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    Reversibly reducible metal complexes as electron transporting materials for OLEDs
    12.
    发明授权
    Reversibly reducible metal complexes as electron transporting materials for OLEDs 有权
    用于OLED的可逆还原金属络合物作为电子传输材料

    公开(公告)号：US07582365B2

    公开(公告)日：2009-09-01

    申请号：US11032941

    申请日：2005-01-10

    Applicant: Robert Walters ,  Raymond Kwong ,  Mark E. Thompson

    Inventor： Robert Walters ,  Raymond Kwong ,  Mark E. Thompson

    IPC: H01L51/54

    CPC classification number: H01L51/0077 ,  H01L51/0084 ,  H01L51/5048 ,  Y10S428/917

    Abstract: The invention is reversibly reducible metal complexes and materials and an organic light emitting device, having an anode; a cathode; and at least one organic layer disposed between the anode and the cathode, made with the complexes of the invention. The reversibly reducible metal complexes are complexes a redox active metal center and at least one ligand; wherein; following a reduction of the complex, adding 1 extra electron to the complex, the extra electron is localized on the metal center. The complexes may function as an ETL or a host material.

    Abstract translation: 本发明是可逆还原的金属络合物和材料以及具有阳极的有机发光器件; 阴极 以及设置在阳极和阴极之间的至少一个有机层，由本发明的配合物制成。 可逆还原的金属络合物是氧化还原活性金属中心和至少一种配体的络合物; 其中; 随着复合物的还原，向络合物中加入1个额外的电子，额外的电子被定位在金属中心。 络合物可以作为ETL或宿主材料。

    Organometallic complexes as singlet oxygen sensitizers
    16.
    发明授权
    Organometallic complexes as singlet oxygen sensitizers 有权
    有机金属配合物作为单线态氧敏感剂

    公开(公告)号：US07368570B2

    公开(公告)日：2008-05-06

    申请号：US10913931

    申请日：2004-08-06

    Applicant: Mark E. Thompson ,  Peter I. Djurovich ,  Drew Murphy ,  Matthias Selke

    Inventor： Mark E. Thompson ,  Peter I. Djurovich ,  Drew Murphy ,  Matthias Selke

    IPC: C07F15/00 ,  A61K31/555

    CPC classification number: C07F15/0033 ,  C02F2305/10

    Abstract: A series of organometallic complexes and the singlet oxygen sensitization properties of these complexes are provided. Complexes with acetylacetonate ligands give singlet oxygen quantum yields near unity, whether exciting the ligand-based state or the lowest energy excited state (MLCT+3LC). The singlet oxygen quenching rates for these β-diketonate complexes are small, roughly three orders of magnitude slower than the corresponding phosphorescence quenching rate. Similar complexes were prepared with glycine or pyridine tethered to the Ir(III) center (i.e. (bsn)2Ir(gly) and (bt)2Ir(py)Cl, where gly=glycine, and py=pyridine). The glycine and pyridine derivatives give high singlet oxygen yields.

    Abstract translation: 提供了一系列有机金属配合物和这些络合物的单线态氧敏感性质。 与乙酰丙酮配体的配合物可使单线态氧量子产率接近一致，无论是激发基于配体的状态还是最低能量激发态（MLCT + 3LC）。 这些β-二酮络合物的单线态氧猝灭速率小，比相应的磷光猝灭速率慢三个数量级。 用连接于Ir（III）中心的甘氨酸或吡啶（即（bsn）2 Ir（gly）和（bt）2 Ir（py）Cl ，其中gly =甘氨酸和py =吡啶）。 甘氨酸和吡啶衍生物具有高的单线态氧产率。

    Materials and structures for enhancing the performance of organic light emitting devices
    19.
    发明授权
    Materials and structures for enhancing the performance of organic light emitting devices 有权
    用于增强有机发光器件性能的材料和结构

    公开(公告)号：US07018723B2

    公开(公告)日：2006-03-28

    申请号：US10626579

    申请日：2003-07-25

    Applicant: Mark E. Thompson ,  Raymond Kwong ,  Yeh-Jiun Tung

    Inventor： Mark E. Thompson ,  Raymond Kwong ,  Yeh-Jiun Tung

    IPC: H05B33/12

    CPC classification number: H01L51/5048 ,  C07C13/567 ,  C07C13/66 ,  C07C15/24 ,  C07C15/38 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  H01L51/005 ,  H01L51/0052 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/5016 ,  H01L2251/308 ,  H05B33/14 ,  Y10S428/917 ,  Y10T428/24942

    Abstract: A device is provided, having an anode, a cathode, and a first organic layer disposed between the anode and the cathode. The first organic layer comprises a material that produces phosphorescent emission when a voltage is applied between the anode and the cathode. A second organic layer is disposed between the first organic layer and the cathode. The second organic layer is in direct contact with the first organic layer. The second organic layer may comprise an aromatic hydrocarbon material, comprising an aromatic hydrocarbon core optionally substituted, and wherein the substituents are the same or different, and each is selected from the group consisting of alkyl, aryl, heteroalkyl, substituted aryl, substituted heteroaryl and heterocyclic groups. The second organic layer may comprise a material having a dipole moment less than about 2.0 debyes, such that the device has an unmodified external quantum efficiency of at least about 3% and a lifetime of at least about 1000 hours at an initial luminance of about 100 to about 1000 cd/m2. The second organic layer may be in direct contact with the cathode, or there may be a separate organic layer between the second organic layer and the cathode.

    Abstract translation: 提供一种具有阳极，阴极和设置在阳极和阴极之间的第一有机层的器件。 第一有机层包括当在阳极和阴极之间施加电压时产生磷光发射的材料。 第二有机层设置在第一有机层和阴极之间。 第二有机层与第一有机层直接接触。 第二有机层可以包括芳族烃材料，其包含任选取代的芳族烃核心，并且其中取代基相同或不同，并且各自选自烷基，芳基，杂烷基，取代的芳基，取代的杂芳基和 杂环基。 第二有机层可以包括具有小于约2.0德拜的偶极矩的材料，使得该装置在约100的初始亮度下具有至少约3％的未修饰的外量子效率和至少约1000小时的寿命 至约1000cd / m 2。 第二有机层可以与阴极直接接触，或者在第二有机层和阴极之间可以存在单独的有机层。

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