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公开(公告)号:US20230163292A1
公开(公告)日:2023-05-25
申请号:US17915051
申请日:2021-03-23
Inventor: Youichirou Uka , Koh Masahara , Tomohiro Harada , Rina Yamamoto , Tomohisa Okazaki
Abstract: This positive electrode for secondary batteries is provided with a positive electrode collector and a positive electrode mixture layer that is arranged on the positive electrode collector. The positive electrode mixture layer contains a positive electrode active material that contains a lithium-transition metal composite oxide and carbon fibers each having an outermost peripheral diameter of 20 nm or less; the lithium-transition metal composite oxide contains 80% by mole or more of Ni relative to the total number of moles of metal elements excluding Li; an alkaline earth metal element is present on the particle surfaces of the oxide; and the content of the carbon fibers relative to the total amount of the positive electrode active material is from 0.01% by mass to 1.0% by mass.
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公开(公告)号:US20220123367A1
公开(公告)日:2022-04-21
申请号:US17424222
申请日:2019-12-18
Inventor: Yasuko Nozaki , Tasuku Ishiguro , Tomohisa Okazaki
IPC: H01M10/0569 , H01M10/0568 , H01M10/0567 , H01M10/0525
Abstract: A non-aqueous electrolyte secondary battery including a positive electrode, a negative electrode and a liquid electrolyte, wherein the liquid electrolyte contains lithium bis(fluorosulfonyl)imide and dimethyl sulfate.
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公开(公告)号:US20220115700A1
公开(公告)日:2022-04-14
申请号:US17424231
申请日:2020-01-06
Inventor: Tasuku Ishiguro , Yasuko Nozaki , Tomohisa Okazaki
IPC: H01M10/0567 , H01M10/0568 , H01M4/525 , H01M10/0525
Abstract: A non-aqueous electrolyte secondary battery including a positive electrode, a negative electrode and a liquid electrolyte, wherein the liquid electrolyte contains a lithium salt and isopropyl acetate, and the lithium salt includes lithium bis(fluorosulfonyl)imide, and a content of isopropyl acetate in the liquid electrolyte is 1000 ppm or less with respect to a mass of the liquid electrolyte.
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公开(公告)号:US20220006120A1
公开(公告)日:2022-01-06
申请号:US17289373
申请日:2019-10-30
Inventor: Yasuko Nozaki , Tasuku Ishiguro , Tomohisa Okazaki
IPC: H01M10/0567 , H01M10/0568 , H01M10/0525
Abstract: A non-aqueous electrolyte secondary battery including a positive electrode, a negative electrode, a separator interposed between the positive electrode and the negative electrode, and a non-aqueous electrolyte. The non-aqueous electrolyte contains a lithium salt and a carboxylic acid, and the lithium salt includes lithium difluorophosphate. The content of the carboxylic acid in the non-aqueous electrolyte is 5 ppm or more and 900 ppm or less with respect to the mass of the non-aqueous electrolyte.
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公开(公告)号:US20220181695A1
公开(公告)日:2022-06-09
申请号:US17442360
申请日:2020-02-17
Inventor: Akira Kano , Tomohisa Okazaki , Ryohei Miyamae
IPC: H01M10/0569 , H01M10/0525
Abstract: In a non-aqueous electrolyte secondary battery including a positive electrode, a negative electrode, and a non-aqueous electrolyte having lithium-ion conductivity, the solvent in the non-aqueous electrolyte includes a first ether compound represented by a general formula (1): R1-(OCH2CH2)n—OR2 in which R1 and R2 are independently an alkyl group with a carbon number of 1 to 5, and n represents 1 to 3; and a second ether compound having a fluorination rate of 60% or more and represented by a general formula (2): Ca1Mb1Fc1Od1(CF2OCH2)Ca2Hb2Fc2Od2 in which a1≥1, a2≥0, b1≤2a1, b2≤2a2, c1=(2a1+1)−b1, c2=(2a2+1)−b2, d≥0, and d2≥0. The proportion of a total amount of the first ether compound and the second ether compound in the solvent is 80 volume % or more.
