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11.发明授权Aligned liquid crystal layer containing azolium salts and process for increasing the tilt 失效含有azolium盐的对准液晶层和增加倾斜的工艺公开(公告)号：US07097888B2
公开(公告)日：2006-08-29
申请号：US10736392
申请日：2003-12-15
CPC分类号： C09K19/584 , Y10T428/10 , Y10T428/1005 , Y10T428/1036
摘要： Disclosed is a multilayer film comprising a substrate bearing an aligned liquid crystal layer wherein the aligned liquid crystal layer contains an azolium salt represented by formula (I): whereinthe subscripts represent the ring positions and each X is independently N or C—R;each Z is independently N, N—R, C—(R)(R), O, S, SO2, SO, C═O, C═S, or C═NR;each R group is independently hydrogen or a substituent; andY is a charge balancing anion, which may be a separate moiety or part of an X, Z, or R;provided two or more X, Z and R groups may form a ring;provided the salt may be part of an oligomer or polymer.Such a film provides a predetermined increase in pre-tilt angle for use in liquid crystal devices.
摘要翻译： 公开了一种多层膜，其包含具有取向的液晶层的基板，其中所述取向的液晶层包含由式（I）表示的唑鎓盐：其中下标表示环位置，并且每个X独立地为N或C-R; 每个Z独立地为N，N-R，C（R）（R），O，S，SO 2，SO，C-O，C-S或C-NR; 每个R基团独立地为氢或取代基; 并且Y是电荷平衡阴离子，其可以是X，Z或R的单独部分或部分; 提供两个或多个X，Z和R基团可以形成环; 条件是盐可以是低聚物或聚合物的一部分。 这样的薄膜提供用于液晶装置的预倾斜角度的预定增加。
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12.发明授权Silver halide light sensitive emulsion layer having enhanced photographic sensitivity 失效具有增强的照相感光度的卤化银感光乳剂层
公开(公告)号：US6054260A
公开(公告)日：2000-04-25
申请号：US118714
申请日：1998-07-17
申请人： Anthony Adin , Jerome J. Looker , Samir Y. Farid , Ian R. Gould , Stephen A. Godleski , Jerome R. Lenhard , Annabel A. Muenter , Lal C. Vishwakarma , Paul A. Zielinski
发明人： Anthony Adin , Jerome J. Looker , Samir Y. Farid , Ian R. Gould , Stephen A. Godleski , Jerome R. Lenhard , Annabel A. Muenter , Lal C. Vishwakarma , Paul A. Zielinski
CPC分类号： G03C1/10 , G03C1/12 , G03C2200/24
摘要： A photographic element comprising at least one silver halide emulsion layer in which the silver halide is sensitized with a compound of the formula: ##STR1## wherein A is a silver halide adsorptive group that contains at least one atom of N, S, Se, or Te that promotes adsorption to silver halide, and Z is a light absorbing group including for example cyanine dyes, complex cyanine dyes, merocyanine dyes, complex merocyanine dyes, homopolar cyanine dyes, styryl dyes, oxonol dyes, hemioxonol dyes, and hemicyanine dyes, and XY is an fragmentable electron donor moiety in which X is an electron donor group and Y is a leaving group other than hydrogen, and wherein:1) XY has an oxidation potential between 0 and about 1.4 V; and2) the oxidized form of XY undergoes a bond cleavage reaction to give the radical X.sup..cndot. and the leaving fragment Y.In a preferred embodiment of the invention, the radical X.sup..cndot. has an oxidation potential .ltoreq.-0.7 V.
摘要翻译： 一种照相元件，包括至少一个卤化银乳剂层，其中卤化银用下式化合物致敏：其中A是含有至少一个促进的N，S，Se或Te原子的卤化银吸附基团 Z为吸光性基团，例如为花青染料，复合花青染料，部花菁染料，复色部花青染料，单极花青染料，苯乙烯基染料，氧杂菁染料，半氧杂菁染料，半花青染料，XY为 其中X是电子给体基团，Y是除氢以外的离去基团，其中：1）XY具有介于0和约1.4V之间的氧化电位; 和2）XY的氧化形式经历键断裂反应，得到基团X.和离去片段Y.在本发明的一个优选实施方案中，基团X的氧化电势为-0.7V。
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公开(公告)号：US5985526A
公开(公告)日：1999-11-16
申请号：US100215
申请日：1998-06-19
CPC分类号： B41M5/267 , Y10S430/165
摘要： A method of forming an image comprising imagewise-exposing a thermal recording element to heat, the element comprising a support having thereon a thermally-sensitive layer comprising particles containing a colorant, the particles having a particle size between about 1 and about 25 .mu.m suspended in a matrix, the layer having an optical density no higher than about 0.5, the heating thereby causing the colorant to spread out from the particles into the matrix, thus increasing the optical density in the imagewise-exposed areas.
