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11.发明申请公开(公告)号：US20120003145A1
公开(公告)日：2012-01-05
申请号：US12827291
申请日：2010-06-30
申请人： Bhadra S. Grover , Paul Terrien
发明人： Bhadra S. Grover , Paul Terrien
IPC分类号： C01B31/20
CPC分类号： C01B3/34 , C01B3/48 , C01B3/505 , C01B2203/0288 , C01B2203/0294 , C01B2203/0405 , C01B2203/043 , C01B2203/046 , C01B2203/0475 , C01B2203/0485 , C01B2203/0495 , C01B2203/147 , C01B2203/86 , C10J3/00 , C10J2300/1612 , C10J2300/1618 , C10K3/04 , Y02E20/18 , Y02E20/185 , Y02P30/30
摘要： The present invention provides a process for recovering high purity gaseous hydrogen and high purity gaseous carbon dioxide from a syngas stream by utilizing a hydrogen selective membrane unit and a primary water gas shift reactor in combination with a cryogenic purification unit, a hydrogen recovery unit and a secondary water gas shift reactor or by utilizing a hydrogen membrane/water gas shift reactor in combination with a cryogenic purification unit, a hydrogen recovery unit and a secondary water gas shift reactor. Each of these embodiments may further include a sulfur recovery unit.
摘要翻译： 本发明提供了一种通过利用氢选择性膜单元和初级水煤气变换反应器与低温净化单元，氢气回收单元和氢气回收单元组合从合成气流中回收高纯度气态氢和高纯度气态二氧化碳的方法 二次水煤气变换反应器，或者与低温净化单元，氢气回收单元和二次水煤气变换反应器结合使用氢气/水煤气变换反应器。 这些实施方案中的每一个可以进一步包括硫回收单元。
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12.发明授权公开(公告)号：US08636922B2
公开(公告)日：2014-01-28
申请号：US12827291
申请日：2010-06-30
申请人： Bhadra S. Grover , Paul Terrien
发明人： Bhadra S. Grover , Paul Terrien
CPC分类号： C01B3/34 , C01B3/48 , C01B3/505 , C01B2203/0288 , C01B2203/0294 , C01B2203/0405 , C01B2203/043 , C01B2203/046 , C01B2203/0475 , C01B2203/0485 , C01B2203/0495 , C01B2203/147 , C01B2203/86 , C10J3/00 , C10J2300/1612 , C10J2300/1618 , C10K3/04 , Y02E20/18 , Y02E20/185 , Y02P30/30
摘要： The present invention provides a process for recovering high purity gaseous hydrogen and high purity gaseous carbon dioxide from a syngas stream by utilizing a hydrogen selective membrane unit and a primary water gas shift reactor in combination with a cryogenic purification unit, a hydrogen recovery unit and a secondary water gas shift reactor or by utilizing a hydrogen membrane/water gas shift reactor in combination with a cryogenic purification unit, a hydrogen recovery unit and a secondary water gas shift reactor. Each of these embodiments may further include a sulfur recovery unit.
摘要翻译： 本发明提供了一种通过利用氢选择性膜单元和初级水煤气变换反应器与低温净化单元，氢气回收单元和氢气回收单元组合从合成气流中回收高纯度气态氢和高纯度气态二氧化碳的方法 二次水煤气变换反应器，或者与低温净化单元，氢气回收单元和二次水煤气变换反应器结合使用氢气/水煤气变换反应器。 这些实施方案中的每一个可以进一步包括硫回收单元。
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公开(公告)号：US20130017146A1
公开(公告)日：2013-01-17
申请号：US13637423
申请日：2011-03-16
申请人： Arthur Darde , Solène Valentin , Philippe Court , Jean-Pierre Tranier , Xavier Traversac , Paul Terrien
发明人： Arthur Darde , Solène Valentin , Philippe Court , Jean-Pierre Tranier , Xavier Traversac , Paul Terrien
IPC分类号： C01B3/02
CPC分类号： C01B3/38 , C01B3/48 , C01B3/56 , C01B2203/0233 , C01B2203/0288 , C01B2203/043 , C01B2203/046 , C01B2203/047 , C01B2203/0475 , C01B2203/0495 , Y02C10/04 , Y02P20/129 , Y02P30/30
摘要： The present invention relates to a method for producing hydrogen, with reduced carbon dioxide emissions, from a hydrocarbon mixture. In said method, the hydrocarbon mixture is reformed so as to produce a synthetic gas that is cooled, then treated in a shift reactor so as to be enriched with H2 and CO2. Optionally dried, said mixture is treated in a PSA hydrogen purification unit in order to produce hydrogen. The residue is treated by means of partial condensation with a view to capturing CO4 before said residue is sent as fuel to reforming.
