公开(公告)号：US06214787B1

公开(公告)日：2001-04-10

申请号：US09142555

申请日：1998-09-11

申请人： Shu Yamaguchi ,  Shigeru Tamura ,  Futoshi Teranishi ,  Noriaki Ushio ,  Masaki Tsumadori ,  Hiroyuki Yamashita

发明人： Shu Yamaguchi ,  Shigeru Tamura ,  Futoshi Teranishi ,  Noriaki Ushio ,  Masaki Tsumadori ,  Hiroyuki Yamashita

IPC分类号： C11D308

CPC分类号： C11D3/046 ,  C11D3/08 ,  C11D3/1273 ,  C11D17/065

摘要： The granular detergent composition for clothes washing including a surfactant, a metal ion capturing agent, a crystalline alkali metal silicate, and an acidic ingredient, wherein the granular detergent composition includes at least two different granules: a first granule containing the crystalline alkali metal silicate, and a second granule, which is an acidic granule, containing the acidic ingredient. In the granular detergent composition, the crystalline alkali metal silicate and the acidic ingredient are being present in different granules, and the granular detergent composition shows alkaline property in distilled water at 25° C. and has a bulk density of 650 g/L or more. Since each of an acidic ingredient and a crystalline alkali metal silicate is included in a different granule, the initial rise in the pH at initial washing can be adjusted, so that a further improved detergency against the sebum dirt stains is exhibited.

摘要翻译： 包含表面活性剂，金属离子捕获剂，结晶性碱金属硅酸盐和酸性成分的衣物用洗涤剂组合物，其中所述颗粒状洗涤剂组合物包含至少两种不同的颗粒：含有结晶性碱金属硅酸盐的第一颗粒， 和含有酸性成分的酸性颗粒的第二颗粒。 在颗粒状洗涤剂组合物中，结晶性碱金属硅酸盐和酸性成分存在于不同的颗粒中，粒状洗涤剂组合物在25℃的蒸馏水中显示碱性，堆积密度为650g / L以上 由于酸性成分和结晶性碱金属硅酸盐中的每一种都包含在不同的颗粒中，因此可以调节初始洗涤时的pH的初始上升，从而显示出对皮脂污垢的去污力的进一步改善。

公开(公告)号：US6159919A

公开(公告)日：2000-12-12

申请号：US633698

申请日：1996-04-19

申请人： Shu Yamaguchi ,  Nobuyosi Yamaguchi ,  Muneo Aoyagi ,  Noriaki Ushio ,  Shigeru Tamura ,  Masaki Tsumadori

发明人： Shu Yamaguchi ,  Nobuyosi Yamaguchi ,  Muneo Aoyagi ,  Noriaki Ushio ,  Shigeru Tamura ,  Masaki Tsumadori

IPC分类号： C11D3/12 ,  C11D3/39 ,  C11D3/395

CPC分类号： C11D3/3907 ,  C11D3/1246 ,  C11D3/3942

摘要： The bleaching detergent composition in a form of granules or powders containing an organic peracid precursor which produces an organic peracid upon reaction with hydrogen peroxide in water, the organic peracid having an alkyl group with 7 to 19 carbon atoms, and a hydrogen peroxide releasing material, wherein the bleaching detergent composition comprises the following components a) to c): a) one or more surfactants; b) one or more crystalline alkali metal silicates; and c) one or more agents for capturing metal ions other than the crystalline alkali metal silicates b), wherein a total amount of the above a), b), and c) components in the bleaching detergent composition occupies from 70 to 99% by weight, and wherein the weight ratio of component b) to component a) is b/a=90/10 to 45/55, and the weight ratio of component b) to component c) is b/c=7/93 to 75/25, and wherein the weight ratio of the organic peracid precursor to nonionic surfactants used as component a) is from 10/90 to 70/30.

