公开(公告)号：US20060254128A1

公开(公告)日：2006-11-16

申请号：US10484971

申请日：2002-07-09

申请人： Matthias Krull ,  Markus Kupetz

发明人： Matthias Krull ,  Markus Kupetz

IPC分类号： C10L1/18

CPC分类号： C10L10/08 ,  C10L1/191

摘要： The invention relates to an additive for improving the lubrication capacity of fuel oils with a maximum sulphur content of 0.035 wt. %. Said additive contains at least one ester of a bivalent or polyvalent alcohol and a mixture of unsaturated and optionally saturated fatty acids, whose carbon chain lengths are between 8 and 30 carbon atoms, the aforementioned esters having an OH value less than 200 mg KOH/g ester and an iodine value greater than 100 g I/100 g ester. The invention also relates to fuel oils with a maximum sulphur content of 0.035 wt. %, which contain the inventive additives. The novel additives exhibit less tendency to emulsify than the additives in prior art.

摘要翻译： 本发明涉及一种用于改善最大硫含量为0.035重量％的燃料油的润滑能力的添加剂。 ％。 所述添加剂含有至少一种二价或多价醇的酯和碳链长度为8至30个碳原子的不饱和脂肪酸和任选的饱和脂肪酸的混合物，上述酯的OH值小于200mg KOH / g 酯，碘值大于100g I / 100g酯。 本发明还涉及最大硫含量为0.035重量％的燃料油。 ％，其含有本发明的添加剂。 与现有技术中的添加剂相比，新型添加剂显示出较少的乳化倾向。

公开(公告)号：US06793696B2

公开(公告)日：2004-09-21

申请号：US10035522

申请日：2001-11-09

申请人： Matthias Krull ,  Markus Kupetz

发明人： Matthias Krull ,  Markus Kupetz

IPC分类号： C10L122

CPC分类号： C10L10/08 ,  C10L1/221 ,  C10L1/2222

摘要： Disclosed is a fuel oil composition comprising a middle distillate having a sulfur content of up to 0.05% by weight and reaction products of A) mono- or dicarboxylic acids of 6 to 50 carbon atoms and B) primary, secondary or tertiary amines of the formula NR1R2R3 where R1 is branched alkyl of 3 to 18 carbon atoms and R2 and R3 are independently hydrogen, R1 or alkyl of 1-12 carbon atoms.

摘要翻译： 公开了一种燃料油组合物，其包含具有高达0.05重量％的硫含量的中间馏分和A）6-50个碳原子的一元或二元羧酸的反应产物，以及B）所述R 1的伯，仲或叔胺， 1>是3至18个碳原子的支链烷基，R 2和R 3独立地是氢，R 1或1-12个碳原子的烷基。

公开(公告)号：US06391071B1

公开(公告)日：2002-05-21

申请号：US09591236

申请日：2000-06-09

申请人： Matthias Krull ,  Markus Kupetz

发明人： Matthias Krull ,  Markus Kupetz

IPC分类号： C10L118

CPC分类号： C10L10/08 ,  C10L1/195 ,  C10L1/1955 ,  C10L1/1963 ,  C10L1/1973 ,  C10L1/236

摘要： The present invention relates to the use of oil-soluble copolymers which comprise A) from 5 to 80 mol-% of structural units derived from olefinically unsaturated compounds containing at least one free hydroxyl group, B) from 5 to 95 mol-% of structural units derived from olefinically unsaturated compounds carrying a hydrocarbon radical having at least 6 carbon atoms, and, if desired, C) from 0 to 40 mol-% of further structural units selected from the group consisting of acrylic acid, acrylates, vinyl esters, vinylethane and alkenes, with the proviso that the structural units mentioned under C) are different from the structural units mentioned under A) and B), and have a mean molecular weight Mw of from 500 to 100,000 g/mol and an OH number of from 10 to 300 mg of KOH/g, for improving the lubricity and cold flow properties of middle distillates having a sulfur content of less than 0.5% by weight.

摘要翻译： 本发明涉及油溶性共聚物的用途，该共聚物包含A）5至80mol％的衍生自含有至少一个游离羟基的烯属不饱和化合物的结构单元，B）5至95mol％的结构单元 衍生自携带具有至少6个碳原子的烃基的烯属不饱和化合物，如果需要，C）0至40摩尔％的选自丙烯酸，丙烯酸酯，乙烯酯，乙烯基乙烷和 烯烃，条件是C）中提到的结构单元不同于A）和B）中提及的结构单元，并且具有500至100,000g / mol的平均分子量Mw和10至 300mg KOH / g，用于改善硫含量小于0.5重量％的中间馏分的润滑性和冷流动性。

