公开(公告)号：US5583246A

公开(公告)日：1996-12-10

申请号：US573545

申请日：1995-12-15

Applicant: Haruhiko Aida ,  Noboru Nakai ,  Osamu Isozaki

Inventor： Haruhiko Aida ,  Noboru Nakai ,  Osamu Isozaki

IPC: C08G77/445 ,  C07F7/04 ,  C08G77/02 ,  C08G77/42 ,  C09D183/04 ,  C09D183/06 ,  C07F7/18 ,  C07F7/08

CPC classification number: C08G77/02 ,  C07F7/04

Abstract: The invention provides a lactone-modified organopolysiloxane compound represented by the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are the same or different and each represents a methyl group, an ethyl group, a n-propyl group, an isopropyl group or a group represented by the formula ##STR2## wherein R.sub.5 is a methyl group, an ethyl group, a n-propyl group or an isopropyl group, X is a saturated divalent hydrocarbon group having 2 to 14 carbon atoms, and m is an integer of 1 to 3, provided that at least one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is a group represented by the formula ##STR3## wherein R.sub.5, X and m are as defined above, and n is an integer of 1 to 100. The polysiloxane compound of the invention is excellent in compatibility with various organic resins.

Abstract translation: 本发明提供由式（I）表示的内酯改性的有机聚硅氧烷化合物，其中R 1，R 2，R 3和R 4相同或不同，并且各自表示甲基，乙基，正丙基， 异丙基或由下式表示的基团：其中R 5为甲基，乙基，正丙基或异丙​​基，X为碳原子数2〜14的饱和二价烃基，m为 其中R 1，R 2，R 3和R 4中的至少一个是由下式表示的基团：其中R 5，X和m定义同上，n为1至100的整数。 本发明的聚硅氧烷化合物与各种有机树脂的相容性优异。

公开(公告)号：US5408001A

公开(公告)日：1995-04-18

申请号：US107580

申请日：1993-08-18

Applicant: Akimasa Nakahata ,  Nobushige Numa ,  Masahiro Yamane ,  Osamu Isozaki ,  Noboru Nakai

Inventor： Akimasa Nakahata ,  Nobushige Numa ,  Masahiro Yamane ,  Osamu Isozaki ,  Noboru Nakai

IPC: C08L63/00 ,  C09D201/04 ,  C08L27/12 ,  C08L27/14 ,  C08L33/14 ,  C08L63/02

CPC classification number: C08L63/00 ,  C09D201/04

Abstract: Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two-component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.

Abstract translation: 公开的是：1）包含含羟基的化合物（A），含环氧基的化合物（B）和含硅烷基的化合物（C）的三组分树脂组合物; 2）包含含羟基的化合物（A）和含硅烷基和含环氧基的化合物（D）的双组分树脂组合物; 3）包含含羟基和含硅烷基的化合物（E）和含环氧基的化合物（B）的双组分树脂组合物; 和4）包含含羟基和含环氧基的化合物（F）和含硅烷基化合物（C）的双组分树脂组合物; 其中，树脂组合物1）〜4）中的至少一种成分为含氟树脂， 5）包含树脂组合物1）至4）之一的可固化组合物和作为固化催化剂的金属螯合物; 和6）包含这种固化组合物和需要时颜料的涂料组合物。

公开(公告)号：US5374665A

公开(公告)日：1994-12-20

申请号：US110676

申请日：1993-08-09

Applicant: Hisashi Isaka ,  Osamu Isozaki

Inventor： Hisashi Isaka ,  Osamu Isozaki

IPC: C09D5/00 ,  C09D5/14 ,  C09D5/16 ,  C09D151/00 ,  C08L51/00 ,  B32B9/04

CPC classification number: C09D151/003 ,  Y10S525/902 ,  Y10T428/31504

Abstract: An antifouling paint composition comprising a resin vehicle, an antifouling agent and a liquid medium, at least part of the resin vehicle being composed of a nonaqueous dispersion-type resin of a skin-core structure having in the core component an acid group or an acid precursor group convertible into the acid group by hydrolysis, and said antifouling composition being capable of maintaining an effect of preventing adhesion of microorganisms over along term.

