摘要:
A gas generant composition contains as a fuel a mixture of a major portion of a triazole or tetrazole and a minor portion of a water soluble fuel; and an oxidizer component, at least 20 wt % of said oxidizer component being a transition metal oxide, such as CuO. Generant compositions in accordance with the invention autoignite in a range around 170.degree. C., providing autoignition of the generant without the need for separate autoignition devices. Also, the generant compositions are useful as autoignition pyrotechnic in autoignition devices.
摘要:
Poly(caprolactone) polymers are provided having molecular weights of 4000 or higher, are used to form propellant binders. When the high molecular weight poly(caprolactone) polymers are used in propellant formulations and cured with isocyanates of adequate functionality, propellants are produced having improved stress and strain characteristics relative to presently formulated propellants having binders of cured, lower molecular weight poly(caprolactone) polymers.
摘要:
2-hydroxymethyl-1,3-propanediol trinitrate, processes for its preparation, and compounds related thereto are disclosed. The final product is useful as a platicizer of relatively low volatility in double based propellant compositions and as a liquid explosive.
摘要:
A method for increasing the burn rate of a gas generant formulation is provided involving the addition of a quantity of at least one transition metal complex of diammonium bitetrazole to the gas generant formulation.
摘要:
Liquid gas generant compositions are aqueous solutions of hydroxylammonium nitrate as the oxidizer and a fuel selected from the group consisting of nitrate salts of amines of the formulae: A.sup.1) an amino tetrazole or amino triazole, A.sup.2) an amine of the formulae (I) (NHZ).sub.2 --C.dbd.O, (II) (NHZ).sub.2 --C.dbd.NZ, (III) HN--(CO--NHZ).sub.2, where the Zs are the same or different and are selected from H and NH.sub.2, A.sup.3) C.sub.2 -C.sub.3 -alkyldiamine, and mixtures of the nitrate salts of amines of the above formulae.
摘要:
A gas generant composition comprises between about 30 and about 85 wt. % of A) fuel, and between about 15 and about 70 wt % of B) oxidizer based on total weight of A) plus B). At least about 60 wt %, up to 100 wt % of the fuel A) comprises an nitrate salt of a polyamine of the general formula selected from the group consisting of: ##STR1## wherein in formulae (I)-(III) the Zs are the same or different and are selected from H and NH.sub.2,(IV) C.sub.2 -C.sub.3 -alkyl diamine, and mixtures thereof. At least about 60 wt %, up to 100 wt % of the oxidizer B) comprises basic copper(II) nitrate, i.e. Cu(NO.sub.3).sub.2.3Cu(OH).sub.2 and/or cobalt(III)triammine trinitrate, i.e., Co(NH.sub.3).sub.3.(NO.sub.3).sub.3.
摘要:
Alkali metal perchlorate-containing gas generant compositions which, upon combustion, produce or result in an improved effluent and related methods for generating an inflation gas for use in an inflatable restraint system are provided. Such alkali metal perchlorate-containing gas generant compositions include at least one alkali metal perchlorate present with a mean particle size in excess of 100 microns. Such alkali metal perchlorate-containing gas generant compositions also include or contain a suitable non-azide, organic, nitrogen-containing fuel and at least one copper-containing compound selected from the group consisting of basic copper nitrate, cupric oxide, copper diammine dinitrate-ammonium nitrate mixture wherein ammonium nitrate is present in the mixture in a range of about 3 to about 90 weight percent, copper diammine bitetrazole, a copper-nitrate complex resulting from reaction of 5-aminotetrazole with basic copper nitrate and combinations thereof.