4-Butyl-3,4,5-trimethylcyclohexa-25-dienone
    11.
    发明授权
    4-Butyl-3,4,5-trimethylcyclohexa-25-dienone 失效
    4-丁基-3,4,5-三甲基环己基-25-二烯酮

    公开(公告)号:US4154763A

    公开(公告)日:1979-05-15

    申请号:US860121

    申请日:1977-12-13

    摘要: Processes and compositions are described for use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma; tobacco flavor and aroma; perfume and perfumed article aroma augmenting, enhancing and imparting compositions; and as foodstuff, chewing gum, toothpaste, medicinal product, tobacco, perfume and perfumed article aroma imparting materials of one or more cyclohexadiene derivatives having the generic formula: ##STR1## wherein R is one of C.sub.1 -C.sub.5 alkyl, R.sub.1 is methyl when R.sub.2 is hydrogen, and R.sub.1 is hydrogen when R.sub.2 is methyl, produced by one of the following processes:(i) Reacting a 1-alkyl-3,5,5-trimethylcyclohexa-1,3-diene with oxygen in the presence of light, an ultraviolet sensitizer, and a basic catalyst; and fractionally distilling the resulting product; or(ii) Reacting a 4-alkyl-4-hydroxy-3,5,5-trimethyl-2-cyclohexen-1-one with dilute aqueous mineral acid and distilling the resulting reaction product.Addition of one or more of the cyclohexadiene derivatives having the formula: ##STR2## wherein R is one of C.sub.1 -C.sub.5 alkyl, R.sub.1 is methyl when R.sub.2 is hydrogen, and R.sub.1 is hydrogen when R.sub.2 is methyl, to consumable materials is indicated to produce:(a) In foodstuffs, foodstuff flavoring compositions, chewing gums, toothpastes and medicinal products, sweet, hay-like, heliotropine-like, black pepper-like, woody, tobacco-like and "Oriental" aroma characteristics with sweet, hay-like, heliotropine-like, black pepper-like, woody, tobacco, "Oriental" flavor characteristics;(b) In perfumes, colognes and perfumed articles, warm sweet, slightly minty, woody, natural green, herbaceous, Jasmine-like, fruity aromas; and(c) In tobaccos and tobacco flavors, "dry black tobacco-like" notes, spicey notes, celery-like notes, black pepper-like notes, sweet notes and Virginia tobacco-like notes prior to and on smoking, in both the main stream and the side stream.

    摘要翻译: 描述了用于食品,口香糖,牙膏和药用产品香味和香气的方法和组合物; 烟草香气和香气; 香水和香水制品香气增强,增强和赋予组合物; 作为一种或多种具有以下通式的环己二烯衍生物的食品,口香糖,牙膏,药用产品,烟草,香料和香料制品香气赋予材料:其中R是C 1 -C 5烷基之一,当R 2为R 1时,R 1为甲基 是氢,当R 2为甲基时,R 1为氢,由以下方法之一制备:

    Detergent containing cyclohexadiene derivatives
    13.
    发明授权
    Detergent containing cyclohexadiene derivatives 失效
    含有环己二烯衍生物的洗涤剂

    公开(公告)号:US4154696A

    公开(公告)日:1979-05-15

    申请号:US917772

    申请日:1978-06-21

    摘要: Processes and compositions are described for use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma; tobacco flavor and aroma; perfume and perfumed article aroma augmenting, enhancing and imparting compositions; and as foodstuff, chewing gum, toothpaste, medicinal product, tobacco, perfume and perfumed article aroma imparting materials of one or more cyclohexadiene derivatives having the generic formula: ##STR1## wherein R is one of C.sub.1 -C.sub.5 alkyl, R.sub.1 is methyl when R.sub.2 is hydrogen, and R.sub.1 is hydrogen when R.sub.2 is methyl, produced by one of the following processes:(i) Reacting a 1-alkyl-3,5,5-trimethylcyclohexa-1,3-diene with oxygen in the presence of light, an ultraviolet sensitizer, and a basic catalyst; and fractionally distilling the resulting product; or(ii) Reacting a 4-alkyl-4-hydroxy-3,5,5-trimethyl-2-cyclohexen-1-one with dilute aqueous mineral acid and distilling the resulting reaction product.Addition of one or more of the cyclohexadiene derivatives having the formula: ##STR2## wherein R is one of C.sub.1 -C.sub.5 alkyl, R.sub.1 is methyl when R.sub.2 is hydrogen, and R.sub.1 is hydrogen when R.sub.2 is methyl, to consumable materials is indicated to produce:(a) In foodstuffs, foodstuff flavoring compositions, chewing gums, toothpastes and medicinal products, sweet, hay-like, heliotropine-like, black pepper-like, woody, tobacco-like and "Oriental" aroma characteristics with sweet, hay-like, heliotropine-like, black pepper-like, woody, tobacco, "Oriental" flavor characteristics;(b) In perfumes, colognes and perfumed articles, warm sweet, slightly minty, woody, natural green, herbaceous, Jasmine-like, fruity aromas; and(c) In tobaccos and tobacco flavors, "dry black tobacco-like" notes, spicey notes, celery-like notes, black pepper-like notes, sweet notes and Virginia tobacco-like notes prior to and on smoking, in both the main stream and the side stream.