Abstract translation: 一种防污涂料组合物，其包含树脂载体，防污剂和液体介质，所述树脂载体的至少一部分由在芯组分中具有酸基或酸的皮芯结构的非水分散型树脂 前体基团可通过水解转化成酸基，并且所述防污组合物能够保持防止微生物粘附的效果。

公开(公告)号：US5079312A

公开(公告)日：1992-01-07

申请号：US522401

申请日：1990-05-11

Applicant: Osamu Isozaki ,  Noboru Nakai ,  Koichiro Murata

Inventor： Osamu Isozaki ,  Noboru Nakai ,  Koichiro Murata

IPC: C08F30/08 ,  C08F283/12 ,  C08F290/00 ,  C08F299/08 ,  C08G77/20 ,  C08G77/22 ,  C08G77/42

CPC classification number: C08F283/124 ,  C08G77/20

Abstract: The invention provides a process for preparing a polysiloxane-containing resin which comprises copolymerizing a polysiloxane-type macromonomer with a vinyl monomer, characterized in that the polysiloxane-type macromonomer is one prepared by reacting about 70 to about 99.999 mole % of a compound (A) represented by the formula ##STR1## wherein R.sub.1 represents aliphatic hydrocarbon group having 1 to 8 carbon atoms or phenyl group, and R.sub.2, R.sub.3 and R.sub.4 each represent alkoxyl group having 1 to 4 carbon atoms or hydroxyl group with about 30 to about 0.001 mole % of a compound (B) represented by the formula ##STR2## wherein R.sub.5 represents hydrogen atom or methyl group, R.sub.6, R.sub.7 and R.sub.8 each represent hydroxyl group, alkoxyl group having 1 to 4 carbon atoms or aliphatic hydrocarbon group having 1 to 8 carbon atoms with the proviso that R.sub.6, R.sub.7 and R.sub.8 can not be aliphatic hydrocarbon groups having 1 to 8 carbon atoms at the same time, and n is an integer of 1 to 6, the polysiloxane-type macromonomer having at least two free functional groups selected from hydroxyl groups and alkoxyl groups per molecule, and the macromonomer having a number-average molecular weight of about 400 to about 100,000.

Abstract translation: 本发明提供一种制备含聚硅氧烷的树脂的方法，其包括将聚硅氧烷型大分子单体与乙烯基单体共聚，其特征在于，所述聚硅氧烷型大分子单体是通过使约70-约99.999摩尔％的化合物（A ），其中R 1表示具有1至8个碳原子的脂族烃基或苯基，R 2，R 3和R 4各自表示具有1至4个碳原子的烷氧基或羟基，其中约30至 约0.001摩尔％的由式（II）表示的化合物（B），其中R5表示氢原子或甲基，R6，R7和R8各自表示羟基，具有1至4个碳原子的烷氧基或脂族烃 具有1至8个碳原子的基团，条件是R 6，R 7和R 8不能同时为具有1至8个碳原子的脂族烃基，n为1至6的整数，聚硅氧烷型大分子量 具有至少两个选自每个分子的羟基和烷氧基的游离官能团，并且大分子单体的数均分子量为约400至约100,000。

公开(公告)号：US4965312A

公开(公告)日：1990-10-23

申请号：US924477

申请日：1986-10-29

Applicant: Noboru Nakai ,  Osamu Isozaki ,  Susumu Midogohchi

Inventor： Noboru Nakai ,  Osamu Isozaki ,  Susumu Midogohchi

IPC: C08F2/14 ,  C08F2/00 ,  C08F2/08 ,  C08F2/18 ,  C08F2/24 ,  C08F2/44 ,  C08L83/04 ,  C09D133/06 ,  C09D157/00 ,  C09D183/04 ,  C09D201/00

CPC classification number: C09D133/06 ,  C09D157/00 ,  C09D183/04 ,  C08L83/04

Abstract: A vehicle composition for coating materials is disclosed. The vehicle composition includes an organic liquid, finely divided particles of a vinyl polymer dispersed in the organic liquid and a polymer of alkoxysiloxane having an alkoxy group of 3 to 5 carbon atoms dissolved in the organic liquid. The vehicle composition is prepared by polymerizing at least one vinyl monomer in the organic liquid which has the alkoxysiloxane polymer dissolved therein, the organic liquid being capable of dissolving the vinyl monomer but incapable of dissolving the vinyl polymer obtained therefrom.