摘要翻译： 本发明涉及一种从碳氢化合物混合物中生产具有减少的二氧化碳排放的氢的方法。 在所述方法中，将烃混合物重整以产生冷却的合成气体，然后在换档反应器中处理以富含H 2和CO 2。 任选地干燥，所述混合物在PSA氢纯化装置中处理以产生氢气。 残余物通过部分冷凝处理，以便在将所述残余物作为燃料送入重整之前捕获CO 4。
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公开(公告)号：US09028794B2
公开(公告)日：2015-05-12
申请号：US13637423
申请日：2011-03-16
申请人： Arthur Darde , Solène Valentin , Philippe Court , Jean-Pierre Tranier , Xavier Traversac , Paul Terrien
发明人： Arthur Darde , Solène Valentin , Philippe Court , Jean-Pierre Tranier , Xavier Traversac , Paul Terrien
CPC分类号： C01B3/38 , C01B3/48 , C01B3/56 , C01B2203/0233 , C01B2203/0288 , C01B2203/043 , C01B2203/046 , C01B2203/047 , C01B2203/0475 , C01B2203/0495 , Y02C10/04 , Y02P20/129 , Y02P30/30
摘要： The present invention relates to a method for producing hydrogen, with reduced carbon dioxide emissions, from a hydrocarbon mixture. In said method, the hydrocarbon mixture is reformed so as to produce a synthetic gas that is cooled, then treated in a shift reactor so as to be enriched with H2 and CO2. Optionally dried, said mixture is treated in a PSA hydrogen purification unit in order to produce hydrogen. The residue is treated by means of partial condensation with a view to capturing CO4 before said residue is sent as fuel to reforming.
摘要翻译： 本发明涉及一种从碳氢化合物混合物中生产具有减少的二氧化碳排放的氢的方法。 在所述方法中，将烃混合物重整以产生冷却的合成气体，然后在换档反应器中处理以富含H 2和CO 2。 任选地干燥，所述混合物在PSA氢纯化装置中处理以产生氢气。 残余物通过部分冷凝处理，以便在将所述残余物作为燃料送入重整之前捕获CO 4。
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15.发明申请公开(公告)号：US20120241678A1
公开(公告)日：2012-09-27
申请号：US13512631
申请日：2010-12-02
申请人： Solene Valentin , Paul Terrien , Pascal Tromeur
发明人： Solene Valentin , Paul Terrien , Pascal Tromeur
IPC分类号： C01B3/02
CPC分类号： C01B3/384 , B01D53/047 , B01D2256/16 , B01D2257/504 , B01D2259/40001 , B01D2259/4003 , B01D2259/40039 , B01D2259/40045 , B01D2259/40069 , C01B3/48 , C01B3/501 , C01B3/506 , C01B3/56 , C01B2203/0233 , C01B2203/0283 , C01B2203/0405 , C01B2203/043 , C01B2203/046 , C01B2203/0475 , C01B2203/1241 , C01B2203/147 , C01B2203/148 , Y02C10/08 , Y02P20/129 , Y02P20/152 , Y02P30/30
摘要： The present invention relates to a method for the combined production of hydrogen and carbon dioxide from a hydrocarbon mixture, in which the hydrocarbon mixture is reformed to produce a syngas which is cooled, then enriched with H2 and CO2, optionally dried, and treated in a PSA hydrogen purification unit to produce hydrogen, the PSA offgas being treated to capture the CO2 and to supply an offgas. This offgas is again treated to supply a stream enriched with H2 and CO2 which is returned to the PSA, where it constitutes a second feed distinct from the main feed.
摘要翻译： 本发明涉及一种从烃混合物中组合生产氢气和二氧化碳的方法，其中烃混合物被重整以产生合成气，其被冷却，然后用任选地干燥的H 2和CO 2富集，并在 PSA氢气净化单元产生氢气，PSA废气被处理以捕获CO 2并提供废气。 该废气再次被处理以提供富含H 2和CO 2的物流，其返回到PSA，其中它构成与主进料不同的第二进料。
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16.发明授权公开(公告)号：US08852456B2
公开(公告)日：2014-10-07
申请号：US13512631
申请日：2010-12-02
申请人： Solene Valentin , Paul Terrien , Pascal Tromeur
发明人： Solene Valentin , Paul Terrien , Pascal Tromeur
CPC分类号： C01B3/384 , B01D53/047 , B01D2256/16 , B01D2257/504 , B01D2259/40001 , B01D2259/4003 , B01D2259/40039 , B01D2259/40045 , B01D2259/40069 , C01B3/48 , C01B3/501 , C01B3/506 , C01B3/56 , C01B2203/0233 , C01B2203/0283 , C01B2203/0405 , C01B2203/043 , C01B2203/046 , C01B2203/0475 , C01B2203/1241 , C01B2203/147 , C01B2203/148 , Y02C10/08 , Y02P20/129 , Y02P20/152 , Y02P30/30
摘要： The present invention relates to a method for the combined production of hydrogen and carbon dioxide from a hydrocarbon mixture, in which the hydrocarbon mixture is reformed to produce a syngas which is cooled, then enriched with H2 and CO2, optionally dried, and treated in a PSA hydrogen purification unit to produce hydrogen, the PSA offgas being treated to capture the CO2 and to supply an offgas. This offgas is again treated to supply a stream enriched with H2 and CO2 which is returned to the PSA, where it constitutes a second feed distinct from the main feed.