    摘要翻译: 描述了用于食品,口香糖,牙膏和药用产品香味和香气的方法和组合物; 烟草香气和香气; 香水和香水制品香气增强,增强和赋予组合物; 作为一种或多种具有以下通式的环己二烯衍生物的食品,口香糖,牙膏,药用产品,烟草,香料和香料制品香气赋予材料:其中R是C 1 -C 5烷基之一,当R 2为R 1时,R 1为甲基 是氢,当R 2为甲基时,R 1为氢,由以下方法之一制备:

    Alkyl esters of 1-alkanoyl cycloalkanols, process for preparing same and
organoleptic uses thereof
    19.
    发明授权
    Alkyl esters of 1-alkanoyl cycloalkanols, process for preparing same and organoleptic uses thereof 失效
    1-烷酰基环烷醇的烷基酯,其制备方法及其感官用途

    公开(公告)号:US4327749A

    公开(公告)日:1982-05-04

    申请号:US133828

    申请日:1980-03-25

    IPC分类号: A24B15/34 A24B15/30

    CPC分类号: A24B15/34

    摘要: Described is a process for preparing several substituted or unsubstituted cycloalkyl acyl alkanoates defined according to the generic structure: ##STR1## wherein R.sub.1 and R.sub.2 taken together complete a cycloalkyl moiety or methyl, dimethyl or trimethyl substituted cycloalkyl moiety containing five or six carbon atoms in the ring and wherein R.sub.3 is C.sub.1 -C.sub.3 lower alkyl and R.sub.4 is methyl or hydrogen by reacting a compound having the generic structure: ##STR2## in an aqueous silver-ion containing solution having a weakly acidic pH at elevated temperatures. The compounds so produced are useful for their organoleptic properties in consumable materials, such as foodstuffs, foodstuff flavorants, chewing gums, chewing gum flavorants, toothpastes, toothpaste flavorants, medicinal products, medicinal product flavorants, chewing tobaccos, chewing tobacco flavorants, smoking tobaccos, smoking tobacco flavorants, perfume compositions, perfumed articles, such as cationic, anionic, nonionic and zwitterionic detergents, fabric softener compositions, drier-added fabric softener articles, textile sizing agents and optical brighteners for textiles as well as colognes.

    摘要翻译: 描述了根据通用结构定义的若干取代或未取代的环烷基酰基链烷酸酯的方法:其中R 1和R 2一起完成环烷基部分或含有5或6个碳原子的甲基,二甲基或三甲基取代的环烷基部分 环,其中R 3是C 1 -C 3低级烷基,R 4是甲基或氢,通过使具有通式结构的化合物:在高温下具有弱酸性pH的含水银离子溶液中。 如此生产的化合物可用于消费材料如食品,食品香料,口香糖,口香糖调味剂,牙膏,牙膏调味剂,药用产品,药用香料,咀嚼烟草,咀嚼烟草香料,烟草烟草, 吸烟烟草调味剂,香料组合物,香料制品,例如阳离子,阴离子,非离子和两性离子洗涤剂,织物柔软剂组合物,干燥剂添加的织物柔软剂制品,纺织品上浆剂和用于纺织品的荧光增白剂以及古龙水。

    Alkyl esters of 1-alkanoyl cycloalkanols and organoleptic uses thereof
    20.
    发明授权
    Alkyl esters of 1-alkanoyl cycloalkanols and organoleptic uses thereof 失效
    1-烷酰基环烷醇的烷基酯及其感官用途

    公开(公告)号:US4374055A

    公开(公告)日:1983-02-15

    申请号:US314002

    申请日:1981-10-22

    CPC分类号: A24B15/34 C11B9/0026 C11D3/50

    摘要: Described is a process for preparing several substituted or unsubstituted cycloalkyl acyl alkanoates defined according to the generic structure: ##STR1## wherein R.sub.1 and R.sub.2 taken together complete a cycloalkyl moiety or methyl, dimethyl or trimethyl substituted cycloalkyl moiety containing five or six carbon atoms in the ring and wherein R.sub.3 is C.sub.1 -C.sub.3 lower alkyl and R.sub.4 is methyl or hydrogen by reacting a compound having the generic structure: ##STR2## in an aqueous silver-ion containing solution having a weakly acidic pH at elevated temperatures. The compounds so produced are useful for their organoleptic properties in consumable materials, such as foodstuffs, foodstuff flavorants, chewing gums, chewing gum flavorants, toothpastes, toothpaste flavorants, medicinal products, medicinal product flavorants, chewing tobaccos, chewing tobacco flavorants, smoking tobaccos, smoking tobacco flavorants, perfume compositions, perfumed articles, such as cationic, anionic, nonionic and zwitterionic detergents, fabric softener compositions, drier-added fabric softener articles, textile sizing agents and optical brighteners for textiles as well as colognes.

    摘要翻译: 描述了根据通用结构定义的若干取代或未取代的环烷基酰基链烷酸酯的方法:其中R 1和R 2一起完成环烷基部分或含有5或6个碳原子的甲基,二甲基或三甲基取代的环烷基部分 环,其中R 3是C 1 -C 3低级烷基,R 4是甲基或氢,通过使具有通式结构的化合物:在高温下具有弱酸性pH的含水银离子溶液中。 如此生产的化合物可用于消费材料如食品,食品香料,口香糖,口香糖调味剂,牙膏,牙膏调味剂,药用产品,药用香料,咀嚼烟草,咀嚼烟草香料,烟草烟草, 吸烟烟草调味剂,香料组合物,香料制品,例如阳离子,阴离子,非离子和两性离子洗涤剂,织物柔软剂组合物,干燥剂添加的织物柔软剂制品,纺织品上浆剂和用于纺织品的荧光增白剂以及古龙水。