摘要翻译： 一种形成图像的方法，该图像包括成像曝光热敏记录元件以加热，所述元件包括其上具有包含着色剂的颗粒的热敏层的载体，所述颗粒具有约1至约25μm的粒度悬浮 在矩阵中，具有不高于约0.5的光密度的层，加热从而使着色剂从颗粒扩散到基质中，从而增加了成像曝光区域中的光密度。
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14.发明授权Silver halide light sensitive emulsion layer having enhanced photographic sensitivity 失效具有增强的照相感光度的卤化银感光乳剂层
公开(公告)号：US5747235A
公开(公告)日：1998-05-05
申请号：US739921
申请日：1996-10-30
申请人： Samir Y. Farid , Jerome R. Lenhard , Chin H. Chen , Annabel A. Muenter , Ian R. Gould , Stephen A. Godleski , Paul A. Zielinski
发明人： Samir Y. Farid , Jerome R. Lenhard , Chin H. Chen , Annabel A. Muenter , Ian R. Gould , Stephen A. Godleski , Paul A. Zielinski
CPC分类号： G03C1/09 , G03C1/10 , G03C2200/24
摘要： A photographic element comprising at least one silver halide emulsion layer in which the silver halide is sensitized with a compound of the formula: ##STR1## wherein A is a silver halide adsorptive group that contains at least one atom of N, S, Se, or Te that promotes adsorption to silver halide, and L represents a linking group containing at least one C, N, S or O atom, k is 1 or 2, and XY is an fragmentable electron donor moiety in which X is an electron donor group and Y is a leaving group other than hydrogen, and wherein: 1) XY has an oxidation potential between 0 and about 1-4 V; and 2) the oxidized form of XY undergoes a bond cleavage reaction to give the radical X.sup..cndot. and the leaving fragment Y. In a preferred embodiment of the invention, the radical X.sup..cndot. has an oxidation potential .ltoreq.-0.7V.
摘要翻译： 一种照相元件，包括至少一个卤化银乳剂层，其中卤化银用下列化学式的化合物敏化：含有至少一个促进对卤化银吸附的N，S，Se或Te原子，L和 表示含有至少一个C，N，S或O原子的连接基团，k为1或2，XY为可裂解的电子给体部分，其中X为电子给体基团，Y为氢以外的离去基团， 其中：1）XY具有介于0和约1-4V之间的氧化电位; 和2）XY的氧化形式经历键断裂反应以得到基团X.和离去片段Y.在本发明的一个优选实施方案中，基团X的氧化势为-0.7V。
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公开(公告)号：US4661429A
公开(公告)日：1987-04-28
申请号：US856543
申请日：1986-04-28
申请人： Michel F. Molaire , Samir Y. Farid
发明人： Michel F. Molaire , Samir Y. Farid
CPC分类号： G03G5/0618 , G03G5/0612 , G03G5/062 , G03G5/0629 , G03G5/0638 , G03G5/064 , G03G5/071
摘要： A photoelectrographic element comprising a conductive layer in electrical contact with an acid photogenerating layer which (a) is free of photopolymerizable materials and (b) comprises an electrically insulating binder and an acid photogenerator is disclosed. A method for forming images with the element is also disclosed.
摘要翻译： 一种光电元件，包括与酸性光生电子层电接触的导电层，（a）不含可光聚合材料，（b）包含电绝缘粘合剂和酸性光电发生器。 还公开了用该元件形成图像的方法。
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16.发明授权Photopolymerization co-initiator compositions comprising amine-substituted ketocoumarins and certain acetic acid derivative activators 失效包含胺取代的酮香豆素和某些乙酸衍生物活化剂的光聚合共引发剂组合物
公开(公告)号：US4278751A
公开(公告)日：1981-07-14
申请号：US95171
申请日：1979-11-16
CPC分类号： C08F2/50 , G03F7/031 , Y10S430/116 , Y10S430/12 , Y10S430/121 , Y10S430/124
摘要： A co-initiator for use in an improved photopolymerization composition, element and method is disclosed. The photopolymerizaton composition comprises an addition-polymerizable compound containing ethylenic unsaturation and the co-initiator which includes a photopolymerization activator and an amine-substituted ketocoumarin sensitizer having an absorption maximum between about 350 and about 550 nm; said activator having the structure ##STR1## wherein Q.sup.1 and Q.sup.2 are each independently hydrogen; alkyl, thioalkyl or alkoxy containing from 1 to about 5 carbon atoms; aryl or aryloxy or benzoyloxy containing from about 6 to 10 carbon atoms; hydroxy; or halogen; or together Q.sup.1 or Q.sup.2 are the necessary atoms to complete a fused heterocyclic or aromatic ring containing from about 4 to 6 ring atoms; and Q.sup.3 is hydrogen or alkyl containing from 1 to about 5 carbon atoms.