Abstract translation: 公开了一种用于涂料的载体组合物。 车辆组合物包括有机液体，分散在有机液体中的细分散的乙烯基聚合物颗粒和溶解在有机液体中的具有3至5个碳原子的烷氧基的烷氧基硅氧烷的聚合物。 载体组合物通过使溶解有烷氧基硅氧烷聚合物的有机液体中的至少一种乙烯基单体聚合而制备，有机液体能够溶解乙烯基单体，但不能溶解由其获得的乙烯基聚合物。

公开(公告)号：US4939219A

公开(公告)日：1990-07-03

申请号：US302659

申请日：1989-01-27

Applicant: Hirokazu Terashima ,  Osamu Isozaki

Inventor： Hirokazu Terashima ,  Osamu Isozaki

IPC: C09D5/14 ,  C09D5/16 ,  C09D133/04 ,  C09D133/14 ,  C09D133/16

CPC classification number: C09D5/1668 ,  C09D133/14 ,  C09D133/16

Abstract: Disclosed is a coating composition for preventing adhesion of aquatic organisms, the composition containing as a vehicle component a copolymer prepared by copolymerizing about 5 to about 85% by weight of (A) a monohydric and/or polyhydric phenol ester of acrylic or methacrylic acid; about 15 to about 75% by weight of (B) an ethylenically unsaturated monomer having a soluble parameter of about 8.0 to about 9.5 and a glass transition temperature of about 0.degree. C. or higher; and about 0 to about 50% by weight of (C) a water-soluble, ethylenically unsaturated monomer containing carboxyl group or amino group, based on the total monomer components.

公开(公告)号：US4927884A

公开(公告)日：1990-05-22

申请号：US269084

申请日：1988-11-09

Applicant: Naozumi Iwasawa ,  Osamu Isozaki ,  Noboru Nakai

Inventor： Naozumi Iwasawa ,  Osamu Isozaki ,  Noboru Nakai

IPC: C08K5/00 ,  C08L83/06 ,  C08L83/07 ,  C08L83/10 ,  C09D183/07

CPC classification number: C08L83/06 ,  C08K5/0091 ,  C08L83/10

Abstract: Disclosed is a curable composition characterized in that the composition comprises:(i) 100 parts by weight of a polymer mixture of(a) about 5 to about 95% by weight of a polymer (X) containing a specific polysiloxane macromonomer as an essential monomer or a polymer (Y) containing a specific alkoxysilane-containing vinyl monomer as an essential monomer, and(b) about 95 to about 5% by weight of a polymer (Z) containing an epoxy-containing vinyl monomer as an essential monomer; and(ii) about 0.01 to about 30 parts by weight of at least one chelate compound selected from the group consisting of aluminum chelate compound, titanium chelate compound and zirconium chelate compound.

Abstract translation: 公开了一种可固化组合物，其特征在于所述组合物包含：（i）100重量份的（a）约5至约95重量％的含有特定聚硅氧烷大分子单体作为必需单体的聚合物（X）的聚合物混合物 或含有特定烷氧基硅烷的乙烯基单体作为必需单体的聚合物（Y），和（b）含有含环氧基乙烯基单体作为必需单体的聚合物（Z）约95〜约5重量％ 和（ii）约0.01至约30重量份的选自铝螯合化合物，钛螯合物和锆螯合物的至少一种螯合化合物。

公开(公告)号：US4904504A

公开(公告)日：1990-02-27

申请号：US240657

申请日：1988-09-06

Applicant: Osamu Isozaki ,  Naozumi Iwasawa

Inventor： Osamu Isozaki ,  Naozumi Iwasawa

IPC: C09D5/14 ,  C09D5/16 ,  C09D183/00 ,  C09D183/14

CPC classification number: C09D183/14 ,  C09D5/1675 ,  Y10T428/31663

Abstract: Disclosed is a method of preventing adhesion of organisms characterized by coating a substrate with a coating composition comprising as its vehicle component a reaction product of a silane compound and/or a low condensation product thereof and an organic compound having at least two hydroxyl groups per molecule, the silane compound being represented by the formula(R.sup.1).sub.n Si--(OR.sup.2).sub.4-nwherein R.sup.1 is alkyl having 1 to 20 carbon atoms, haloalkyl having 1 to 12 carbon atoms, cycloalkyl having 3 to 7 carbon atoms, aryl or aralkyl having an alkyl portion with 1 to 12 carbon atoms, R.sup.2 is a hydrogen atom, alkyl having 1 to 8 carbon atoms, cycloalkyl having 3 to 7 carbon atoms or haloalkyl having 1 to 8 carbon atoms and n is an integer of 0 to 3.

