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11.
公开(公告)号:US10923731B2
公开(公告)日:2021-02-16
申请号:US16384426
申请日:2019-04-15
Inventor: Akira Kano , Ryohei Miyamae , Kiyohiro Isii , Kensuke Nakura
IPC: H01M4/78 , H01M4/38 , H01M10/052 , H01M10/0587 , H01M4/02
Abstract: A lithium secondary battery comprises an electrode group and a nonaqueous electrolyte having lithium-ion conductivity. A negative electrode current collector has a first surface facing outward of winding of the electrode group and a second surface facing inward of the winding of the electrode group. At least the first surface or the second surface includes a first region and a second region that is closer to an innermost circumference of the winding of the electrode group than the first region. Protrusions include outer-circumference-side protrusions disposed on the first region and inner-circumference-side protrusions disposed on the second region. A first average height of the outer-circumference-side protrusions is smaller than a second average height of the inner-circumference-side protrusions.
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公开(公告)号:US20240128591A1
公开(公告)日:2024-04-18
申请号:US18276529
申请日:2022-02-10
Inventor: Shinichiro Kondo , Ryohei Miyamae , Akira Kano
IPC: H01M50/477 , H01M10/052 , H01M10/058 , H01M50/474 , H01M50/486
CPC classification number: H01M50/477 , H01M10/052 , H01M10/058 , H01M50/474 , H01M50/486
Abstract: A lithium secondary battery includes a positive electrode, a negative electrode disposed opposed to the positive electrode, a separator interposed between the positive electrode and the negative electrode, a non-aqueous electrolyte having a lithium ion conductivity, and a spacer interposed between the negative electrode and the separator. A lithium metal deposits on the negative electrode during charging, and the lithium metal dissolves from the negative electrode during discharging. The spacer has a net structure formed with a plurality of lined projected portions.
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公开(公告)号:US20220181695A1
公开(公告)日:2022-06-09
申请号:US17442360
申请日:2020-02-17
Inventor: Akira Kano , Tomohisa Okazaki , Ryohei Miyamae
IPC: H01M10/0569 , H01M10/0525
Abstract: In a non-aqueous electrolyte secondary battery including a positive electrode, a negative electrode, and a non-aqueous electrolyte having lithium-ion conductivity, the solvent in the non-aqueous electrolyte includes a first ether compound represented by a general formula (1): R1-(OCH2CH2)n—OR2 in which R1 and R2 are independently an alkyl group with a carbon number of 1 to 5, and n represents 1 to 3; and a second ether compound having a fluorination rate of 60% or more and represented by a general formula (2): Ca1Mb1Fc1Od1(CF2OCH2)Ca2Hb2Fc2Od2 in which a1≥1, a2≥0, b1≤2a1, b2≤2a2, c1=(2a1+1)−b1, c2=(2a2+1)−b2, d≥0, and d2≥0. The proportion of a total amount of the first ether compound and the second ether compound in the solvent is 80 volume % or more.
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14.
公开(公告)号:US11283102B2
公开(公告)日:2022-03-22
申请号:US16391946
申请日:2019-04-23
Inventor: Ryohei Miyamae , Akira Kano , Kensuke Nakura
IPC: H01M10/0525 , H01M4/134 , H01M4/38 , H01M4/70 , H01M4/02
Abstract: A lithium secondary battery includes a positive electrode, a negative electrode, a separator, and a nonaqueous electrolyte having lithium-ion conductivity. A negative electrode current collector includes a layer having a first surface and a second surface opposite to the first surface, first protrusions protruding from the first surface, and second protrusions protruding from the second surface. The first and second surfaces are surfaces on which lithium metal is deposited during charge. When viewed in a direction of a normal to the first surface, a total area of overlap between the first protrusions and the second protrusions is ½ or less of a total area of the first protrusions.
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15.
公开(公告)号:US11271252B2
公开(公告)日:2022-03-08
申请号:US16383244
申请日:2019-04-12
Inventor: Akira Kano , Ryohei Miyamae , Kiyohiro Isii , Kensuke Nakura
IPC: H01M10/0587 , H01M4/134 , H01M4/38 , H01M10/052 , H01M4/02
Abstract: A lithium secondary battery includes an electrode group and a nonaqueous electrolyte having lithium ion conductivity. A negative electrode includes a negative electrode current collector. The negative electrode current collector has a first surface facing an outward direction of winding of the electrode group and a second surface facing an inward direction of the winding of the electrode group. Lithium metal is deposited on the first surface and the second surface by charge. The negative electrode further includes first protrusions protruding from the first surface and second protrusions protruding from the second surface. A ratio A1X/A1 is greater than a ratio A2X/A2. A1X is a sum of projected areas of the first protrusions on the first surface. A1 is an area of the first surface. A2X is a sum of projected areas of the second protrusions on the second surface. A2 is an area of the second surface.
