公开(公告)号：US20140088260A1

公开(公告)日：2014-03-27

申请号：US13838459

申请日：2013-03-15

Applicant: MATERIA, INC.

Inventor： Michael A. GIARDELLO ,  Christopher M. HAAR ,  Brian EDGECOMBE ,  Anthony R. STEPHEN ,  Li-Sheng WANG ,  Diana STOIANOVA

IPC: C07C265/08 ,  C08F32/08

CPC classification number: C09J145/00 ,  C07C265/08 ,  C08F32/08 ,  C08F263/04 ,  C08G61/08 ,  C08G2261/142 ,  C08G2261/144 ,  C08G2261/3324 ,  C08G2261/418 ,  C09J4/00 ,  C09J5/00 ,  C09J165/00

Abstract: The invention discloses an adhesion agent composition comprising at least one C3-C200 olefin compound having at least one metathesis active double bond, wherein the olefin is substituted or unsubstituted; and at least one compatibilizing functionality for interacting with a substrate surface. The substrate surface can be any surface, for example, silicate glasses, silicate minerals, metals, metal alloys, ceramics, natural stones, plastics, carbon, silicon, and semiconductors. The invention also discloses articles of manufacture utilizing these adhesion agents as well as methods for adhering a polyolefin to a substrate surface.

Abstract translation: 本发明公开了一种粘合剂组合物，其包含至少一种具有至少一个复分解活性双键的C 3 -C 20烯烃化合物，其中所述烯烃是取代或未取代的; 以及用于与衬底表面相互作用的至少一种相容性功能。 衬底表面可以是任何表面，例如硅酸盐玻璃，硅酸盐矿物，金属，金属合金，陶瓷，天然石，塑料，碳，硅和半导体。 本发明还公开了利用这些粘合剂的制品以及将聚烯烃粘附到基材表面的方法。

公开(公告)号：US20180237581A1

公开(公告)日：2018-08-23

申请号：US15955876

申请日：2018-04-18

Applicant: MATERIA, INC.

Inventor： Anthony R. STEPHEN ,  Christopher J. CRUCE ,  Mark S. TRIMMER ,  Michael A. GIARDELLO

IPC: C08G61/02 ,  C03C17/32 ,  C09D165/00 ,  B29B15/12

CPC classification number: C08G61/02 ,  B29B15/122 ,  B29K2309/08 ,  C03C17/328 ,  C03C25/30 ,  C08G61/08 ,  C08G2261/3325 ,  C08G2261/964 ,  C08J5/043 ,  C08J2323/20 ,  C08K3/36 ,  C08K3/40 ,  C08K5/14 ,  C08K5/5419 ,  C08K5/5425 ,  C08K7/14 ,  C08K7/28 ,  C08L65/00 ,  C09D165/00

Abstract: A method of improving the adhesion of metathesis compositions, such as ring-opening metathesis polymerization (ROMP) compositions, to a substrate is disclosed, in which an adhesion promoter is added to a polymerizable resin composition in order to improve the adhesion of the polymerizing resin to a substrate material. The addition of the adhesion promoter has been found to provide beneficial improvements in the adhesion of metathesis, especially ROMP, compositions to substrates, particularly glass surfaces, leading to improved characteristics in ROMP materials formed therefrom. The adhesion promoter generally comprises a functionalized silane compound and a peroxide compound. A ROMP composition is further disclosed comprising a cyclic olefin, a ROMP metathesis catalyst, and the adhesion promoter. Polymer products produced via metathesis (ROMP) reactions of the invention may be utilized to provide a wide range of materials and in a variety of composite applications. The invention has utility in the fields of catalysis, organic synthesis, and polymer and materials chemistry and manufacture.

公开(公告)号：US20160186022A1

公开(公告)日：2016-06-30

申请号：US14926830

申请日：2015-10-29

Applicant: MATERIA, INC.

Inventor： Michael A. GIARDELLO ,  Christopher M. HAAR ,  Brian EDGECOMBE ,  Anthony R. STEPHEN ,  Li-Sheng WANG ,  Diana STOIANOVA

IPC: C09J145/00 ,  C09J5/00

CPC classification number: C09J145/00 ,  C07C265/08 ,  C08F32/08 ,  C08F263/04 ,  C08G61/08 ,  C08G2261/142 ,  C08G2261/144 ,  C08G2261/3324 ,  C08G2261/418 ,  C09J4/00 ,  C09J5/00 ,  C09J165/00

Abstract: The invention discloses an adhesion agent composition comprising at least one C3-C200 olefin compound having at least one metathesis active double bond, wherein the olefin is substituted or unsubstituted; and at least one compatibilizing functionality for interacting with a substrate surface. The substrate surface can be any surface, for example, silicate glasses, silicate minerals, metals, metal alloys, ceramics, natural stones, plastics, carbon, silicon, and semiconductors. The invention also discloses articles of manufacture utilizing these adhesion agents as well as methods for adhering a polyolefin to a substrate surface.