公开(公告)号：US20130000184A1

公开(公告)日：2013-01-03

申请号：US13515376

申请日：2010-12-07

申请人： Matthias Krull ,  Werner Reimann ,  Stefan Dilsky ,  Sabine Goetzke ,  Dirk Leinweber

发明人： Matthias Krull ,  Werner Reimann ,  Stefan Dilsky ,  Sabine Goetzke ,  Dirk Leinweber

IPC分类号： C10L1/188 ,  C10M169/04

CPC分类号： C10L1/143 ,  C10L1/1608 ,  C10L1/1616 ,  C10L1/1641 ,  C10L1/1963 ,  C10L1/1973 ,  C10L1/1981 ,  C10L1/1983 ,  C10L1/1985 ,  C10L1/224 ,  C10L10/14 ,  C10L10/16

摘要： The present invention relates to cooling additives for middle distillates, containing A) at least one comb polymer carrying hydroxyl groups, which can be produced by polycondensation of a polyol that contains two primary OH groups and at least one secondary OH group with a dicarboxylic acid or the anhydride or ester thereof, which carries a C16-C40 alkyl radical or a C16-C40 alkenyl radical, characterized in that the OH number of the comb polymer is at least 40 mg KOH/g, B) at least one copolymer of ethylene and of at least one ethylenically unsaturated ester, and C) at least one organic solvent.

摘要翻译： 本发明涉及用于中间馏分的冷却添加剂，其包含A）至少一个带有羟基的梳形聚合物，其可以通过将含有两个伯OH基和至少一个仲OH基的多元醇与二羧酸缩聚制备，或 其具有C 16 -C 40烷基或C 16 -C 40烯基的酸酐或酯，其特征在于梳状聚合物的OH值为至少40mg KOH / g，B）至少一种乙烯和 的至少一种烯属不饱和酯，和C）至少一种有机溶剂。

公开(公告)号：US08283298B2

公开(公告)日：2012-10-09

申请号：US11494951

申请日：2006-07-28

申请人： Matthias Krull ,  Werner Reimann

发明人： Matthias Krull ,  Werner Reimann

IPC分类号： C09K15/08 ,  C08K5/13 ,  C07C309/62 ,  C10L1/18 ,  C10L1/22

CPC分类号： C10L1/143 ,  C10L1/1641 ,  C10L1/1835 ,  C10L1/195 ,  C10L1/1981 ,  C10L1/1985 ,  C10L1/221 ,  C10L1/2222 ,  C10L1/2225 ,  C10L1/224 ,  C10L1/2364 ,  C10L1/2383 ,  C10L1/2475 ,  C10L10/14

摘要： Mineral oil distillates having an aromatics content of less than 21% by weight, a water content of less than 150 ppm and a conductivity of at least 50 pS/m, and comprising from 0.1 to 200 ppm of at least one alkylphenol-aldehyde resin (constituent I) which includes a structural element of the formula in which R5 is C1-C200-alkyl or C2-C200-alkenyl, O—R6 or O—C(O)—R6, R6 is C1-C200-alkyl or C2-C200-alkenyl and n is from 2 to 100, and from 0.1 to 200 ppm of at least one polar oil-soluble nitrogen compound (constituent II), excluding those mineral oil distillates in which between 0.001 and 10 ppm of an oil-soluble, organic sulfonic acid-ammonium salt are present.

摘要翻译： 芳族化合物含量小于21重量％，含水量小于150ppm，电导率至少为50pS / m的矿物油馏分，并且包含0.1至200ppm的至少一种烷基酚醛树脂（ 组分I），其包括其中R 5是C 1 -C 20 - 烷基或C 2 -C 20 - 烯基，O-R 6或O-C（O）-R 6的下式的结构元件，R 6是C 1 -C 20 - 烷基或C 2 -C 20 - C 200 - 烯基，n为2〜100，和0.1〜200ppm的至少一种极性油溶性氮化合物（成分II），不包括那些矿物油馏分，其中0.001〜10ppm的油溶性， 有机磺酸铵盐存在。

公开(公告)号：US08153567B2

公开(公告)日：2012-04-10

申请号：US11644228

申请日：2006-12-22

申请人： Matthias Krull ,  Robert Janssen ,  Werner Reimann

发明人： Matthias Krull ,  Robert Janssen ,  Werner Reimann

IPC分类号： C10L1/18 ,  C10M133/56

CPC分类号： C10L1/143 ,  C10L1/146 ,  C10L1/1641 ,  C10L1/196 ,  C10L1/1981 ,  C10L1/1985 ,  C10L1/2222 ,  C10L1/2225 ,  C10L1/224 ,  C10L1/2383 ,  C10L10/14

摘要： The invention provides for the use of at least one oil-soluble polyoxyalkylene compound,this polyoxyalkylene compound being an oil-soluble ester, ether or ether/ester of alkoxylated polyols having at least three repeat alkoxy units derived from alkylene oxides having from 2 to 5 carbon atoms per OH group of the polyol which bears at least two aliphatic hydrocarbon radicals having from 12 to 30 carbon atoms for improving the response behavior of mineral oil cold flow improvers in middle distillates which comprise at least one ashless, nitrogen-containing detergent additive which is an oil-soluble amphiphilic compound which comprises at least one alkyl or alkenyl radical which is bonded to a polar group, the alkyl or alkenyl radical comprising from 10 to 500 carbon atoms and the polar group comprising 2 or more nitrogen atoms.