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16.
公开(公告)号:US11024874B2
公开(公告)日:2021-06-01
申请号:US16392570
申请日:2019-04-23
Inventor: Ryohei Miyamae , Akira Kano , Kensuke Nakura
IPC: H01M10/0525 , H01M4/134 , H01M4/38 , H01M4/66 , H01M4/02
Abstract: A lithium secondary battery includes a positive electrode, a negative electrode, a separator, and a nonaqueous electrolyte having lithium-ion conductivity. The positive electrode contains a positive electrode active material containing lithium. The negative electrode faces the positive electrode. The separator is disposed between the positive and negative electrodes. The negative electrode includes a negative electrode current collector. The negative electrode current collector includes a layer and protrusions. The layer has a first surface on which lithium metal is deposited during charge. The protrusions protrude from the first surface. At least one of the protrusions includes a conductive material and an insulative material.
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公开(公告)号:US10916809B2
公开(公告)日:2021-02-09
申请号:US16260134
申请日:2019-01-29
Inventor: Akira Kano , Ryohei Miyamae , Kiyohiro Isii , Junichi Sakamoto
IPC: H01M10/0587 , H01M4/13 , H01M4/66 , H01M10/0525 , H01M4/76 , H01M4/02 , H01M10/052
Abstract: A lithium secondary battery includes a wound electrode group and a lithium-ion conductive nonaqueous electrolyte. The wound electrode group includes a positive electrode, a negative electrode, and a separator between the positive electrode and the negative electrode. The negative electrode includes a negative electrode current collector. The negative electrode current collector includes: a layer having a first surface facing outward of the winding of the electrode group and a second surface facing inward of the winding of the electrode group; first protrusions protruding from the first surface; and second protrusions protruding from the second surface. Lithium metal is deposited on the first surface and the second surface by charging. A second average height of the second protrusions is higher than a first average height of the first protrusions.
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公开(公告)号:US20240429561A1
公开(公告)日:2024-12-26
申请号:US18694573
申请日:2022-09-22
Inventor: Ryohei Miyamae , Akira Kano , Shinichiro Kondo
IPC: H01M50/463 , H01M10/0525 , H01M10/0568 , H01M10/058 , H01M50/411 , H01M50/431 , H01M50/443 , H01M50/446 , H01M50/451 , H01M50/457 , H01M50/46 , H01M50/489
Abstract: A disclosed lithium secondary battery includes a positive electrode (11), a negative electrode (12), a separator (50) disposed between the positive electrode (11) and the negative electrode (12), and a non-aqueous electrolyte having lithium ion conductivity. The negative electrode (12) is an electrode on which lithium metal is deposited during charging and from which the lithium metal dissolves during discharging. The separator (50) includes a substrate (51) and a spacer (53). The spacer (53) is disposed on the positive electrode side with respect to the substrate (51). The spacer (53) includes line-shaped protrusions arranged in a mesh pattern. The mesh pattern includes a lacking part connecting regions within adjacent meshes.
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公开(公告)号:US20240429395A1
公开(公告)日:2024-12-26
申请号:US18273864
申请日:2022-01-21
Inventor: Ryohei Miyamae , Akira Kano , Kiyohiro Ishii
IPC: H01M4/62 , H01M4/02 , H01M4/36 , H01M10/0525
Abstract: A lithium secondary battery includes a positive electrode that absorbs lithium ions during discharge and releases the lithium ions during charge, a negative electrode at which a lithium metal deposits during charge and from which the lithium metal dissolves during discharge, and a non-aqueous electrolyte having lithium ion conductivity. The surface of the negative electrode is covered with a protective layer. The protective layer includes a block polymer in which a first polymer segment having a repeating structure of a monomer unit A and a second polymer segment having a repeating structure of a monomer unit B are bound together.
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公开(公告)号:US20230369639A1
公开(公告)日:2023-11-16
申请号:US18029212
申请日:2021-09-27
Inventor: Ryohei Miyamae , Akira Kano
IPC: H01M10/0525 , H01M4/62 , H01M4/66
CPC classification number: H01M10/0525 , H01M4/623 , H01M4/667 , H01M4/131
Abstract: A lithium secondary battery includes: a positive electrode that absorbs lithium ions during discharging and releases the lithium ions during charging; a negative electrode on which lithium metal is deposited during charging and from which the lithium metal dissolves during discharging; and a non-aqueous electrolyte that has lithium ion conductivity. A surface of the negative electrode is covered with a protective layer that contains a resin material and inorganic particles having a density of 6 g/cm3 or more.
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