摘要翻译： 漂白洗涤剂组合物为颗粒或粉末形式，其含有有机过酸前体，其与水中的过氧化氢反应产生有机过酸，具有7至19个碳原子的烷基的有机过酸和过氧化氢释放物质， 其中所述漂白洗涤剂组合物包含以下组分a）至c）：a）一种或多种表面活性剂; b）一种或多种结晶碱金属硅酸盐; 和c）一种或多种用于捕获除结晶性碱金属硅酸盐b）之外的金属离子的试剂，其中漂白洗涤剂组合物中上述a），b）和c）组分的总量占70-99％ 成分b）与成分a）的重量比为b / a = 90/10〜45/55，成分b）与成分c）的重量比为b / c = 7/93〜75 / 25，其中有机过酸前体与用作组分a）的非离子表面活性剂的重量比为10/90至70/30。

公开(公告)号：US06521585B1

公开(公告)日：2003-02-18

申请号：US09068476

申请日：1998-05-06

申请人： Hiroyuki Yamashita ,  Shu Yamaguchi ,  Teruo Kubota ,  Katsuhiko Kasai ,  Shigeru Tamura ,  Masaki Tsumadori

发明人： Hiroyuki Yamashita ,  Shu Yamaguchi ,  Teruo Kubota ,  Katsuhiko Kasai ,  Shigeru Tamura ,  Masaki Tsumadori

IPC分类号： C11D1100

CPC分类号： C11D3/08 ,  C11D1/04 ,  C11D1/143 ,  C11D1/146 ,  C11D1/29 ,  C11D1/72 ,  C11D1/83 ,  C11D3/1273 ,  C11D3/128 ,  C11D11/0082 ,  C11D11/04 ,  C11D17/065

摘要： Detergent formulations incorporating crystalline alkali metal silicate granules provide enhanced performance in removing sebum dirt stains at low dosages of detergent in the wash. The detergent formulations are prepared by combining an alkali metal silicate having a high pH value with a nonionic surfactant and an acid precursor of an anionic surfactant capable of having a lamellar orientation. The formulation is granulated by tumbling in an agitating mixer while increasing the bulk density at elevated temperatures to yield alkali metal silicate granules having a bulk density of from 0.6 to 1.2 g/ml.

摘要翻译： 掺入结晶碱金属硅酸盐颗粒的洗涤剂配方提供了在洗涤剂中低剂量洗涤剂中除去皮脂污垢的增强性能。 洗涤剂配方通过将具有高pH值的碱金属硅酸盐与非离子表面活性剂和能够具有层状取向性的阴离子表面活性剂的酸前体组合来制备。 通过在搅拌混合器中翻转而将制剂造粒，同时在升高的温度下增加堆积密度，得到体积密度为0.6至1.2g / ml的碱金属硅酸盐颗粒。

公开(公告)号：US06284722B1

公开(公告)日：2001-09-04

申请号：US09142748

申请日：1998-09-15

申请人： Shu Yamaguchi ,  Hitoshi Tanimoto ,  Masaki Tsumadori ,  Hiroyuki Yamashita

发明人： Shu Yamaguchi ,  Hitoshi Tanimoto ,  Masaki Tsumadori ,  Hiroyuki Yamashita

IPC分类号： C11D308

CPC分类号： C11D3/08 ,  C11D3/1273 ,  C11D3/3761 ,  C11D17/065

摘要： The present invention is targeted to obtain a high-density granular detergent composition for clothes washing having sufficient detergency even when the amount of dosage is small without lowering its detergency even after long-term storage by blending a non-soap anionic surfactant and a crystalline alkali metal silicate in a state of non-contact as much as possible. The high-density granular detergent composition for clothes washing, the granular detergent composition having a bulk density of from 0.7 to 1.2 g/cm3, including (A) a non-soap anionic surfactant; (B) a crystalline alkali metal silicate; and (C) a metal ion capturing agent other than Component (B). In the above detergent composition, Component (A) is added in an amount of from 10 to 50% by weight, and a total amount of Component (B) and Component (C) is from 30 to 80% by weight, and a weight ratio of Component (B) to Component (C) is (B)/(C)=1/15 to 5/1, and at least a part of (B) the crystalline alkali metal silicate is blended in builder granules, the builder granules including the crystalline alkali metal silicate, a binder and optionally an aluminosilicate. Further, (A) the non-soap anionic surfactant is contained in the builder granules in an amount of less than 10% by weight.

