯）多元醇，并且多羰基部分衍生自通常为丙烯酸酯或甲基丙烯酸酯盐的第二化合物，即丙烯酸的碱金属或铵盐 甲基丙烯酸。 第一种化合物通常是丙烯酸或甲基丙烯酸的2-羟基乙酯。 这种超吸收性聚氨酯泡沫可用于制造吸收制品，特别是一次性吸收制品如尿布，卫生巾，床垫，失禁垫等。

公开(公告)号：US4168982A

公开(公告)日：1979-09-25

申请号：US858352

申请日：1977-12-07

申请人： Jose F. Pazos

发明人： Jose F. Pazos

IPC分类号： C08F2/46 ,  G03F7/027 ,  G03C1/68 ,  C08F8/18

CPC分类号： G03F7/027 ,  Y10S430/118

摘要： Thermally stable photopolymerizable compositions comprise(i) at least one nongaseous ethylenically unsaturated compound,(ii) a nitroso dimer which is a noninhibitor of free-radical polymerization but thermally dissociates to nitroso monomer which is an inhibitor of free-radical polymerization, and(iii) an organic, radiation-sensitive free-radical generating system.

摘要翻译： 热稳定的可光聚合组合物包含（I）至少一种壬基乙烯亚胺化不饱和化合物，（II）NITROSO二异氰酸酯，其为自由基聚合的非硝基化物，但是对于作为自由基聚合的抑制剂的硝基单体和（III） ）有机辐射敏感型自由放电系统。

公开(公告)号：US20100324340A1

公开(公告)日：2010-12-23

申请号：US12489522

申请日：2009-06-23

申请人： Jose F. Pazos ,  Edward P. Browne ,  Anthony Loveday

发明人： Jose F. Pazos ,  Edward P. Browne ,  Anthony Loveday

IPC分类号： C07C43/10 ,  C07C41/03

CPC分类号： C08G65/2663 ,  C08G65/2696

摘要： The present invention provides a process for the polyoxyalkylation of a starter involving establishing oxyalkylation conditions in an oxyalkylation reactor in the presence of a double metal cyanide (DMC) catalyst, continuously introducing into the reactor at least one alkylene oxide and an acidified, ultra-low water content starter, in which the starter contains greater than about 100 ppm and less than or equal to about 500 ppm water, based on the weight of the starter, and recovering an oxyalkylated low molecular weight starter polyether product. The inventive process allows the production of short chain polyether polyols which have hydroxyl numbers of from greater than 250 up to about 500, from hygroscopic initiators, such as glycerin, without DMC catalyst deactivation.

摘要翻译： 本发明提供了一种引发剂的聚氧化烷基化方法，其涉及在双重金属氰化物（DMC）催化剂的存在下在烷氧基化反应器中建立烷氧基化条件，连续向反应器中引入至少一种烯化氧和酸化的超低 水含量起动器，其中起动器基于起动器的重量包含大于约100ppm且小于或等于约500ppm的水，并且回收烷氧基化的低分子量引发剂聚醚产物。 本发明的方法允许生产具有大于250至约500的羟值的短链聚醚多元醇，来自吸湿性引发剂如甘油，没有DMC催化剂失活。

公开(公告)号：US06083420A

公开(公告)日：2000-07-04

申请号：US356625

申请日：1999-07-19

申请人： Jeffrey J. Lear ,  Oliver D. Sloan ,  Jose F. Pazos

发明人： Jeffrey J. Lear ,  Oliver D. Sloan ,  Jose F. Pazos

IPC分类号： C08G18/48 ,  C08G65/26 ,  C07C43/18

CPC分类号： C08G65/2663 ,  C08G18/4845 ,  C08G18/485 ,  C08G18/4866 ,  C08G2101/0008

摘要： During polyoxyalkylation in the presence of certain double metal cyanide catalysts, a very high molecular weight hydrophobic fraction, i.e. a "tail", is produced during preparation of high secondary hydroxyl polyols which is believed to contribute to foam collapse in polyurethane foam formulations. The processing latitude of such foams may be improved by altering the hydrophile/lipophile balance of the high molecular weight tail by oxyalkylating with a mixture of ethylene oxide and higher alkylene oxide during the greatest portion of total oxyalkylation such that essentially pure higher alkylene oxide is present in a terminal portion of oxyalkylation not exceeding 15 weight percent of total polyol weight.

