摘要:
A cocatalyst employed with a titanium-containing catalyst, said titanium-containing catalyst comprising titanium atoms, halogen atoms, and an electron donor compound, said cocatalyst comprising(a) an organoaluminum compound represented by the formula R.sup.1 R.sup.2 R.sup.3 (wherein R.sup.1, R.sup.2, and R.sup.3 which may be the same or different, each denote a C.sub.1-20 alkyl, alkenyl, cycloalkyl, aryl, aralkyl, or alkoxy group, or a hydrogen atom;(b) an organoaluminum compound represented by the formula R.sub.3-n.sup.4 AlX.sub.n (wherein R.sup.4 denotes a C.sub.1-20 alkyl, alkenyl, cycloalkyl, aryl, aralkyl, or alkoxy group; X denotes a halogen atom; and n.gtoreq.1),(c) an electron donor compound containing a nitrogen atom, sulfur atom, oxygen atom, or phosphorus atom, and(d) an aromatic carboxylic acid ester.The catalyst is useful for the polymerization of olefins.
摘要翻译:一种与含钛催化剂一起使用的助催化剂,所述含钛催化剂包含钛原子,卤素原子和电子给体化合物,所述助催化剂包括(a)由式R 1 R 2 R 3表示的有机铝化合物(其中R1,R2和R3 + L可以相同或不同,各自表示C1-20烷基,烯基,环烷基,芳基,芳烷基或烷氧基或氢原子;(b)由式R3-n4AlXn(式 其中R4表示C1-20烷基,烯基,环烷基,芳基,芳烷基或烷氧基; X表示卤素原子; n表示1),(c)含有氮原子,硫原子, 氧原子或磷原子,和(d)芳族羧酸酯,该催化剂可用于烯烃的聚合。
摘要:
The present invention is intended to provide a sliding member which exhibits an excellent anti-seizure property even under starved lubricant conditions. In the present invention, there is provided a sliding member with a structure, in which a coating layer having a sliding surface is adhered to the surface of the base material, wherein the coating layer does not contain a resin binder but has solid lubricant plate crystal particles laminated therein, wherein these solid lubricant plate crystal particles have a lamellar crystal structure in which (001) planes are stacked in parallel, and at least in the sliding surface, the orientation index of the (001) plane of the solid lubricant plate crystal particles is 90% or more.
摘要:
A process for homopolymerizing an olefin or copolymerizing an olefin with another olefin in the presence of a catalyst composed of(a) a solid catalyst component containing magnesium atoms, titanium atoms, halogen atoms, and an electron donor compound,(b) an organoaluminum compound represented by the formula R.sup.1 R.sup.2 R.sup.3 Al (wherein R.sup.1, R.sup.2, and R.sup.3, which may be the same or different, each denote a C.sub.1-20 alkyl, alkenyl, cycloalkyl, aryl, aralkyl, or alkoxy group, or a hydrogen atom;(c) an organoaluminum compound represented by the formula R.sup.4.sub.3-n AlX.sub.n (wherein R.sup.4 denotes a C.sub.1-20 alkyl, alkenyl, cycloalkyl, aryl, aralkyl, or alkoxy group; X denotes a halogen atom; and n.gtoreq.1),(d) an electron donor compound containing a nitrogen atom, sulfur atom, oxygen atom, or phosphorus atom, and(e) an aromatic ester compound.
摘要:
A stainless steel powder is mixed with at least a Ni--Mn and a Ni--Cr powder, and the powder mixture is formed by loose packing into a required configuration. The powder mixture is sintered in a non-oxidizing atmosphere at the melting point of the Ni--Mn powder or at a higher temperature thereby to obtain a porous body.
摘要:
In the case where rolling printing is used to apply a coating liquid to an inner surface of a half bearing to form a coating layer thereon, the coating layer is formed in uniform thickness.A transfer roll rotates to have a coating liquid in a coating liquid tank filled in recesses formed on a roll surface thereof and to have a surplus coating liquid scraped off by a doctor blade, and rotates contacting with a coating roll. Thereby, the coating liquid in the recesses of the transfer roll is transferred to the coating roll. Thereafter, while the transfer roll is moved upward, an arm is rotated counterclockwise whereby the coating roll is separated from the transfer roll. The arm is further rotated whereby the coating roll is moved along an inner surface of a half bearing fixed to a jig and the coating roll applies the coating liquid to the inner surface of the half bearing.
摘要:
An object of the present invention is that in a sliding member whose substrate is improved in sliding characteristics by a coating layer comprising a solid lubricant, the coating layer is obtained as one having a low coefficient of friction and an excellent wear resistance. In the present invention, the coating layer 7 has a structure formed by laminating solid lubricant plate crystal grains 3, and contains not more than 10 mass % of a resin for binder 8 for bonding the solid lubricant plate crystal grains 3, and the lubricant plate crystal grains have a crystal structure formed by piling (00l) planes (wherein l is an integer of not less than 1) in parallel, the index of orientation of the (00l) planes being not less than 90% at least on the sliding surface.
摘要:
The present invention is intended to provide a sliding member which exhibits an excellent anti-seizure property even under starved lubricant conditions. In the present invention, there is provided a sliding member with a structure, in which a coating layer having a sliding surface is adhered to the surface of the base material, wherein the coating layer does not contain a resin binder but has solid lubricant plate crystal particles laminated therein, wherein these solid lubricant plate crystal particles have a lamellar crystal structure in which (001) planes are stacked in parallel, and at least in the sliding surface, the orientation index of the (001) plane of the solid lubricant plate crystal particles is 90% or more.
摘要:
A sliding member has a coating layer deposited on a base material through an intermediate layer, wherein the intermediate layer is formed of a lead-free metal, and the coating layer is formed of Bi or a lead-free Bi alloy; and wherein a grain in the intermediate layer becomes gradually large toward a coating layer side from a base material side, and a grain in the coating layer forms a columnar grain of which the major axis directs toward the surface of the coating layer from the intermediate layer side. Thus formed configuration improves a bonding strength between the base material and the coating layer owing to the intermediate layer, and has the grain of the coating layer formed into a desirable shape for bearing a load from an opposite material to improve fatigue resistance.