公开(公告)号：US20090134360A1

公开(公告)日：2009-05-28

申请号：US12092316

申请日：2006-10-30

申请人： Satoshi Komatsu ,  Junji Kawai ,  Toshihiro Ohtsuki ,  Takanobu Yamamoto ,  Ryoichiro Takahashi ,  Kaoru Fukuda ,  Hiroshi Shinkai

发明人： Satoshi Komatsu ,  Junji Kawai ,  Toshihiro Ohtsuki ,  Takanobu Yamamoto ,  Ryoichiro Takahashi ,  Kaoru Fukuda ,  Hiroshi Shinkai

IPC分类号： H01B1/12

CPC分类号： C08G65/405 ,  C08G65/4006 ,  C08G65/4025 ,  C08G65/4037 ,  C08G65/4056 ,  C08G75/23 ,  C08L27/12 ,  C09D133/16 ,  H01M4/8605 ,  H01M4/8652 ,  H01M8/1004 ,  H01M2300/0082 ,  C08L2666/06

摘要： An object of the invention is to provide an electrode catalyst layer of a solid polymer electrolyte membrane-electrode assembly expressing excellent balance between water retention and drainage in an electrode, good power generation performance under any of low humidity and high humidity conditions, and also excellent durability of power generation.The electrode catalyst layer of the invention contains catalyst particles, an ion exchange resin and a water repellent agent, wherein said water repellent agent contains at least one kind selected from the group consisting of (A) a fluorine-containing copolymer having a structure unit derived from a polyfluoroalkyl-containing (meth)acrylate and (B) a fluorine-containing copolymer having a specific structure unit derived from a fluorine-containing olefin monomer and a specific structure unit derived from a vinyl ether monomer.

摘要翻译： 本发明的目的是提供一种固体高分子电解质膜 - 电极组件的电极催化剂层，其表现出在电极中的保水性和排水性之间的平衡，在任何低湿度和高湿度条件下都具有良好的发电性能，并且还优异 发电耐久性。 本发明的电极催化剂层含有催化剂粒子，离子交换树脂和防水剂，其中所述防水剂含有选自（A）含有结构单元的含氟共聚物中的至少一种 来自含氟烷基的（甲基）丙烯酸酯和（B）具有来自含氟烯烃单体的特定结构单元的含氟共聚物和衍生自乙烯基醚单体的特定结构单元。

公开(公告)号：US07022426B2

公开(公告)日：2006-04-04

申请号：US09956828

申请日：2001-09-21

申请人： Kaoru Fukuda ,  Keisuke Andou ,  Nobuhiro Saito ,  Masaaki Nanaumi ,  Junji Matsuo

发明人： Kaoru Fukuda ,  Keisuke Andou ,  Nobuhiro Saito ,  Masaaki Nanaumi ,  Junji Matsuo

IPC分类号： H01M8/10 ,  H01M4/96

CPC分类号： H01M4/8605 ,  H01M4/8668 ,  H01M4/8673 ,  H01M4/9083 ,  H01M8/1004

摘要： A solid polymer fuel cell includes an electrolyte membrane having a polymer ion-exchange component, and an air electrode and a fuel electrode between which the electrolyte membrane is sandwiched. Each of the air electrode and the fuel electrode can be formed of a polymer ion-exchange component and a plurality of catalyst particles including a catalyst metal carried on surfaces of carbon black particles, and includes no third component. When a moistening for maintaining the electrolyte membrane in a wet state is carried out from both of the side of the air electrode and the side of the fuel electrode, the carbon black particles have a water-repellent property such that an amount A of water adsorbed under a saturated steam pressure at 60° C. is equal to or smaller than 80 cc/g, and a ratio Wp/Wc of a weight Wp of polymer ion-exchange component incorporated to a weight Wc of carbon black particles incorporated is set in a range of 0.4≦Wp/Wc≦1.25.