摘要翻译： 在某些双金属氰化物催化剂存在下的聚氧化烷基化过程中，在制备高次羟基多羟基化合物期间产生非常高分子量的疏水部分，即“尾”，这被认为有助于聚氨酯泡沫制剂中的泡沫破裂。 通过在总烷氧基化的最大部分期间通过用环氧乙烷和较高环氧烷的混合物进行烷氧基化改变高分子量尾料的亲水/亲油平衡来改善这种泡沫的加工范围，使得基本上纯的高级环氧烷存在 在烷氧基化的末端部分不超过总多元醇重量的15重量％。

公开(公告)号：US5777177A

公开(公告)日：1998-07-07

申请号：US597781

申请日：1996-02-07

申请人： Jose F. Pazos

发明人： Jose F. Pazos

IPC分类号： C08G65/10 ,  C08G18/08 ,  C08G18/48 ,  C08G65/26 ,  C07C41/03

CPC分类号： C08G65/2663 ,  C08G18/14 ,  C08G18/4866 ,  C08G65/2696 ,  C08G2101/0008 ,  C08G2101/0083

摘要： Double metal cyanide-catalyzed polyols are made by an improved process in which a starter is continuously added during polymerization of the epoxide. The process includes a continuously added starter (S.sub.c), and optionally, an initially charged starter (S.sub.i). The continuously added starter comprises at least about 2 equivalent percent of the total starter used. The process enables the use of water and low molecular weight polyol starters in DMC-catalyzed polyol synthesis. In addition, the process gives polyether polyols having reduced levels of high molecular weight polyol tail, which can adversely affect polyurethane foam processing.

摘要翻译： 双金属氰化物催化的多元醇通过改进的方法制备，其中在环氧化物的聚合期间连续加入起始物。 该方法包括连续添加的起动器（Sc），以及可选的初始充电起动器（Si）。 连续添加的起动器包括使用的总起动器的至少约2当量％。 该方法能够在DMC催化的多元醇合成中使用水和低分子量多元醇起始物。 此外，该方法提供具有降低水平的高分子量多元醇尾巴的聚醚多元醇，其可能不利地影响聚氨酯泡沫处理。

公开(公告)号：US5773525A

公开(公告)日：1998-06-30

申请号：US880040

申请日：1997-06-20

申请人： Jose F. Pazos

发明人： Jose F. Pazos

IPC分类号： B01J21/10 ,  C08G65/26 ,  C08G65/28

CPC分类号： B01J21/10 ,  C08G65/2609 ,  C08G65/2651 ,  C08G65/2663

摘要： Oligomeric polyoxyalkylene polyethers are prepared by oxyalkylating a low molecular weight hydroxyl-functional starter molecule with one or more alkylene oxides in the presence of a solid, heterogeneous magnesium oxide catalyst. The catalyst is readily and rapidly removed by simple filtration to yield a polyether with minimal metal ion content suitable for use directly or as a starter molecule for further double metal cyanide complex catalyzed oxyalkylation.

摘要翻译： 低聚聚氧化烯聚醚通过在固体异相氧化镁催化剂存在下，用低级分子量的羟基官能起始物分子与一种或多种烯化氧进行烷氧基化来制备。 催化剂通过简单的过滤容易且快速地除去，得到最小金属离子含量的聚醚，其适用于直接使用或作为进一步双金属氰化物络合物催化氧化烷基化的起始分子。