摘要翻译： 本发明的目标是获得即使即使在长时间保存后不掺入非皂性阴离子表面活性剂和结晶性碱也能减少洗涤力的情况下，即使使用量少的洗涤剂也可获得高洗涤性高密度粒状洗涤剂组合物 金属硅酸盐处于非接触状态。 用于洗衣的高密度颗粒洗涤剂组合物，其中堆积密度为0.7-1.2g / cm3的粒状洗涤剂组合物，包括（A）非皂阴离子表面活性剂; （B）结晶性碱金属硅酸盐; 和（C）除了组分（B）以外的金属离子捕获剂。 在上述洗涤剂组合物中，组分（A）的添加量为10至50重量％，组分（B）和组分（C）的总量为30至80重量％，重量 组分（B）与组分（C）的比例为（B）/（C）= 1/15至5/1，并且至少一部分（B）结晶性碱金属硅酸盐掺混在助洗剂颗粒中， 颗粒包括结晶的碱金属硅酸盐，粘合剂和任选的铝硅酸盐。 此外，（A）非皂性阴离子表面活性剂的含量小于10重量％。

公开(公告)号：US5821207A

公开(公告)日：1998-10-13

申请号：US750489

申请日：1996-12-11

申请人： Hiroyuki Kanai ,  Mikio Sakaguchi ,  Shu Yamaguchi

发明人： Hiroyuki Kanai ,  Mikio Sakaguchi ,  Shu Yamaguchi

IPC分类号： C01B33/38 ,  C01B39/02 ,  C11D3/12 ,  C11D7/20 ,  C11D11/00 ,  C11D10/02 ,  C11D17/06

CPC分类号： C11D11/0082 ,  C11D3/1273 ,  C11D3/128

摘要： The method for producing a fine solid builder particle includes the steps of suspending a solid builder in a dispersion medium containing 20 to 100% by weight of a surfactant, and carrying out wet grinding of the solid builder. The builder composition containing the fine solid builder particle is obtainable by the above method. The detergent composition containing the fine solid builder particle is obtainable by the method. The method for producing a detergent composition includes the steps of carrying out wet grinding of a solid builder using a dispersion medium containing a surfactant to give a mixture of a fine solid builder particle and the surfactant, and further adding the mixture to a composition for a detergent.

摘要翻译： PCT No.PCT / JP95 / 01105 Sec。 371日期1996年12月11日第 102（e）日期1996年12月11日PCT提交1995年6月5日PCT公布。 WO95 / 34623 PCT出版物 1995年12月21日，生产微细固体助洗剂颗粒的方法包括以下步骤：将固体助洗剂悬浮在含有20-100重量％表面活性剂的分散介质中，并进行固体助洗剂的湿磨。 包含微细固体助洗剂颗粒的助洗剂组合物可通过上述方法获得。 含有微细固体助洗剂颗粒的洗涤剂组合物可通过该方法获得。 洗涤剂组合物的制造方法包括以下步骤：使用含有表面活性剂的分散介质对固体助洗剂进行湿磨，得到微细固体助洗剂颗粒和表面活性剂的混合物，并进一步将混合物加入到 洗涤剂。

公开(公告)号：US5618783A

公开(公告)日：1997-04-08

申请号：US395994

申请日：1995-02-28

申请人： Mikio Sakaguchi ,  Ichiro Sakamoto ,  Ryuichi Akagi ,  Shu Yamaguchi ,  Masaki Tsumadori

发明人： Mikio Sakaguchi ,  Ichiro Sakamoto ,  Ryuichi Akagi ,  Shu Yamaguchi ,  Masaki Tsumadori