Abstract translation: 公开了一种防止生物体粘附的方法，其特征在于用涂料组合物涂布基材，该涂料组合物包含作为其载体组分的硅烷化合物和/或其低缩合产物和每分子具有至少两个羟基的有机化合物的反应产物 硅烷化合物由式（R 1）n -Si-（OR 2）4-n表示，其中R 1是具有1至20个碳原子的烷基，具有1至12个碳原子的卤代烷基，具有3至7个碳原子的环烷基，芳基或芳烷基 具有1至12个碳原子的烷基部分，R 2是氢原子，具有1至8个碳原子的烷基，具有3至7个碳原子的环烷基或具有1至8个碳原子的卤代烷基，n是0至3的整数。

公开(公告)号：US20110196059A1

公开(公告)日：2011-08-11

申请号：US13122789

申请日：2009-09-09

Applicant: Akinori Nagai ,  Yoshiaki Chino ,  Masami Kobata ,  Osamu Isozaki

Inventor： Akinori Nagai ,  Yoshiaki Chino ,  Masami Kobata ,  Osamu Isozaki

IPC: C08F2/46 ,  C07F7/10

CPC classification number: C09D143/04 ,  C07F7/21 ,  C08F230/08 ,  C08G77/04 ,  C08G77/20 ,  C08G77/26

Abstract: To provide a composition comprising a silsesquioxane compound that is capable of producing a coating film with excellent heat resistance and scratch resistance, and that has excellent compatibility with general polymerizable unsaturated compounds as well as polymerizable unsaturated compounds with high polarity.A silsesquioxane compound comprising organic groups each directly attached to a silicon atom of the compound, at least one of the organic groups being an organic group having one or more urethane bonds and one (meth)acryloyloxy group.

Abstract translation: 本发明提供一种能够制造耐热性，耐划伤性优异的涂膜的倍半硅氧烷化合物，与一般的聚合性不饱和化合物以及具有高极性的聚合性不饱和化合物的相容性优异的组合物。 包含与化合物的硅原子直接相连的有机基团的倍半硅氧烷化合物，所述有机基团中的至少一个为具有1个以上的氨基甲酸酯键和1个（甲基）丙烯酰氧基的有机基团。

公开(公告)号：US20110160330A1

公开(公告)日：2011-06-30

申请号：US13060920

申请日：2009-08-12

Applicant: Akinori Nagai ,  Masami Kobata ,  Osamu Isozaki

Inventor： Akinori Nagai ,  Masami Kobata ,  Osamu Isozaki

IPC: C08F2/46 ,  C07F7/21

CPC classification number: C07F7/21 ,  C08F30/08 ,  C08F283/12 ,  C08F290/068 ,  C08F290/148 ,  C08G77/045 ,  C08G77/20 ,  C09D183/04 ,  C08F220/10

Abstract: An object of the present invention is to provide a silsesquioxane compound that is capable of producing a coating film with excellent heat resistance and scratch resistance, and that has excellent compatibility with general polymerizable unsaturated compounds as well as polymerizable unsaturated compounds with high polarity.The present invention provides a silsesquioxane compound comprising organic groups each directly bonded to a silicon atom of the compound, at least one of the organic groups being an organic group having one or more secondary hydroxyl groups and one (meth)acryloyloxy group.

Abstract translation: 本发明的目的在于提供能够制造耐热性，耐划伤性优异的涂膜，并且与一般的聚合性不饱和化合物以及高极性的聚合性不饱和化合物的相容性优异的倍半硅氧烷化合物。 本发明提供一种倍半硅氧烷化合物，其包含与化合物的硅原子直接键合的有机基团，所述有机基团中的至少一个为具有一个以上的仲羟基和一个（甲基）丙烯酰氧基的有机基团。