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公开(公告)号:US20220069339A1
公开(公告)日:2022-03-03
申请号:US17424778
申请日:2019-12-04
Inventor: Tomohisa Okazaki , Akira Kano
IPC: H01M10/0525 , H01M10/0567 , H01M4/134 , H01M4/131 , H01M4/66 , H01M4/38 , H01M4/28
Abstract: A lithium metal secondary battery includes: a positive electrode including a positive electrode active material which contains a lithium transition metal oxide; a negative electrode which is disposed to face the positive electrode, which includes a negative electrode collector, and on which a lithium metal is precipitated in charge; a separator provided between the positive electrode and the negative electrode; and an electrolyte which is impregnated in the separator and which contains a lithium halogenated compound in an amount of more than 0.1 to less than 10 percent by weight and at least one selected from a fluorinated cyclic carbonate and a fluorinated oxalate complex.
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公开(公告)号:US12148885B2
公开(公告)日:2024-11-19
申请号:US17424231
申请日:2020-01-06
Inventor: Tasuku Ishiguro , Yasuko Nozaki , Tomohisa Okazaki
IPC: H01M10/0567 , H01M4/525 , H01M10/0525 , H01M10/0568 , H01M10/0569 , H01M4/02
Abstract: A non-aqueous electrolyte secondary battery including a positive electrode, a negative electrode and a liquid electrolyte, wherein the liquid electrolyte contains a lithium salt and isopropyl acetate, and the lithium salt includes lithium bis(fluorosulfonyl)imide, and a content of isopropyl acetate in the liquid electrolyte is 1000 ppm or less with respect to a mass of the liquid electrolyte.
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公开(公告)号:US11973188B2
公开(公告)日:2024-04-30
申请号:US17289373
申请日:2019-10-30
Inventor: Yasuko Nozaki , Tasuku Ishiguro , Tomohisa Okazaki
IPC: H01M10/0567 , H01M10/0525 , H01M10/0568
CPC classification number: H01M10/0567 , H01M10/0525 , H01M10/0568 , H01M2300/004
Abstract: A non-aqueous electrolyte secondary battery including a positive electrode, a negative electrode, a separator interposed between the positive electrode and the negative electrode, and a non-aqueous electrolyte. The non-aqueous electrolyte contains a lithium salt and a carboxylic acid, and the lithium salt includes lithium difluorophosphate. The content of the carboxylic acid in the non-aqueous electrolyte is 5 ppm or more and 900 ppm or less with respect to the mass of the non-aqueous electrolyte.
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公开(公告)号:US20220190379A1
公开(公告)日:2022-06-16
申请号:US17599358
申请日:2020-02-17
Inventor: Tomohisa Okazaki , Akira Kano
IPC: H01M10/052 , H01M4/134 , H01M4/131 , H01M10/056 , H01M4/66
Abstract: A lithium secondary battery including a positive electrode including a positive electrode material mixture containing a positive electrode additive, a negative electrode, a separator, and an electrolyte. The positive electrode additive includes at least one selected from the group consisting of a first compound represented by formula (1): Lia1Fex1M1y1Oz1 and a second compound represented by formula (2): Lia2Nix2M2y2Oz2. The formula (1) satisfies 0≤a1≤5, 0≤x1≤5, 0≤y1≤1, and 0≤z1≤4, where at least two of a1, x1, y1 and z1 are greater than 0. The formula (2) satisfies 0≤a2≤2, 0≤x2≤1, 0≤y2≤1, and 1≤z2≤2, where at least one of a2 and x2 is greater than 0. The electrolyte contains an oxalate complex salt having an oxalate complex anion and a lithium ion.
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公开(公告)号:US20250132345A1
公开(公告)日:2025-04-24
申请号:US18685595
申请日:2022-07-20
Inventor: Tomohisa Okazaki
IPC: H01M4/62 , H01M4/02 , H01M4/48 , H01M10/0567
Abstract: A nonaqueous electrolyte secondary battery includes a positive electrode, a negative electrode, and a nonaqueous electrolyte. The positive electrode includes a positive electrode current collector, and a positive electrode mixture layer supported on the positive electrode current collector. The negative electrode includes a negative electrode current collector, and a negative electrode mixture layer supported on the negative electrode current collector. The negative electrode mixture layer includes a negative electrode active material capable of absorbing and releasing lithium ions, and negative-electrode-side carbon nanotubes. The positive electrode mixture layer includes a positive electrode active material capable of absorbing and releasing lithium ions, and positive-electrode-side carbon nanotubes. The expansion rate during charging of the negative electrode is 10% or more.
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