IPC分类号： B01J39/14 ,  C01B33/36 ,  C11D3/12 ,  C11D7/02 ,  C11D7/14

CPC分类号： B01J39/14 ,  C01B33/36 ,  C11D3/1246

摘要： The synthesized inorganic crystalline ion exchange material has a composition represented by the following general formula in an anhydride form:aX.sub.2 O.bSiO.sub.2.cX'O,wherein X represents Na and K; X' represents Ca, or Ca and Mg; b/a is 1.4 to 2.1; c/a is 0.001 to 0.35; K/Na in X.sub.2 O is 0.09 to 1.11; Mg/Ca in X'O is 0 to 100; and K.sub.2 O/SiO.sub.2 is 0.06 to 0.25. The synthesized inorganic crystalline ion exchange material exhibits main shift peaks at least at 1080.+-.6 cm.sup.-1 in Raman scattering spectra in the range of from 900 to 1200 cm.sup.-1. The inorganic ion exchange material of the present invention is excellent in cationic exchange capacity, cationic exchange speed, and anti-solubility, making it useful to be used for a water softener and an alkalinity adjusting agent in detergents.

摘要翻译： 合成的无机结晶离子交换材料具有由以下通式表示的组成，其为酸酐形式：aX2O.bSiO2.cX'O，其中X表示Na和K; X'表示Ca或Ca和Mg; b / a为1.4〜2.1; c / a为0.001〜0.35; X2O中的K / Na为0.09〜1.11; X'O中的Mg / Ca为0〜100; K2O / SiO2为0.06〜0.25。 合成的无机结晶离子交换材料在900-1200cm -1范围内的拉曼散射光谱中至少在1080 +/- 6cm -1处显示出主要的偏移峰。 本发明的无机离子交换材料的阳离子交换能力，阳离子交换速度，抗溶解性优异，可用于洗涤剂中的软水剂和碱性调节剂。

公开(公告)号：US06734156B1

公开(公告)日：2004-05-11

申请号：US09762948

申请日：2001-02-14

申请人： Shuji Takana ,  Hitoshi Takaya ,  Hiroki Yamaboshi ,  Yoichi Sugiyama ,  Hiroshi Kitagaito ,  Shu Yamaguchi ,  Hiroyuki Yamashita

发明人： Shuji Takana ,  Hitoshi Takaya ,  Hiroki Yamaboshi ,  Yoichi Sugiyama ,  Hiroshi Kitagaito ,  Shu Yamaguchi ,  Hiroyuki Yamashita

IPC分类号： C11D1100

CPC分类号： C11D3/046 ,  C11D3/10 ,  C11D3/37 ,  C11D11/0082 ,  C11D11/02 ,  C11D17/065

摘要： The present invention relates to particles for supporting a surfactant and a process for preparing the same. Further, the present invention relates to high-density detergent particles using the particles for supporting a surfactant, and a process for preparing the same. According to the present invention, there can be obtained particles for supporting a surfactant which are excellent in the supporting ability (supporting capacity/supporting strength) for the liquid surfactant composition, and particles for supporting a surfactant which are excellent in the absorption properties (supporting rate) for the liquid surfactant composition, by spray-drying a preparation liquid obtainable by a process comprising the steps of preparing a first preparation liquid comprising a solution or slurry comprising a water-soluble polymer and a water-soluble salt; and subjecting the first preparation liquid to a treatment of increasing a number of water-soluble salt particles, thereby preparing a second preparation liquid having an increased number of water-soluble salt particles, as compared to the number of water-soluble salt particles which are present in the first preparation liquid. Further, since the liquid surfactant composition is supported by the particles for supporting a surfactant, detergent particles which are excellent in detergent performance, quality and the like can be efficiently obtained.

