Abstract:
Described herein are associative polymers capable of controlling a physical and/or chemical property of non-polar compositions and related compositions, methods and systems. Associative polymers herein described have a non-polar backbone and functional groups presented at ends of the non-polar backbone, with a number of the functional groups presented at the ends of the non-polar backbone formed by associative functional groups capable of undergoing an associative interaction with another associative functional group with an association constant (k) such that the strength of each associative interaction is less than the strength of a covalent bond between atoms and in particular less than the strength of a covalent bond between backbone atoms.
Abstract:
Described herein are associative polymers capable of controlling a physical and/or chemical property of non-polar compositions and related compositions, methods and systems. Associative polymers herein described have a non-polar backbone and functional groups presented at ends of the non-polar backbone, with a number of the functional groups presented at the ends of the non-polar backbone formed by associative functional groups capable of undergoing an associative interaction with another associative functional group with an association constant (k) such that the strength of each associative interaction is less than the strength of a covalent bond between atoms and in particular less than the strength of a covalent bond between backbone atoms.
Abstract:
The invention relates to the use, in a hydrocarbon distillate with a boiling temperature of between 150 and 450° C. and a crystallization onset temperature as measured by Differential calorimetric Analysis of greater than or equal to −50° C., preferably of −5° C. to +10° C., of a homopolymer obtained from an olefinic ester of carboxylic acid of 3 to 12 carbon atoms and from a fatty alcohol containing a chain of more than 16 carbon atoms and optionally an olefinic double bond, as a compound for revealing the efficiency of filterability additives based on copolymer and/or terpolymers of ethylene and of vinyl ester of a carboxylic acid of 3 to 12 carbon atoms, and of a monoalcohol containing 1 to 10 carbon atoms. The invention is also directed to an additive composition comprising a conventional hydrocarbon filterability additive in combination with an efficiency reveal additive, and also to the combustion fuels, motor fuel and oil fuel that comprise these additive combinations.
Abstract:
Mineral oil distillates having an aromatics content of less than 21% by weight, a water content of less than 150 ppm and a conductivity of at least 50 pS/m, and comprising from 0.1 to 200 ppm of at least one alkylphenol-aldehyde resin (constituent I) which includes a structural element of the formula in which R5 is C1-C200-alkyl or C2-C200-alkenyl, O—R6 or O—C(O)—R6, R6 is C1-C200-alkyl or C2-C200-alkenyl and n is from 2 to 100, and from 0.1 to 200 ppm of at least one polar oil-soluble nitrogen compound (constituent II), excluding those mineral oil distillates in which between 0.001 and 10 ppm of an oil-soluble, organic sulfonic acid-ammonium salt are present.
Abstract:
The invention relates to fuel oils comprising a larger proportion of middle distillates having a sulfur content of at most 350 ppm and an aromatics content of at most 22% by weight, and also a smaller proportion of at least one copolymer of ethylene and vinyl esters, said copolymer containing a) bivalent structural units derived from ethylene of the formula 1 —CH2—CH2— (1) b) from 5 to 12 mol % of bivalent structural units of the formula 2 where R1 is saturated, branched C5-C18-alkyl, and c) from 4 to 13 mol % of bivalent structural units of the formula 3 and the sum of the molar proportions of structural units of the formulae 2 and 3 being between 12 and 16 mol %, to the corresponding polymers, and also to their use for improving the cold flow behavior of middle distillates having a sulfur content of at most 350 ppm and an aromatics content of at most 22% by weight.
Abstract:
The invention relates to the use, in a hydrocarbon distillate with a boiling temperature of between 150 and 450° C. and a crystallization onset temperature as measured by Differential Calorimetric Analysis of greater than or equal to −50° C., preferably of −5° C. to +10° C., of a homopolymer obtained from an olefinic ester of carboxylic acid of 3 to 12 carbon atoms and from a fatty alcohol containing a chain of more than 16 carbon atoms and optionally an olefinic double bond, as a compound for revealing the efficiency of filterability additives based on copolymer and/or terpolymers of ethylene and of vinyl ester of a carboxylic acid of 3 to 12 carbon atoms, and of a monoalcohol containing 1 to 10 carbon atoms. The invention is also directed to an additive composition comprising a conventional hydrocarbon filterability additive in combination with an efficiency reveal additive, and also to the combustion fuels, motor fuel and oil fuel that comprise these additive combinations.
Abstract:
Drag reducing compositions comprising polymer particles, where the polymer particles include copolymers comprising the residues of at least one methacrylate monomer and at least one comonomer having a polymerizable vinyl group, where the comonomer has no more than one pendant substituent per vinyl carbon. The drag reducing compositions can have improved dissolution rates in hydrocarbon-containing fluids. The drag reducing compositions can be added to a hydrocarbon-containing fluid to decrease the pressure drop associated with the turbulent flow of the hydrocarbon-containing fluid through a conduit.
Abstract:
The present invention relates to the preparation of Ω-(dimethylisopropenylbenzylurethane) polyalkylene glycols with α-alkoxy or α-dihydroxy groups and to the use thereof as hydrolysis-stable macromonomers for the dispersion and crosslinking of polymers in which, A is C2-C4-alkylene, m is an integer from 5 to 900, and R is C1-C20-alkyl, C6-C18-aryl or a radical according to formula 2a, 2b, 2c, 3a, 3b or 3c which is bonded to the terminal oxygen atom of the alkoxy group (A-O) in formula 1 via the valence denoted by *, and in which A is not exclusively C3- or C4-alkylene.
Abstract:
A method of operating a turbo charged diesel engine is provided where a viscosity increasing component in a diesel fuel composition is used, to improve the acceleration performance, at low engine speeds (for example up to 2200 rpm). This method may be used for reducing the engine speed at which the turbo charger reaches its maximum speed when accelerating at low engine speeds, or reducing the time taken for the turbo charger to reach its maximum speed. It may mitigate a deterioration in the acceleration performance of the engine due to another cause. The VK 40 of the resultant fuel composition is suitably 2.8 mm2/s (centistokes) or greater. The viscosity increasing component may in particular be a Fischer-Tropsch derived fuel component, an oil or a fatty acid alkyl ester. A density increasing component may be used in the fuel composition together with the viscosity increasing component.
Abstract:
A method for increasing removal of drag reducer additive (DRA) from liquid hydrocarbon fuel. The method comprises producing contaminated liquid hydrocarbon fuel comprising a concentration of removable DRA comprising a quantity of one or more polar groups, and contacting the contaminated liquid hydrocarbon fuel with an amount of one or more removal agents under removal conditions effective to produce a reduced concentration of the removable DRA.