摘要:
A solution or slurry containing a carbonate or sulfite, or both is continuously supplied into a tightly closed vessel, while any excess of the liquid is allowed to overflow the vessel. Sulfuric acid is supplied into the vessel to maintain the pH level of the liquid in the vessel at a value not exceeding 3. Air is supplied into the vessel as a carrier gas for CO.sub.2 or SO.sub.2 or both formed by the reaction of the carbonate or sulfite or both in the liquid with the sulfuric acid. The carrier gas is collected from the vessel, and the concentration of CO.sub.2 or SO.sub.2 or both in the carrier gas is determined. The concentration of the carbonate or sulfite or both in the liquid is obtained by calculations from the concentration of CO.sub.2 or SO.sub.2 or both, the flow rate of the liquid and the flow rate of the carrier gas.
摘要:
A process for desulfurizing an exhaust gas which comprises desulfurizing an exhaust gas containing SO.sub.2 by bringing it into contact with a slurry containing calcium compounds and aluminum compounds, characterized in that the concentration of the dissolved aluminum ion in said slurry is detected and a manganese compound is supplied into said slurry in such a manner that the ratio of the concentration of manganese (including both solid and liquid) to said concentration of the dissolved aluminum ion may be maintained in a molar ratio of less than 1 in said slurry.
摘要:
Five combustion exhaust gas treatment systems capable of removing dust and selenium (Se) in combustion exhaust gas and making harmless are proposed: (1) combustion exhaust gas is cooled to 350° C. or less, dust is separated, Se is transformed into insoluble compound, and Se is separated; (2) combustion exhaust gas is cooled to 350° C. or less, dust is separated, Se elution preventive agent is added, and dust is formed into scale; (3) dust in combustion exhaust gas is collected by dust collector, dust is formed into slurry by making use of part of circulation liquid in desulfurization apparatus, and tetravalent Se in dust slurry is transformed into insoluble compound, which is separated into solid and liquid; (4) dust is separated from combustion exhaust gas by dust collector, and it is heated to gasify Se, and is led into desulfurization apparatus, etc., and formed into slurry, and Se is made into insoluble compound; and (5) a treating agent for making tetravalent Se insoluble is added to part of circulation liquid in desulfurization apparatus, and it is sprayed into combustion exhaust gas to make Se insoluble.
摘要:
A method for desulfurizing an exhaust gas containing SO.sub.2 and NO.sub.x in accordance with a wet lime process, the aforesaid desulfurizing method being characterized by comprising the steps of drawing a part of an absorbing slurry, subjecting a filtrate obtained by the solid-liquid separation of the drawn absorbing slurry to an electrolysis treatment in the presence of chlorine ions, or after adjusting the filtrate to pH 3-4, mixing a hydrochlorite with the filtrate, and then refeeding the filtrate as a make-up water to an absorbing tower.
摘要:
A process for the treatment of sewage to provide effective removal of selenium (especially the 6-valent selenium) to meet required standards for the dissolved amount of selenium, and the like, at a low cost are developed. The process and apparatus reduces selenium from the 6-valent selenium using microbiological treatment to obtain 4-valent selenium and/or simple selenium, and then provide a solid-liquid separation.
摘要:
A desulfurization process which comprises the steps of bringing a combustion exhaust gas into contact with a gypsum slurry containing 1% or less of calcium carbonate in a first absorption tower, and then bringing the combustion exhaust gas into contact with a gypsum slurry containing 1% or more of calcium carbonate in a second absorption tower. SO.sub.x can be removed from a combustion exhaust gas with a high efficiency in accordance with a wet lime/gypsum method.
摘要:
A method of treating an exhaust gas containing SO.sub.2 and HF which is characterized by using an absorbing liquid containing CaCO.sub.3 and Ca(OH).sub.2 as absorbents to be fed to an absorption tower for the exhaust gas, circulating the absorbing liquid from a second slurry tank to the absorption tower, from the absorption tower to a first slurry tank, and from the first flurry tank to the second slurry tank, introducing Ca(OH).sub.2 into the second slurry tank to keep the pH value of the absorbing liquid in the second slurry tank in the range of 5.5-7.0, and blowing air into the absorbing liquid in the first slurry tank.
摘要:
Five combustion exhaust gas treatment systems capable of removing dust and selenium (Se) in combustion exhaust gas and making harmless are proposed: (1) combustion exhaust gas is cooled to 350° C. or less, dust is separated, Se is transformed into insoluble compound, and Se is separated; (2) combustion exhaust gas is cooled to 350° C. or less, dust is separated, Se elution preventive agent is added, and dust is formed into scale; (3) dust in combustion exhaust gas is collected by dust collector, dust is formed into slurry by making use of part of circulation liquid in desulfurization apparatus, and tetravalent Se in dust slurry is transformed into insoluble compound, which is separated into solid and liquid; (4) dust is separated from combustion exhaust gas by dust collector, and it is heated to gasify Se, and is led into desulfurization apparatus, etc., and formed into slurry, and Se is made into insoluble compound; and (5) a treating agent for making tetravalent Se insoluble is added to part of circulation liquid in desulfurization apparatus, and it is sprayed into combustion exhaust gas to make Se insoluble.
摘要:
Five combustion exhaust gas treatment systems capable of removing dust and selenium (Se) in combustion exhaust gas and making harmless are proposed: (1) combustion exhaust gas is cooled to 350.degree. C. or less, dust is separated, Se is transformed into insoluble compound, and Se is separated; (2) combustion exhaust gas is cooled to 350.degree. C. or less, dust is separated, Se elution preventive agent is added, and dust is formed into scale; (3) dust in combustion exhaust gas is collected by dust collector, dust is formed into slurry by making use of part of circulation liquid in desulfurization apparatus, and tetravalent Se in dust slurry is transformed into insoluble compound, which is separated into solid and liquid; (4) dust is separated from combustion exhaust gas by dust collector, and it is heated to gasify Se, and is led into desulfurization apparatus, etc., and formed into slurry, and Se is made into insoluble compound; and (5) a treating agent for making tetravalent Se insoluble is added to part of circulation liquid in desulfurization apparatus, and it is sprayed into combustion exhaust gas to make Se insoluble.
摘要:
A wet-type exhaust gas desulfurization system comprises a reservoir for trapping an absorbing solution which has absorbed SO.sub.2 from exhaust gas; an absorbing solution circulating tank disposed directly under the reservoir; a plurality of bottom pipes which are installed at the bottom of reservoir and extend downward into the absorbing solution in the circulating tank and whose lower end is open, or drop pipes which depend into the absorbing solution and whose lower ends are open; and air supply pipe at least one end of which is open to the atmosphere; a pipe for discharging the air above the surface of absorbing solution onto the surface of solution in the reservoir; and a pipe for supplying the absorbing solution in the circulating tank to a spray nozzle at the upper part of the absorbing tower.