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    Odorless modified silicone compound, cosmetic preparation containing the same, and method of purifying modified silicone compound having branch polymer comprising hydrophilic group
    12.
    发明授权
    Odorless modified silicone compound, cosmetic preparation containing the same, and method of purifying modified silicone compound having branch polymer comprising hydrophilic group 有权
    无水改性硅氧烷化合物，含有该化合物的化妆品，以及具有包含亲水基团的支链聚合物的改性硅氧烷化合物的纯化方法

    公开(公告)号：US06784271B2

    公开(公告)日：2004-08-31

    申请号：US10221274

    申请日：2002-09-10

    申请人： Tetsuo Nakanishi

    发明人： Tetsuo Nakanishi

    IPC分类号： C08G7712

    CPC分类号： A61K8/894 ,  A61Q1/02 ,  A61Q1/06 ,  A61Q1/10 ,  A61Q1/14 ,  A61Q5/00 ,  A61Q15/00 ,  A61Q17/04 ,  A61Q19/00 ,  A61Q19/04 ,  A61Q19/10 ,  C08G77/14 ,  C08G77/34 ,  C08G77/46

    摘要： A modified silicone compound having a branch polymer comprising a hydrophilic group, this compound being synthesized by performing an addition reaction between an organohydrogenpolysiloxane, and at least one compound chosen from an alkenylated polyoxyalkenylated compound, an alkenylated glycerine compound and an alkenylated sugar in the presence of a platinum catalyst or rhodium catalyst, and a cosmetic material containing this modified silicone compound. This compound is purified by decomposing aldehyde condensation products remaining in the silicone by alkylating the remaining unsaturated bonds after hydrogenating the reaction liquor after said addition reaction, and treating with an aqueous solution of pH 7 or lower containing an acidic substance, or decomposing the propenyl etherated polyether in the reaction liquor after said addition reaction by treating with an aqueous solution of pH 7 or lower containing an acidic substance, and then alkylating the generated aldehydes and alkenylated ether compounds by hydrogenation. The degree of unsaturation (meq/g) in the modified silicone compound is 0.002 or less. The generation amount of aldehydes when heat ageing is performed in 0.23N hydrochloric acid at 50° C. for 0.5 hours is 70 ppm or less of the modified silicone compound.

    摘要翻译： 一种具有包含亲水基团的分支聚合物的改性硅氧烷化合物，该化合物是通过在有机氢聚硅氧烷和至少一种选自烯基化的聚氧化烯化的化合物，链烯基化的甘油化合物和链烯基糖的化合物之间进行加成反应而合成的， 铂催化剂或铑催化剂，以及含有该改性硅酮化合物的化妆品。 该化合物通过在加成反应后氢化反应液后将残留的不饱和键进行烷基化，用含有酸性物质的pH7以下的水溶液进行处理，分解存在于硅氧烷中的醛缩合产物， 在通过用含有酸性物质的pH7或更低的水溶液处理之后，在所述加成反应后的反应液中的聚醚，然后通过氢化将所生成的醛和烯基醚化合物烷基化。 改性硅氧烷化合物中的不饱和度（meq / g）为0.002以下。 在0.23N盐酸中，在50℃下进行0.5小时热老化时的醛的产生量为70ppm以下。

    Preparation of contract mass for alkylhalosilane production and process for producing alkylhalosilanes
    13.
    发明授权
    Preparation of contract mass for alkylhalosilane production and process for producing alkylhalosilanes 失效
    制备烷基卤硅烷生产的合同质量和制备烷基卤代硅烷的方法

    公开(公告)号：US6090966A

    公开(公告)日：2000-07-18

    申请号：US76153

    申请日：1998-05-12

    申请人： Tetsuo Nakanishi ,  Tetsuya Inukai ,  Kazumasa Tsukioka ,  Hiroshi Nakayama ,  Yukinori Satoh

    发明人： Tetsuo Nakanishi ,  Tetsuya Inukai ,  Kazumasa Tsukioka ,  Hiroshi Nakayama ,  Yukinori Satoh