摘要翻译： 本发明涉及用于支持表面活性剂的颗粒及其制备方法。 此外，本发明涉及使用用于支撑表面活性剂的颗粒的高密度洗涤剂颗粒及其制备方法。 根据本发明，可以获得支撑液体表面活性剂组合物的支持能力（支撑能力/支撑强度）优异的表面活性剂用颗粒和吸收性优异的支撑表面活性剂的颗粒（支撑 速率），通过喷雾干燥可通过包括以下步骤的方法获得的制备液：制备包含水溶性聚合物和水溶性盐的溶液或浆液的第一制备液; 并且对第一制备液进行处理以增加数量的水溶性盐颗粒，从而制备具有增加数量的水溶性盐颗粒的第二制备液，与水溶性盐颗粒的数量相比， 存在于第一准备液中。 此外，由于液体表面活性剂组合物被用于支撑表面活性剂的颗粒负载，所以可以有效地获得洗涤剂性能，质量等方面优异的洗涤剂颗粒。

公开(公告)号：US06645931B1

公开(公告)日：2003-11-11

申请号：US09594025

申请日：2000-06-15

申请人： Yuhki Yanagisawa ,  Nobuyoshi Yamaguchi ,  Shu Yamaguchi ,  Hitoshi Takaya ,  Hiroyuki Yamashita

发明人： Yuhki Yanagisawa ,  Nobuyoshi Yamaguchi ,  Shu Yamaguchi ,  Hitoshi Takaya ,  Hiroyuki Yamashita

IPC分类号： C11D1700

CPC分类号： C11D3/0052 ,  C11D17/0047 ,  C11D17/065

摘要： A solid-shaped detergent comprising particles for detergent, wherein the particles have a dissolution rate of 90% or more, under conditions where the particles are supplied in water at 5° C.; stirred for 60 seconds under the stirring conditions that 1 g of the particles are supplied to a 1-L beaker having an inner diameter of 105 mm which is charged with 1 L of hard, water having 71.2 mg CaCO3/L, wherein a molar ratio of Ca/Mg is 7/3, and stirred with a stirring bar of 35 mm in length and 8 mm in diameter at a rotational speed of 800 rpm; and filtered with a standard sieve having a sieve-opening of 74 &mgr;m as defined by JIS Z 8801, wherein the dissolution rate of the particles is calculated by the Equation (1): Dissolution Rate (%)=[1−(T/S)]×100 (1), wherein S is a weight (g) of the particles supplied; and T is a dry weight (g) of insoluble remnants of the particles remaining on the sieve when an aqueous solution prepared under the above stirring conditions is filtered with the sieve.

摘要翻译： 一种固体形洗涤剂，其包含用于洗涤剂的颗粒，其中颗粒在5℃的水中供应的条件下，其溶解速率为90％以上。 在搅拌条件下搅拌60秒，将1g的颗粒供给到内径为105mm的1L的烧杯中，该烧杯装入1L的具有71.2mg CaCO 3 / L的硬水，其中摩尔比 的Ca / Mg为7/3，并以800rpm的转速与长35mm，直径8mm的搅拌棒一起搅拌， 用JIS Z 8801定义的筛孔为74μm的标准筛过滤，其中通过式（1）计算颗粒的溶解速率：溶解速率（％）= [1-（T / S ）]×100（1），其中S是供给的颗粒的重量（g） 当用筛子过滤在上述搅拌条件下制备的水溶液时，T是残留在筛上的颗粒的不溶性残留物的干重（g）。

公开(公告)号：US06534474B1

公开(公告)日：2003-03-18

申请号：US09701781

申请日：2000-12-04

申请人： Kyoko Okada ,  Teruo Kubota ,  Hitoshi Takaya ,  Shu Yamaguchi ,  Hiroyuki Yamashita

发明人： Kyoko Okada ,  Teruo Kubota ,  Hitoshi Takaya ,  Shu Yamaguchi ,  Hiroyuki Yamashita

