Abstract:
Provided is a fluoride phosphor having higher durability. The fluoride phosphor includes a first fluoride and a second fluoride deposited on at least part of a surface of the first fluoride. The first fluoride has a composition containing an alkali metal, Si, Al, Mn, and F, wherein, when the number of moles of the alkali metal is taken as 2, the total number of moles of Si, Al, and Mn is 0.9 to 1.1; the number of moles of Al is more than 0 and less than 0.10; the number of moles of Mn is more than 0 and less than 0.20; and the number of moles of F is 5.9 to 6.1. The second fluoride has a composition which contains an alkali metal, Si, and F, and which is substantially free of Al and Mn.
Abstract:
A fluoride phosphor, comprising fluoride particles having an average particle size of 0.1 μm to 7 μm and a maximum particle size of 1 μm to 18 μm, wherein a ratio of the maximum particle size with respect to the average particle size is higher than 1. The fluoride particles have a composition containing an element M containing at least one selected from the group consisting of Group 4 elements, Group 13 elements, and Group 14 elements; an alkali metal; Mn; and F. In the composition, when the number of moles of the alkali metal is 2, the number of moles of Mn is more than 0 but less than 0.2, the number of moles of the element M is more than 0.8 but less than 1, and the number of moles of F is more than 5 but less than 7.
Abstract:
A fluoride fluorescent material includes a composition including K, Ge, Mn4+, and F and having a molar ratio of K of 2, a total molar ratio of Ge and Mn4+ of 1, a molar ratio of Mn4+ of more than 0 and less than 0.2, and a molar ratio of F of 6 in 1 mol of the composition, has a light emission spectrum having a first light emission peak in a range of 615 nm or more and less than 625 nm having a full width at half maximum of 6 nm or less, and a second light emission peak in a range of 625 nm or more and less than 635 nm, and has an internal quantum of 85% or more efficiency under excitation of light having a wavelength of 450 nm.
Abstract:
Provided are a method of producing an aluminate fluorescent material, an aluminate fluorescent material and a light emitting device. The production method includes heat-treating a mixture prepared by mixing a compound containing at least one alkaline earth metal element selected from the group consisting of Ba, Sr and Ca, a Mg-containing compound not acting as a flux, a Mn-containing compound, an Al-containing compound, a first flux containing at least one alkali metal element selected from the group consisting of Na, K, Rb and Cs, and a Mg-containing second flux to give an aluminate fluorescent material.
Abstract:
Provided is an aluminate fluorescent material having a high emission intensity and having a composition containing a first element that contains one or more of Ba and Sr, and a second element that contains Mg and Mn. In the composition, when a molar ratio of Al is 10, a total molar ratio of the first element is a parameter a, a total molar ratio of the second element is a parameter b, a molar ratio of Sr is a product of a parameter m and the parameter a, a molar ratio of Mn is a product of a parameter n and the parameter b. The parameters a and b satisfy 0.5
Abstract:
Provided is a light-emitting device including a light-emitting element having a peak emission wavelength in a range of from 400 nm to 470 nm, and a fluorescent member including a first fluorescent material including an aluminate that contains Mg, Mn, and at least one alkali earth metal selected from the group consisting of Ba, Sr, and Ca, a second fluorescent material having a different composition from the first fluorescent material, and a third fluorescent material. The first, second and third fluorescent materials have a peak emission wavelength in a range of from 510 nm to 525 nm, from 510 nm to 550 nm, and from 620 nm to 670 nm, respectively.
Abstract:
Provided is a light emitting device capable of realizing color reproducibility in a broad range. The light emitting device contains a light emitting element having an emission peak wavelength in a range of 430 nm or more and 470 nm or less, a first fluorescent material having a composition represented by formula (I), which has an emission peak wavelength in a range of 510 nm or more and 525 nm or less and has an average particle diameter that is 10.0 μm or more and 30.0 μm or less, and a second fluorescent material having an emission peak wavelength in a range of 620 nm or more and 670 nm or less: X1aMgbMncAldOa+b+c+1.5d (I) wherein X1 represents at least one element selected from the group consisting of Ba, Sr and Ca, and a, b, c and d satisfy 0.5≦a≦1.0, 0.0≦b≦0.7, 0.3≦c≦0.7, and 8.5≦d≦13.0.
Abstract:
A red phosphor including the composition represented by the following general formula. (x-a)MgO·(a/2)Sc2O3·yMgF2·cCaF2·(1-b)GeO2·(b/2)Mt2O3:zMn4+ where x, y, z, a, b, and c satisfy 2.0≦x≦4.0, 0
Abstract:
A fluoride phosphor activated with tetravalent Mn can absorb blue light and emit red light, and is represented by the general formula: K2[M1-aMn4+aF6] (M is at least one selected from group-IV elements of Ti, Zr, and Hf and group IVB elements of Si, Ge, Sn, and a is 0
Abstract:
Provided is a fluoride phosphor that can improve reliability in a light-emitting device. The fluoride phosphor includes fluoride particles and an oxide covering at least a portion of the surface of the fluoride particles. The oxide contains at least one element selected from the group consisting of Si, Al, Ti, Zr, Sn, and Zn, and a content percentage of the oxide is in a range from 2 mass % to 30 mass %. The fluoride particles have a composition containing an element M including at least one element selected from the group consisting of Group 4 elements, Group 13 elements, and Group 14 elements, an alkali metal, Mn, and F, and when the number of moles of the alkali metal is 2, the number of moles of Mn is in a range greater than 0 and less than 0.2, the number of moles of the element M is a range greater than 0.8 and less than 1, and the number of moles of F is in a range greater than 5 and less than 7.