摘要翻译： 本发明提供至少一种油溶性聚氧化烯化合物的用途，该聚氧化烯化合物是具有至少三个衍生自具有2至5个碳原子的氧化烯的重复烷氧基单元的油溶性酯，醚或醚/ 含有至少两个具有12至30个碳原子的脂族烃基的多元醇OH基团的碳原子，用于改善中间馏分中矿物油冷流改进剂在至少一种无灰含氮洗涤剂添加剂中的响应行为， 是一种油溶性两亲化合物，其包含至少一个与极性基团键合的烷基或烯基，所述烷基或烯基包含10至500个碳原子，极性基团包含2个或更多个氮原子。

公开(公告)号：USRE40758E1

公开(公告)日：2009-06-23

申请号：US10938495

申请日：2004-09-10

申请人： Matthias Krull ,  Werner Reimann

发明人： Matthias Krull ,  Werner Reimann

IPC分类号： C10L1/18 ,  C10L1/22

CPC分类号： C10L1/143 ,  C10L1/14 ,  C10L1/1616 ,  C10L1/1824 ,  C10L1/1852 ,  C10L1/1855 ,  C10L1/1881 ,  C10L1/1883 ,  C10L1/1885 ,  C10L1/1888 ,  C10L1/19 ,  C10L1/191 ,  C10L1/1966 ,  C10L1/1981 ,  C10L1/221 ,  C10L1/2222 ,  C10L1/2225 ,  C10L1/224 ,  C10L1/2364 ,  C10L1/238 ,  C10L1/2383 ,  C10L1/2387 ,  C10L10/04 ,  C10L10/08 ,  C10L10/14

摘要： The invention relates to low-temperature-stabilized additives for fuel oils having a sulfur content of up 0.05% by weight, comprising fatty acid mixtures of A1) from 1 to 99% by weight of at least one saturated mono- or dicarboxylic acid having from 6 to 50 carbon atoms, A2) from 1 to 99% by weight of at least one unsaturated mono- or dicarboxylic acid having from 6 to 50 carbon atoms, and B) at least one polar nitrogen-containing compound which is effective as paraffin dispersant in middle distillates, in an amount of from 0.01 to 90% by weight, based on the total weight of A1), A2) and B); and to the use of said mixtures for improving the lubrication properties of low-sulfur middle distillates.

摘要翻译： 本发明涉及具有0.05重量％以上硫含量的燃料油的低温稳定添加剂，其包含A1至1重量％的至少一种饱和的单羧酸或二羧酸的脂肪酸混合物 6至50个碳原子，A2）1至99重量％的至少一种具有6至50个碳原子的不饱和单羧酸或二羧酸，和B）至少一种作为石蜡分散剂有效的极性含氮化合物 在中间馏分中，基于A1），A2）和B）的总重量，其量为0.01至90重量％。 以及使用所述混合物来改善低硫中间馏分的润滑性能。

公开(公告)号：US06652610B2

公开(公告)日：2003-11-25

申请号：US09760319

申请日：2001-01-11

申请人： Matthias Krull ,  Werner Reimann

发明人： Matthias Krull ,  Werner Reimann

IPC分类号： C10L118

CPC分类号： C10L10/08 ,  C10L1/143 ,  C10L1/1852 ,  C10L1/1881 ,  C10L1/191 ,  C10L1/1973 ,  C10L1/1981 ,  C10L1/2225 ,  C10L1/224 ,  C10L1/2364 ,  C10L1/24 ,  C10L10/04 ,  C10L10/14

摘要： The invention relates to additives for improving cold-flow and lubricating properties of fuel oils, comprising A) 5-95% by weight of at least one oil-soluble amphiphile of the formula  in which R1 is an alkyl, alkenyl, hydroxyalkyl or aromatic radical having 1 to 50 carbon atoms, X is NH, NR3, O or S, y is 1, 2, 3 or 4, R2 is hydrogen or an alkyl radical carrying hydroxyl groups and having 2 to 10 carbon atoms and R3 is an alkyl radical carrying nitrogen and/or hydroxyl groups and having 2 to 10 carbon atoms or C1-C20-alkyl, and B) 5 to 95% by weight of a terpolymer containing from 10 to 35 mol % of structural units derived from the vinyl ester of a carboxylic acid having 2 to 4 carbon atoms, from 1 to 15 mol % of structural units derived from the vinyl ester of a neocarboxylic acid having 8 to 15 carbon atoms, and structural units of ethylene to 100 mol %, having a melt viscosity, measured at 140° C., of from 20 to 10,000 mPas.