    IPC分类号： B01J23/72 ,  B01J37/08 ,  C07B61/00 ,  C07F7/14 ,  C07F7/16

    CPC分类号： B01J23/72 ,  C07F7/14

    摘要： Alkylhalosilanes are produced by first fluidizing a metallic silicon powder with an inert gas, preheating the silicon powder at a temperature between 200.degree. C. and a steady reaction temperature while keeping the silicon powder fluidized, adding a copper catalyst to the preheated silicon powder to form a contact mass, and feeding an alkyl halide into the contact mass whereby the alkylhalosilanes are formed by direct synthesis. This process prevents the copper catalyst from being sintered by thermal hysteresis and activates a high catalysis on the contact mass at the start of reaction. The desired dialkyldihalosilane can be produced at a high selectivity.

    摘要翻译： 烷基卤代硅烷首先用惰性气体流化金属硅粉末，在保持硅粉末流动的同时在200℃和稳定的反应温度之间预热硅粉末，向预热的硅粉末中加入铜催化剂以形成 接触物质，并将烷基卤化物进料到接触物质中，由此通过直接合成形成烷基卤代硅烷。 该过程防止铜催化剂通过热滞后烧结，并且在反应开始时对接触质量起到高催化作用。 所需的二烷基二卤硅烷可以高选择性制备。

    Preparation of alkylhalosilanes
    14.
    发明授权
    Preparation of alkylhalosilanes 失效
    烷基卤硅烷的制备

    公开(公告)号：US6025513A

    公开(公告)日：2000-02-15

    申请号：US106145

    申请日：1998-06-29

    申请人： Tetsuo Nakanishi ,  Tetsuya Inukai ,  Kazumasa Tsukioka ,  Hiroshi Nakayama ,  Yukinori Satoh

    发明人： Tetsuo Nakanishi ,  Tetsuya Inukai ,  Kazumasa Tsukioka ,  Hiroshi Nakayama ,  Yukinori Satoh

    IPC分类号： C07F7/16

    CPC分类号： C07F7/16

    摘要： An alkylhalosilane is prepared by charging a reactor with a contact mass comprising a metallic silicon powder and a copper catalyst, and feeding an alkyl halide into the reactor whereby the silane is formed by direct synthesis. The contact mass contains 1-10,000 ppm of elemental boron. The addition of boron to the contact mass is effective for increasing the throughput of dialkyldihalosilane at desired STY in an inexpensive manner while suppressing formation of unnecessary hydrosilanes and disilanes.

    摘要翻译： 通过向反应器中加入包含金属硅粉末和铜催化剂的接触物质，并将烷基卤化物进料到反应器中制备烷基卤硅烷，由此通过直接合成形成硅烷。 接触质量含有1-10,000 ppm的元素硼。 向接触物质中加入硼对于以便宜的方式在期望的STY下提高二烷基二卤代硅烷的通量是有效的，同时抑制不必要的氢硅烷和二硅烷的形成。

    Preparation of alkylhalosilanes
    15.
    发明授权
    Preparation of alkylhalosilanes 失效
    烷基卤硅烷的制备

    公开(公告)号：US5986123A

    公开(公告)日：1999-11-16

    申请号：US053059

    申请日：1998-04-01

    申请人： Hiroshi Nakayama ,  Tetsuo Nakanishi ,  Kazumasa Tsukioka ,  Yukinori Satoh

    发明人： Hiroshi Nakayama ,  Tetsuo Nakanishi ,  Kazumasa Tsukioka ,  Yukinori Satoh

    IPC分类号： B01J23/72 ,  B01J35/00 ,  C07B61/00 ,  C07F7/16

    CPC分类号： C07F7/16

    摘要： An alkylhalosilane is prepared by charging a reactor with a contact mass comprising a metallic silicon powder and a copper catalyst, and feeding an alkyl halide into the reactor whereby the silane is formed by direct synthesis. The use of a metallic silicon powder having a specific particle size distribution ensures effective fluidization whereby the alkylhalosilane of quality is formed at a high selectivity and in high yields.