摘要翻译： 公开了用于改进的光聚合组合物，元素和方法的共引发剂。 光聚合组合物包含含有烯属不饱和度的加成聚合化合物和包含光聚合活化剂的共引发剂和吸收最大值在约350至约550nm之间的胺取代的酮香豆素敏化剂; 所述活化剂具有以下结构：其中Q1和Q2各自独立地为氢; 烷基，硫代烷基或含有1至约5个碳原子的烷氧基; 含有约6至10个碳原子的芳基或芳氧基或苯甲酰氧基; 羟基; 或卤素; 或者Q1或Q2一起是完成含有约4至6个环原子的稠合杂环或芳环的必要原子; 并且Q3是氢或含有1至约5个碳原子的烷基。
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公开(公告)号：US06436624B2
公开(公告)日：2002-08-20
申请号：US09729330
申请日：2000-12-04
IPC分类号： G03C110
摘要： A method for reducing dye stain of an exposed photographic element, said element comprising a support having thereon at least one image-forming layer containing a photobleachable dye, the method comprising processing the element, and exposing the processed element, in presence of a N-oxyazinium, to radiation that can be absorbed either by the photobleachable dye or by the N-oxyazinium.
摘要翻译： 一种用于减少曝光的照相元件染色污染的方法，所述元件包括其上具有至少一个包含可光漂白染料的图像形成层的支撑体，该方法包括处理该元件，并在N- 可以通过光漂白染料或N-氧嗪鎓吸收的辐射。
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18.发明授权Silver halide light sensitive emulsion layer having enhanced photographic sensitivity 失效具有增强的照相感光度的卤化银感光乳剂层
公开(公告)号：US06010841A
公开(公告)日：2000-01-04
申请号：US739911
申请日：1996-10-30
申请人： Samir Y. Farid , Jerome R. Lenhard , Chin H. Chen , Annabel A. Muenter , Ian R. Gould , Stephen A. Godleski , Paul A. Zielinski
发明人： Samir Y. Farid , Jerome R. Lenhard , Chin H. Chen , Annabel A. Muenter , Ian R. Gould , Stephen A. Godleski , Paul A. Zielinski
CPC分类号： C09B23/04 , G03C1/16 , G03C2200/24
摘要： A photographic element comprises at least one silver halide emulsion layer in which the silver halide is sensitized with a compound of formulaZ-(L-XY).sub.kwherein:Z is a light absorbing group;L is a linking group containing a least one C, N, S, or O atom; andk is 1 or 2; andXY represents a fragmentable electron donor moiety wherein:1) XY has a an oxidation potential between 0 and about 1.4 V;2) X is an electron donor group;3) Y is a leaving group other than hydrogen; and4) the oxidized form of XY undergoes a bond cleavage reaction to give the radical X.sup..cndot. and the leaving fragment Y.In a preferred embodiment the radical X.sup..cndot. has an oxidation potential of .ltoreq.-0.7 V.