公开(公告)号：US20160185897A1

公开(公告)日：2016-06-30

申请号：US14843448

申请日：2015-09-02

Applicant: MATERIA, INC.

Inventor： Anthony R. STEPHEN ,  Christopher J. CRUCE ,  Michael A. GIARDELLO

IPC: C08G61/08

CPC classification number: C08G61/08 ,  B01J31/28 ,  B01J2231/14 ,  B01J2231/54 ,  B01J2531/821 ,  C08F4/80 ,  C08F32/00 ,  C08F132/08 ,  C08G2261/11 ,  C08G2261/135 ,  C08G2261/3325 ,  C08G2261/418 ,  C08G2261/76

Abstract: This invention relates to olefin metathesis catalysts and methods for controlling olefin metathesis reactions. More particularly, the present invention relates to methods and compositions for catalyzing and controlling ring opening metathesis polymerization (ROMP) reactions and the manufacture of polymer articles via ROMP. This invention also relates to olefin metathesis catalyst compositions comprising at least two metal carbene olefin metathesis catalysts, wherein the at least two metal carbene olefin metathesis catalysts are structurally different, are chemically different, are distinct compounds, are not isomers, are not structural isomers, are not diastereoisomers, are not stereoisomers, are not enantiomers, or are not cis/trans isomers of each other, or any combinations thereof. This invention also relates to a ROMP composition comprising a resin composition comprising at least one cyclic olefin, and an olefin metathesis catalyst composition comprising at least two metal carbene olefin metathesis catalysts, wherein the at least two metal carbene olefin metathesis catalysts are structurally different, are chemically different, are distinct compounds, are not isomers, are not structural isomers, are not diastereoisomers, are not stereoisomers, are not enantiomers, or are not cis/trans isomers of each other, or any combinations thereof. This invention also relates to a method of making an article comprising combining an olefin metathesis catalyst composition comprising at least two metal carbene olefin metathesis catalysts with a resin composition comprising at least one cyclic olefin, thereby forming a ROMP composition, and subjecting the ROMP composition to conditions effective to polymerize the ROMP composition, wherein the at least two metal carbene olefin metathesis catalysts are structurally different, are chemically different, are distinct compounds, are not isomers, are not structural isomers, are not diastereoisomers, are not stereoisomers, are not enantiomers, or are not cis/trans isomers of each other, or any combinations thereof. Polymer products produced via the metathesis reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of catalysis, organic synthesis, and polymer and materials chemistry and manufacture.

公开(公告)号：US20160185885A1

公开(公告)日：2016-06-30

申请号：US14959233

申请日：2015-12-04

Applicant: MATERIA, INC.

Inventor： Anthony R. STEPHEN ,  Christopher J. CRUCE ,  Michael A. GIARDELLO

IPC: C08F32/00

CPC classification number: C08F32/00 ,  B01J31/2278 ,  B01J2231/543 ,  C08F4/80 ,  C08F132/08 ,  C08G61/08 ,  C08G2261/3325 ,  C08G2261/418

Abstract: This invention relates to olefin metathesis catalysts and methods for controlling olefin metathesis reactions. More particularly, the present invention relates to methods and compositions for catalyzing and controlling ring opening metathesis polymerization (ROMP) reactions and the manufacture of polymer articles via ROMP. This invention also relates to olefin metathesis catalyst compositions comprising at least two metal carbene olefin metathesis catalysts. This invention also relates to a ROMP composition comprising a resin composition comprising at least one cyclic olefin, and an olefin metathesis catalyst composition comprising at least two metal carbene olefin metathesis catalysts. This invention also relates to a method of making an article comprising combining an olefin metathesis catalyst composition comprising at least two metal carbene olefin metathesis catalysts with a resin composition comprising at least one cyclic olefin, thereby forming a ROMP composition, and subjecting the ROMP composition to conditions effective to polymerize the ROMP composition. Polymer products produced via the metathesis reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of catalysis, organic synthesis, and polymer and materials chemistry and manufacture.

Abstract translation: 本发明涉及烯烃复分解催化剂和控制烯烃复分解反应的方法。 更具体地说，本发明涉及用于催化和控制开环易位聚合（ROMP）反应和通过ROMP制备聚合物制品的方法和组合物。 本发明还涉及包含至少两种金属卡宾烯烃复分解催化剂的烯烃复分解催化剂组合物。 本发明还涉及包含至少一种环烯烃的树脂组合物和包含至少两种金属卡宾烯烃复分解催化剂的烯烃易位催化剂组合物的ROMP组合物。 本发明还涉及一种制备制品的方法，包括将包含至少两种金属卡宾烯烃复分解催化剂的烯烃复分解催化剂组合物与包含至少一种环烯烃的树脂组合物组合，从而形成ROMP组合物，并将ROMP组合物 有效聚合ROMP组合物的条件。 通过本发明的复分解反应产生的聚合物产物可用于广泛的材料和复合材料应用。 本发明可用于催化，有机合成，聚合物和材料的化学和制造领域。