摘要翻译： 本发明涉及用于改善燃料油的冷流和润滑性能的添加剂，包括A）5-95重量％的至少一种油溶性两性物质，其中R 1是烷基，烯基，羟基烷基或芳族 具有1至50个碳原子的基团，X是NH，NR 3，O或S，y是1,2,3或4，R 2是氢或带有羟基并具有2至10个碳原子的烷基 原子和R 3是带有氮和/或羟基并且具有2-10个碳原子或C 1 -C 20烷基的烷基，B）5至95重量％的含有10至35摩尔％ 衍生自碳原子数为2〜4的羧酸的乙烯基酯的结构单元，1〜15摩尔％的来自碳原子数为8〜15的新羧酸的乙烯基酯的结构单元，乙烯的结构单元为100〜 mol，在140℃下测得的熔体粘度为20至10,000mPa·s。

公开(公告)号：US06565616B1

公开(公告)日：2003-05-20

申请号：US09808454

申请日：2001-03-14

申请人： Matthias Krull ,  Thomas Volkmer ,  Werner Reimann

发明人： Matthias Krull ,  Thomas Volkmer ,  Werner Reimann

IPC分类号： C10L118

CPC分类号： C10L1/195 ,  C10L1/146 ,  C10L1/1963 ,  C10L1/1966 ,  C10L1/1973 ,  C10L1/2364

摘要： The invention relates to blends of copolymers containing structural units of olefins, derivatives of dibasic carboxylic acids and, if required, polyolefins and, structural units of ethylene and vinyl esters of tertiary carboxylic acids, and their use as additives to fuel oils for improving their cold flow properties.

摘要翻译： 本发明涉及含有烯烃的结构单元，二元羧酸的衍生物和根据需要的聚烯烃和乙烯和叔羧酸的乙烯基酯的结构单元的共聚物的共混物，以及它们作为燃料油添加剂用于改善其冷的用途 流量属性。

公开(公告)号：US06475250B2

公开(公告)日：2002-11-05

申请号：US09760318

申请日：2001-01-11

申请人： Matthias Krull ,  Werner Reimann

发明人： Matthias Krull ,  Werner Reimann

IPC分类号： C10L118

CPC分类号： C10L10/08 ,  C10L1/143 ,  C10L1/1852 ,  C10L1/1881 ,  C10L1/191 ,  C10L1/1973 ,  C10L1/1981 ,  C10L1/2225 ,  C10L1/224 ,  C10L1/2364 ,  C10L1/24

摘要： The invention relates to additives for improving cold-flow and lubricating properties of fuel oils, comprising A) 5-95% by weight of at least one oil-soluble amphiphile of the formulae in which R1 is an alkyl, alkenyl, hydroxyalkyl or aromatic radical having 1 to 50 carbon atoms, X is NH, NR3, O or S, y is 1, 2, 3 or 4, R2 is an alkyl radical carrying hydroxyl groups and having 2 to 10 carbon atoms and R3 is an alkyl radical carrying nitrogen and/or hydroxyl groups and having 2 to 10 carbon atoms or a C1-C20-alkyl radical, and B) 5 to 95% by weight of a terpolymer of ethylene, the vinyl ester of one or more aliphatic, linear or branched monocarboxylic acids which contain 2 to 20 carbon atoms in the molecule and a C5-C7-olefin containing from 9 to 18 mol % of vinyl ester and from 0.5 to 5 mol % of olefin (based in each case on the terpolymer), having a melt viscosity, measured at 140° C., of from 20 to 10,000 mPas.

摘要翻译： 本发明涉及用于改善燃料油的冷流和润滑性能的添加剂，包括A）5-95重量％的至少一种油溶性二醇，其中R1是具有1个烷基，烯基，羟基烷基或芳族基团的烷基，链烯基，羟基烷基或芳族基团 至50个碳原子，X是NH，NR 3，O或S，y是1,2,3或4，R 2是带有羟基且具有2至10个碳原子的烷基，R 3是带有氮和/ 或羟基并且具有2至10个碳原子或C 1 -C 20烷基，和B）5至95重量％的乙烯三元共聚物，一种或多种脂族，直链或支链单羧酸的乙烯基酯，其含有2 至20个碳原子和含有9至18摩尔％乙烯基酯和0.5至5摩尔％烯烃（基于每种情况下在三元共聚物上）的C5-C7-烯烃，其熔体粘度在 140℃，为20至10,000mPas。