公开(公告)号：US07208242B2

公开(公告)日：2007-04-24

申请号：US10473388

申请日：2002-04-01

申请人： Yoichi Asano ,  Masaaki Nanaumi ,  Hiroshi Sohma ,  Nagayuki Kanaoka ,  Nobuhiro Saito ,  Keisuke Andou ,  Kaoru Fukuda ,  Junji Matsuo

发明人： Yoichi Asano ,  Masaaki Nanaumi ,  Hiroshi Sohma ,  Nagayuki Kanaoka ,  Nobuhiro Saito ,  Keisuke Andou ,  Kaoru Fukuda ,  Junji Matsuo

IPC分类号： H01M8/10

CPC分类号： H01M4/8605 ,  H01M8/1004 ,  H01M8/1023 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/1032 ,  H01M8/1039 ,  H01M2008/1095 ,  H01M2300/0082 ,  Y02P70/56

摘要： The present invention provides a polymer electrolyte fuel cell, which is inexpensive and has an excellent efficiency of generating electric power, by using a material alternative to a perfluoroalkylene sulfonic acid polymer. The polymer electrolyte fuel cell comprises a pair of electrodes (2, 3) consisting of an oxygen electrode (2) and a fuel electrode (3) both having a catalyst layer (5) containing a catalyst and an ion conducting material; and a polymer electrolyte membrane (1) sandwiched between the two catalyst layers (5) of the both electrodes (2, 3). The above ion conducting material contained in the above polymer electrolyte membrane (1) or in the catalyst (5) layer of at least one of the above electrodes (2, 3) comprises a sulfonated polyarylene having sulfonic acid side-chain groups.

摘要翻译： 本发明通过使用替代全氟亚烷基磺酸聚合物的材料，提供廉价且具有优异的发电效率的聚合物电解质燃料电池。 聚合物电解质燃料电池包括由氧电极（2）和燃料电极（3）组成的一对电极（2,3），两者均具有含催化剂的催化剂层（5）和离子传导材料; 和夹在两个电极（2,3）的两个催化剂层（5）之间的聚合物电解质膜（1）。 上述高分子电解质膜（1）中含有的上述离子导电材料或上述电极（2,3）中的至少一个的催化剂（5）层包含具有磺酸侧链基团的磺化聚亚芳基。

公开(公告)号：US07745037B2

公开(公告)日：2010-06-29

申请号：US11265463

申请日：2005-11-01

申请人： Junji Matsuo ,  Kaoru Fukuda

发明人： Junji Matsuo ,  Kaoru Fukuda

IPC分类号： H01M4/96

CPC分类号： H01M8/1004 ,  H01M4/625 ,  H01M4/8657 ,  H01M4/881 ,  H01M4/921 ,  H01M4/926 ,  H01M2004/021

摘要： A membrane electrode assembly for a solid polymer electrolyte fuel cell includes an anode electrode, a cathode electrode, and a polymer electrolyte membrane sandwiched by the electrodes, the catalyst layer of the cathode electrode containing a catalyst supporting particle in which a precious metal is supported on heat-treated carbon black or activated carbon, an ion conductive material, and a crystalline carbon fiber. Heat treatment is preferably applied at 2,500 to 3,000° C. (degrees Celsius).The membrane electrode assembly provides superior power generation performance.

摘要翻译： 固体聚合物电解质燃料电池的膜电极组件包括阳极电极，阴极电极和夹在电极之间的聚合物电解质膜，阴极电极的催化剂层含有载持贵金属的催化剂载体颗粒 热处理炭黑或活性炭，离子导电材料和结晶碳纤维。 热处理优选在2500至3000℃（摄氏度）下进行。 膜电极组件提供优异的发电性能。

公开(公告)号：US20060093893A1

公开(公告)日：2006-05-04

申请号：US11265463

申请日：2005-11-01

申请人： Junji Matsuo ,  Kaoru Fukuda

发明人： Junji Matsuo ,  Kaoru Fukuda

IPC分类号： H01M4/96 ,  H01M4/94 ,  H01M8/10 ,  H01M4/92

CPC分类号： H01M8/1004 ,  H01M4/625 ,  H01M4/8657 ,  H01M4/881 ,  H01M4/921 ,  H01M4/926 ,  H01M2004/021

摘要： A membrane electrode assembly for a solid polymer electrolyte fuel cell includes an anode electrode, a cathode electrode, and a polymer electrolyte membrane sandwiched by the electrodes, the catalyst layer of the cathode electrode containing a catalyst supporting particle in which a precious metal is supported on heat-treated carbon black or activated carbon, an ion conductive material, and a crystalline carbon fiber. Heat treatment is preferably applied at 2,500 to 3,000° C. (degrees Celsius). The membrane electrode assembly provides superior power generation performance.