摘要翻译： 照相元件包括至少一个卤化银乳剂层，其中卤化银与式Z-（L-XY）k化合物敏化，其中：Z是光吸收基团; L是含有至少一个C，N，S或O原子的连接基团; k为1或2; 并且XY表示可裂解的电子供体部分，其中：1）XY具有在0和约1.4V之间的氧化电位; 2）X是电子给体基团; 3）Y是氢以外的离去基团; 和4）XY的氧化形式经历键断裂反应，得到基团X.和离去片段Y.在优选的实施方案中，基团X.具有
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公开(公告)号：US4366228A
公开(公告)日：1982-12-28
申请号：US262675
申请日：1981-05-11
CPC分类号： G03F7/031 , C08F2/50 , Y10S430/114 , Y10S430/117 , Y10S430/121
摘要： A photopolymerizable composition, element and method of photopolymerizing the composition or element are disclosed wherein the composition comprises an addition polymerizable compound containing ethylenic unsaturation and a co-initiator including a photopolymerization activator and photosensitizer.In one aspect of the invention, the photosensitizer is selected to be a coumarin having an absorption maximum between about 250 and about 550 nm, and a ##STR1## substituent in the 3-position wherein R.sup.1 is alkyl or alkenyl having 1-12 carbon atoms, or a carboxylic or heterocyclic group having 5-20 nuclear carbon and hetero atoms, the coumarin and the activator being present in an amount sufficient to provide, when the compound is coated, dried and exposed to a medium-pressure mercury light source, a speed which is at least about one-fifth that of the same composition coated, dried and exposed identically except with a co-initiator consisting of Michler's ketone and benzophenone.In another aspect of the invention, the activator is selected to have the structure: ##STR2## wherein: J is --O--, --S-- or a carbon-to-carbon bond;J.sup.1, J.sup.2, and J.sup.3 are each independently hydrogen; alkyl, alkoxy, or alkylthio having from 1 to 5 carbon atoms; aryloxy having from 6 to 10 carbon atoms; halogen; or any two of J.sup.1, J.sup.2, and J.sup.3 taken together comprise the atoms necessary to complete a 5- or 6-membered fused heterocyclic or aromatic ring; andZ is the number of atoms necessary to complete a heterocyclic or aromatic ring of from 4 to 6 ring atoms. This application is a division of Ser. No. 184,606 filed 9/5/80, now U.S. Pat. No. 4,289,844, which is a continuation-in-part of Ser. No. 49,661, filed 6/18/79, now abandoned.
摘要翻译： 公开了可光聚合的组合物，组合物或元素的光聚合组分，元素和方法，其中组合物包含含有烯属不饱和的加成聚合化合物和包含光聚合活化剂和光敏剂的共引发剂。 在本发明的一个方面，光敏剂选择为吸收最大值在约250至约550nm之间的香豆素，以及3-位上的取代基，其中R1是具有1-12个碳原子的烷基或烯基 或具有5-20个核碳原子和杂原子的羧基或杂环基团时，香豆素和活化剂的存在量足以提供当化合物被涂覆干燥并暴露于中压水银光源时， 除了使用由米ler酮和二苯甲酮组成的共引发剂之外，相同组合物的涂覆，干燥和曝光相同的速度至少约为五分之一。 在本发明的另一方面，活化剂被选择为具有以下结构：其中：J为-O-，-S-或碳 - 碳键; J1，J2和J3各自独立地为氢; 具有1至5个碳原子的烷基，烷氧基或烷硫基; 具有6至10个碳原子的芳氧基; 卤素; 或J1，J2和J3中的任何两个一起包含完成5或6元稠合杂环或芳环所必需的原子; Z是完成4至6个环原子的杂环或芳环所必需的原子数。 这个应用程序是Ser的一个部门。 现在的美国专利申请第184,606号。 第4,289,844号是Ser的继续部分。 第49,661号，于6/18/79提交，现已放弃。
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20.发明授权Photoreactive compositions comprising a light sensitive compound and another compound with reactive site 失效包含光敏化合物和具有反应性位点的另一种化合物的光反应性组合物
公开(公告)号：US4302527A
公开(公告)日：1981-11-24
申请号：US180211
申请日：1980-08-21
CPC分类号： G03F7/031 , Y10S430/114 , Y10S430/115 , Y10S430/116 , Y10S430/117
摘要： There are disclosed light-sensitive compounds and a composition comprising (a) such compounds and (b) a compound having at least one reactive site capable of stepwise photo-reaction with the light-sensitive compounds. The light-sensitive compounds have the structural formula, ##STR1## wherein Z.sup.1 and Z.sup.2 are each independently the number of non-metallic atoms necessary to complete 1, 2, 3, or 4 unsaturated carbocyclic or heterocyclic rings of from 6 to 18 nuclear atoms;Z.sup.3 is either a carbon-to-carbon bond or vinylene;and X is a linking group.The composition can be applied to a variety of supports and photoreacted by exposure to activating radiation.
摘要翻译： 公开了光敏化合物和包含（a）这样的化合物的组合物和（b）具有至少一个能够与光敏化合物进行逐步光反应的反应位点的化合物。 光敏化合物具有结构式，其中Z1和Z2各自独立地是完成1,2,3或4个6至18个核原子的不饱和碳环或杂环所必需的非金属原子的数目 ; Z3是碳 - 碳键或亚乙烯基; X是连接基团。 组合物可以应用于多种载体并通过暴露于活化辐射而被光反应。
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