    摘要翻译： 通过向反应器中加入包含金属硅粉末和铜催化剂的接触物质，并将烷基卤化物进料到反应器中制备烷基卤硅烷，由此通过直接合成形成硅烷。 使用具有特定粒度分布的金属硅粉末确保有效的流化，从而以高选择性和高产率形成质量的烷基卤代硅烷。

    Preparation of alkylhalosilanes
    16.
    发明授权
    Preparation of alkylhalosilanes 失效
    烷基卤硅烷的制备

    公开(公告)号：US5847181A

    公开(公告)日：1998-12-08

    申请号：US812942

    申请日：1997-03-04

    申请人： Tetsuo Nakanishi ,  Tetsuya Inukai ,  Kazumasa Tsukioka ,  Hiroshi Nakayama ,  Yukinori Satoh

    发明人： Tetsuo Nakanishi ,  Tetsuya Inukai ,  Kazumasa Tsukioka ,  Hiroshi Nakayama ,  Yukinori Satoh

    IPC分类号： C07F7/12 ,  C07F7/16

    CPC分类号： C07F7/16

    摘要： An alkylhalosilane is prepared by charging a reactor with a contact mass comprising metallic silicon powder and a copper catalyst and feeding a reactant gas containing an alkyl halide into the reactor whereby the silane is formed by direct synthesis. A phosphorus compound is added to the contact mass in an amount of 3,000-10,000 ppm calculated as phosphorus. The invention produces a more amount of dialkyldihalosilane in a desirable STY while minimizing the amount of unnecessary disilanes.

    摘要翻译： 通过将包含金属硅粉末和铜催化剂的接触物质装入反应器并将含有烷基卤化物的反应气体进料到反应器中制备烷基卤硅烷，由此通过直接合成形成硅烷。 按磷计算，磷化合物的量为3,000〜10000ppm。 本发明在所需的STY中产生更多量的二烷基二卤硅烷，同时使不需要的二硅烷的量最小化。

    Flame retardant composition and method for use in synthetic thermoplastic resins
    17.
    发明授权
    Flame retardant composition and method for use in synthetic thermoplastic resins 失效
    阻燃剂组合物和用于合成热塑性树脂的方法

    公开(公告)号：US5532302A

    公开(公告)日：1996-07-02

    申请号：US202630

    申请日：1994-02-28

    申请人： Tetsuo Nakanishi ,  Mitsuo Asai ,  Hiroyuki Ohata ,  Keiichi Uchida

    发明人： Tetsuo Nakanishi ,  Mitsuo Asai ,  Hiroyuki Ohata ,  Keiichi Uchida

    IPC分类号： C08L33/06 ,  C08L25/06 ,  C08L33/04 ,  C08L43/00 ,  C08L43/04 ,  C08L51/08 ,  C08J5/10 ,  C08K5/52 ,  C08L25/02

    CPC分类号： C08L25/06 ,  C08L51/085

    摘要： An improved flame-retardant composition and method for its use are provided. The composition imparts flame retardency to synthetic thermoplastic resins to prevent dripping of the melt of the resin when the resin is burnt. The composition comprises a flame retardant agent such as phosphate ester compound, optionally combined with a metal hydroxide, and an organopoly-siloxane-based graft copolymer of a (meth)acrylic acid ester such as methyl(meth)-acrylate. The flame retardant is used in an amount from 1-50 parts by weight per 100 parts by weight of the synthetic resin, and the graft copolymer provides 0.5 to 20 parts by weight of an organosilicone group per 100 parts by weight of the synthetic resin.

    摘要翻译： 提供了改进的阻燃组合物及其使用方法。 该组合物赋予合成热塑性树脂阻燃性，以防止树脂燃烧时树脂熔体滴落。 组合物包含任选与金属氢氧化物结合的磷酸酯化合物等阻燃剂，（甲基）丙烯酸甲酯等（甲基）丙烯酸酯的有机聚硅氧烷类接枝共聚物。 阻燃剂的使用量为每100重量份合成树脂1-50重量份，接枝共聚物每100重量份合成树脂提供0.5-20重量份的有机硅酮基。