摘要翻译： 固体聚合物电解质燃料电池的膜电极组件包括阳极电极，阴极电极和夹在电极之间的聚合物电解质膜，阴极电极的催化剂层含有载持贵金属的催化剂载体颗粒 热处理炭黑或活性炭，离子导电材料和结晶碳纤维。 热处理优选在2500至3000℃（摄氏度）下进行。 膜电极组件提供优异的发电性能。

公开(公告)号：US06485855B1

公开(公告)日：2002-11-26

申请号：US09598266

申请日：2000-06-21

申请人： Kaoru Fukuda ,  Kazuhide Terada ,  Nobuhiro Saito

发明人： Kaoru Fukuda ,  Kazuhide Terada ,  Nobuhiro Saito

IPC分类号： H01M810

CPC分类号： H01M8/1004 ,  H01M2300/0082 ,  Y02P70/56 ,  Y10T29/49115

摘要： An active solid polymer electrolyte membrane in a solid polymer type fuel cell comprises a solid polymer electrolyte membrane and a plurality of precious metal catalyst particles supported on the surfaces of the aforementioned solid polymer electrolyte membrane by ion exchange and distributed uniformly over the surfaces thereof. In accordance with the use of this active solid polymer electrolyte membrane the ability to generate power can be enhanced.

摘要翻译： 固体聚合物型燃料电池中的活性固体聚合物电解质膜包括固体聚合物电解质膜和通过离子交换在其表面上均匀分布的在上述固体高分子电解质膜的表面上负载的多种贵金属催化剂颗粒。 根据这种活性固体聚合物电解质膜的使用，可以提高发电的能力。

公开(公告)号：US08120495B2

公开(公告)日：2012-02-21

申请号：US12197509

申请日：2008-08-25

申请人： Kaoru Fukuda ,  Yoshinori Kimura ,  Tsuyoshi Matsueda ,  Hitoshi Nishino ,  Shiroh Sakamoto

发明人： Kaoru Fukuda ,  Yoshinori Kimura ,  Tsuyoshi Matsueda ,  Hitoshi Nishino ,  Shiroh Sakamoto

IPC分类号： G08B13/14

CPC分类号： H01Q1/2216 ,  H01Q7/00 ,  H04Q2213/13095

摘要： An RFID system according to the present invention includes an RFID antenna system including: a first antenna that can communicate with an external reader/writer; an antenna selector for connecting with the first antenna; and a plurality of second antennas that can connect with the first antenna in order via the antenna selector, each of the second antennas can communicate with an IC tag that is attached to an article placed in a region defined by the second antenna.

摘要翻译： 根据本发明的RFID系统包括RFID天线系统，其包括：可与外部读/写器通信的第一天线; 用于与第一天线连接的天线选择器; 以及可以经由天线选择器按顺序与第一天线连接的多个第二天线，每个第二天线可以与附接到放置在由第二天线限定的区域中的物品的IC标签通信。

公开(公告)号：US20090072949A1

公开(公告)日：2009-03-19

申请号：US12197509

申请日：2008-08-25

申请人： Kaoru Fukuda ,  Yoshinori Kimura ,  Tsuyoshi Matsueda ,  Hitoshi Nishino ,  Shiroh Sakamoto

发明人： Kaoru Fukuda ,  Yoshinori Kimura ,  Tsuyoshi Matsueda ,  Hitoshi Nishino ,  Shiroh Sakamoto

IPC分类号： H04Q5/22 ,  H01Q21/00

CPC分类号： H01Q1/2216 ,  H01Q7/00 ,  H04Q2213/13095

摘要： An RFID system according to the present invention includes an RFID antenna system including: a first antenna that can communicate with an external reader/writer; an antenna selector for connecting with the first antenna; and a plurality of second antennas that can connect with the first antenna in order via the antenna selector, each of the second antennas can communicate with an IC tag that is attached to an article placed in a region defined by the second antenna.

