Abstract:
Deinked paper/wood pulps are improvedly bleached to high levels of whiteness by conjointly treating such pulps with a sulfite bleaching agent, e.g., Na.sub.2 SO.sub.3, NaHSO.sub.3 or mixture thereof, or SO.sub.2 and NaOH, and a reducing agent more electronegative than the sulfite ion, e.g., thiourea dioxide, sodium borohydride or sodium dithionite, in a reaction medium having an initial pH ranging from 6 to 12, advantageously followed by washing sulfite and reducing agent values from the bleached pulp and then treating the washed pulp with hydrogen peroxide in an aqueous alkaline medium.
Abstract translation:通过用亚硫酸盐漂白剂(例如Na 2 SO 3,NaHSO 3或其混合物)或SO 2和NaOH联合处理这种纸浆,以及比亚硫酸盐离子更具电负性的还原剂,将脱墨的纸/木纸浆漂白至高白度。 ,二氧化硫脲,硼氢化钠或连二亚硫酸钠,在初始pH范围为6至12的反应介质中,有利地随后从漂白的纸浆中洗涤亚硫酸盐和还原剂值,然后用碱性水溶液中的过氧化氢处理洗涤过的纸浆 中。
Abstract:
The acyl cyanides (nitriles) are prepared by reacting an acid halide with an alkali metal cyanide, in the presence of an alkylene oxide compound and a catalytically effective amount of water.
Abstract:
The acyl cyanides (nitriles), notably benzoyl cyanide, are prepared by reacting an acid halide with an alkali metal cyanide, in an anhydrous solvent medium, in the presence of an alkylene oxide compound and a polar compound other than water, e.g., glycerol, ethylene glycol, formamide or a sugar derivative.
Abstract:
Bleached chemithermomechanical wood pulp having a high degree of whiteness is economically prepared by mechanically disintegrating and chemically digesting lignocellulosic material with sulfite at a temperature of at least 100.degree.C. under saturated water vapor pressure and thereafter bleaching the pulp thus treated with hydrogen peroxide in an alkaline medium, and wherein no solids or liquids are removed from the pulp from the outset of treatment through completion of the bleaching step.
Abstract:
The amount of peroxide contaminants in H.sub.2 O.sub.2 bleached/dried vegetable material is reduced to a value on the order of less than about 1%, even approaching nil, by heat-treating such bleached/dried vegetable material at a temperature of at least 60.degree. C. in a confined atmosphere such that its amount by weight of water remains essentially the same during the heat-treatment.
Abstract translation:通过在至少60℃的温度下对这种漂白/干燥的植物材料进行热处理,将H 2 O 2漂白/干燥的植物材料中的过氧化物污染物的量减少到小于约1%的数量级甚至接近零的值 在密闭的气氛中,使其在热处理过程中水的重量含量基本相同。
Abstract:
Process for the decomposition of complexes of orthobenzoyl-benzoic acid, hydrogen fluoride, and boron trifluoride in which the complex is subjected to the action of sulfuric acid in a concentration of at least about 96% by weight or to the action of an oleum, under atmospheric pressure or under a pressure lower than atmospheric pressure.
Abstract:
The present invention relates to a method for producing 1,2,3,3,3-pentafluoropropane, involving reacting gaseous phase 1,2,3,3,3-pentafluoropropene with hydrogen in a superstoichimetric amount in the presence of a hydrogenation catalyst in a reactor, and recirculating a part of the gaseous effluent from the reactor.
Abstract:
The invention relates to coated reactors resistant to acid corrosion, the production method thereof and the use of same in processes in superacid media. More specifically, the invention relates to a reactor comprising an inner metal wall having a fluoropolymer coating anchored thereto using a perforated sheet positioned between the inner metal wall and the fluoropolymer coating. The surface of the sheet that is in contact with the metal wall of the reactor has a sufficient roughness in order to form a free space (for gases) between same and the metal wall of the reactor. In addition, the reactor is provided with a device for maintaining the pressure in the free space below that in the reactor.
Abstract:
A subject-matter of the invention is a process for the preparation of fluoroolefin compounds. It relates more particularly to a process for the manufacture of a compound of formula (I) CF3—CF=CHX in which X represents a hydrogen or fluorine atom, comprising at least one stage of dehydrofluorination of a compound of formula (II) CF3—CHF—CHFX during which the compound of formula (II) is brought into contact with a mixture composed of water and of potassium hydroxide in which the potassium hydroxide is present in an amount of between 58 and 86% by weight.
Abstract:
The invention relates to a reinforced fluoropolymer plate comprising a fluoropolymer layer on one of the faces thereof and a carbon fiber sheet on the other face of same, whereby at least part of the carbon fiber sheet is impregnated with fluoropolymer. The invention also relates to an acid-corrosion-resistant chemical reactor comprising said plates, the production methods thereof and the uses of same in processes in superacid media.