IPC分类号： C11D183

CPC分类号： C11D17/06 ,  C11D1/83 ,  C11D3/3707 ,  C11D10/045

摘要： The surfactant composition of the present invention is a surfactant composition which is capable of being formulated for use in a non-liquid detergent composition, the surfactant composition comprising a) a nonionic surfactant having a melting point of 30° C. or less; b) an anionic surfactant having sulfonate group; and c) an immobilization agent for a) component, wherein b) component is formulated in an amount of from 0 to 300 parts by weight, based on 100 parts by weight of a) component, and wherein c) component is formulated in an amount of from 1 to 100 parts by weight, based on 100 parts by weight of a) component, and wherein the surfactant composition has (1) a temperature range that a viscosity of the composition is 10 Pa·s or less at a temperature equal to or higher than a pour point of the surfactant composition; and (2) a temperature range that a penetrating hardness of the composition is 100 g/cm2 or more in a temperature range between a temperature lower than the pour point of the surfactant composition and a temperature higher than the melting point of a) component.

摘要翻译： 本发明的表面活性剂组合物是能够配制用于非液体洗涤剂组合物的表面活性剂组合物，所述表面活性剂组合物包含a）熔点为30℃以下的非离子表面活性剂; b）具有磺酸盐基团的阴离子表面活性剂; 和c）a）组分的固定剂，其中b）组分的配制量为0至300重量份，基于100重量份的a）组分，并且其中c）组分配制成一定量 1至100重量份，基于100重量份的a）组分，并且其中表面活性剂组合物具有（1）组合物的粘度在等于或等于10℃的温度下为10Pa·s以下的温度范围 或高于表面活性剂组合物的倾点; 和（2）在比表面活性剂组合物的倾点低的温度和高于a）成分的熔点的温度的温度范围内组合物的穿透硬度为100g / cm 2以上的温度范围。

公开(公告)号：US06376453B1

公开(公告)日：2002-04-23

申请号：US09355032

申请日：1999-07-22

申请人： Teruo Kubota ,  Hitoshi Takaya ,  Shu Yamaguchi ,  Hiroyuki Yamashita ,  Shuji Takana

发明人： Teruo Kubota ,  Hitoshi Takaya ,  Shu Yamaguchi ,  Hiroyuki Yamashita ,  Shuji Takana

IPC分类号： C11D1700

CPC分类号： C11D11/02 ,  C11D3/0052 ,  C11D17/065

摘要： To provide detergent particles having high-speed dissolution capable of dissolving quickly in water after supplying the detergent particles in water, and a method for preparing the detergent particles, and a detergent composition comprising the detergent particles. Detergent particles having an average particle size of from 150 to 500 &mgr;m and a bulk density of 500 g/liter or more, wherein the detergent particles comprising a detergent particle being capable of releasing a bubble from an inner portion of the detergent particles in a process of dissolving the detergent particle in water, the bubble having a size of one-tenth or more of a particle size of the detergent particle, and wherein the detergent particles have a dissolution rate as calculated by Equation (1) of 90% or more, under conditions where the detergent particles are supplied in water at 5° C.; stirred for 60 seconds under the test stirring conditions; and filtered with a standard sieve having a sieve-opening of 74 &mgr;m as defined by JIS Z 8801, or wherein the detergent particles have a dissolution rate of 82% or more, the detergent particles stirred for 30 seconds and calculated in the same manner as above.

摘要翻译： 提供具有高速溶解性能的洗涤剂颗粒，以及包含洗涤剂颗粒的洗涤剂组合物，其中洗涤剂颗粒在将洗涤剂颗粒供给到水中之后能迅速溶解在水中。 平均粒度为150〜500μm，体积密度为500g / l以上的洗涤剂粒子，其中，含有洗涤剂粒子的洗涤剂粒子能够以洗涤剂粒子的内部从内部释放气泡 将洗涤剂颗粒溶解在水中，气泡的尺寸为洗涤剂颗粒的粒径的十分之一以上，其中洗涤剂颗粒具有90％以上的等式（1）计算的溶解速率， 在洗涤剂颗粒在5℃的水中供应的条件下进行。 在试验搅拌条件下搅拌60秒; 用JIS Z 8801定义的筛孔为74μm的筛子进行过滤，或者其中洗涤剂颗粒的溶解率为82％以上，洗涤剂颗粒搅拌30秒，并以与 以上。