摘要翻译： 根据本发明的RFID系统包括RFID天线系统，其包括：可与外部读/写器通信的第一天线; 用于与第一天线连接的天线选择器; 以及可以经由天线选择器按顺序与第一天线连接的多个第二天线，每个第二天线可以与附接到放置在由第二天线限定的区域中的物品的IC标签通信。

公开(公告)号：US06847518B2

公开(公告)日：2005-01-25

申请号：US10725331

申请日：2003-12-02

申请人： Kaoru Fukuda ,  Masaki Tani ,  Hayato Kaji ,  Shigeru Inai ,  Takeshi Muro ,  Shinya Watanabe ,  Tomoyuki Tada ,  Masahiko Inoue

发明人： Kaoru Fukuda ,  Masaki Tani ,  Hayato Kaji ,  Shigeru Inai ,  Takeshi Muro ,  Shinya Watanabe ,  Tomoyuki Tada ,  Masahiko Inoue

IPC分类号： H01M4/90 ,  H01G9/02 ,  H01G9/04 ,  H01M4/86 ,  H01M4/88 ,  H01M4/92 ,  H01M4/96 ,  H01M8/10

CPC分类号： H01M4/926 ,  H01M4/8605 ,  H01M4/921 ,  H01M8/1004

摘要： A membrane electrode assembly for a polymer electrolyte fuel cell has a polymer electrolyte membrane, an anode, and a cathode having a catalytic layer and a diffusion layer. The alloy catalyst contains ruthenium in the anode diffusion layer. The assembly has less loss of efficiency, particularly when operated at high potentials.

摘要翻译： 用于聚合物电解质燃料电池的膜电极组件具有聚合物电解质膜，阳极和具有催化层和扩散层的阴极。 合金催化剂在阳极扩散层中含有钌。 该组件的效率损失较小，特别是在高电位下运行时。

公开(公告)号：US20050227138A1

公开(公告)日：2005-10-13

申请号：US11098425

申请日：2005-04-05

申请人： Kaoru Fukuda ,  Taku Eguchi ,  Makoto Tsuji

发明人： Kaoru Fukuda ,  Taku Eguchi ,  Makoto Tsuji

IPC分类号： H01M4/86 ,  B01D71/52 ,  B01D71/82 ,  H01M4/92 ,  H01M4/94 ,  H01M4/96 ,  H01M8/02 ,  H01M8/04 ,  H01M8/10

CPC分类号： B01D71/52 ,  B01D71/82 ,  H01M4/921 ,  H01M4/926 ,  H01M8/0234 ,  H01M8/0239 ,  H01M8/0243 ,  H01M8/04291 ,  H01M8/1004 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/1039 ,  H01M2300/0082

摘要： A polymer electrolyte fuel cell consists of plural units, and the unit has an anode side separator, an anode diffusion layer, an anode catalytic layer, polymer electrolyte membrane, a cathode catalytic layer, a cathode diffusion layer, and a cathode side separator. The cathode catalytic layer further includes a catalyst in which platinum or platinum alloy is supported on a carbon supporting body having an average lattice space d002 of [002] surface of 0.338 to 0.355 nm and specific surface area of the supporting body of 80 to 250 m2/g, electrolyte containing ion exchange resin, and vapor grown carbon fiber. Furthermore, a water holding layer containing ion exchange resin, carbon particles, and vapor grown carbon fiber is arranged at an interface of the cathode diffusion layer and the cathode catalytic layer.

摘要翻译： 聚合物电解质燃料电池由多个单元构成，该单元具有阳极侧隔板，阳极扩散层，阳极催化剂层，高分子电解质膜，阴极催化剂层，阴极扩散层和阴极侧隔板。 阴极催化剂层还包括铂或铂合金负载在表面平均晶格空间d002为0.338〜0.355nm的碳载体上，催化剂的比表面积为80〜250μm的催化剂 含电解质的离子交换树脂和气相生长碳纤维。 此外，在阴极扩散层和阴极催化剂层的界面配置含有离子交换树脂，碳粒子，气相生长碳纤维的保水层。