摘要翻译： 本发明涉及一种从烃混合物中组合生产氢气和二氧化碳的方法，其中烃混合物被重整以产生合成气，其被冷却，然后用任选地干燥的H 2和CO 2富集，并在 PSA氢气净化单元产生氢气，PSA废气被处理以捕获CO 2并提供废气。 该废气再次被处理以提供富含H 2和CO 2的物流，其返回到PSA，其中它构成与主进料不同的第二进料。
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公开(公告)号：US08663364B2
公开(公告)日：2014-03-04
申请号：US12828295
申请日：2010-07-01
申请人： David J. Hasse , Sudhir S. Kulkarni , Edgar S. Sanders, Jr. , Jean-Pierre Tranier , Paul Terrien
发明人： David J. Hasse , Sudhir S. Kulkarni , Edgar S. Sanders, Jr. , Jean-Pierre Tranier , Paul Terrien
CPC分类号： B01D53/002 , B01D53/229 , B01D2256/22 , B01D2257/504 , F23J15/006 , F23J15/06 , F23J2215/50 , F23J2219/70 , F25J3/067 , F25J2205/20 , F25J2205/40 , F25J2205/80 , F25J2210/04 , F25J2210/70 , F25J2215/04 , F25J2220/82 , F25J2235/80 , F25J2240/02 , F25J2240/80 , F25J2240/90 , F25J2245/02 , F25J2270/02 , F25J2270/04 , F25J2270/06 , Y02C10/10 , Y02C10/12 , Y02E20/326 , Y02E20/363
摘要： Disclosed are methods of obtaining carbon dioxide from a CO2-containing gas mixture. The methods combine the benefits of gas membrane separation with cryogenic temperatures.
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18.发明授权Method of obtaining carbon dioxide from carbon dioxide-containing gas mixture 有权从含二氧化碳的气体混合物中获得二氧化碳的方法公开(公告)号：US08617292B2
公开(公告)日：2013-12-31
申请号：US12828293
申请日：2010-07-01
申请人： David J. Hasse , Sudhir S. Kulkarni , Edgar S. Sanders, Jr. , Jean-Pierre Tranier , Paul Terrien
发明人： David J. Hasse , Sudhir S. Kulkarni , Edgar S. Sanders, Jr. , Jean-Pierre Tranier , Paul Terrien
CPC分类号： B01D53/228 , B01D53/002 , B01D53/229 , B01D71/64 , B01D2257/504 , F25J3/067 , F25J2205/20 , F25J2205/40 , F25J2205/80 , F25J2210/04 , F25J2210/70 , F25J2215/04 , F25J2220/82 , F25J2230/08 , F25J2230/30 , F25J2230/80 , F25J2235/80 , F25J2240/80 , F25J2240/90 , F25J2245/02 , F25J2270/02 , F25J2270/06 , Y02C10/10 , Y02C10/12
摘要： Disclosed are methods of obtaining carbon dioxide from a CO2-containing gas mixture. The methods combine the benefits of gas membrane separation with cryogenic temperatures.
摘要翻译： 公开了从含CO 2的气体混合物中获得二氧化碳的方法。 该方法结合了气膜分离与低温温度的优点。
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19.发明申请公开(公告)号：US20130025317A1
公开(公告)日：2013-01-31
申请号：US13524762
申请日：2012-06-15
申请人： Paul Terrien , Pascal Tessier
发明人： Paul Terrien , Pascal Tessier
IPC分类号： F25J1/00
CPC分类号： B01D53/002 , B01D2256/22 , B01D2257/10 , B01D2258/0283 , B01D2259/65 , F25J3/067 , F25J2205/20 , F25J2210/70 , F25J2220/82 , F25J2230/30 , F25J2230/80 , F25J2235/80 , F25J2270/04 , F25J2270/80 , Y02C10/12
摘要： A process for removing carbon dioxide from a carbon dioxide containing gas stream is obtained through de-sublimation, vaporization, and liquefaction of various carbon dioxide-containing streams with little or no external refrigeration.
摘要翻译： 通过几乎没有或没有外部制冷的各种含二氧化碳的物流的脱升，蒸发和液化来获得从含二氧化碳气流中除去二氧化碳的方法。
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20.发明授权Method of obtaining carbon dioxide from carbon dioxide-containing gas mixture 有权从含二氧化碳的气体混合物中获得二氧化碳的方法公开(公告)号：US08734569B2
公开(公告)日：2014-05-27
申请号：US12828294
申请日：2010-07-01
申请人： David J. Hasse , Sudhir S. Kulkarni , Edgar S. Sanders, Jr. , Jean-Pierre Tranier , Paul Terrien
发明人： David J. Hasse , Sudhir S. Kulkarni , Edgar S. Sanders, Jr. , Jean-Pierre Tranier , Paul Terrien
CPC分类号： B01D53/229 , B01D53/002 , B01D2256/22 , B01D2257/504 , F23J15/06 , F23J2215/50 , F23J2900/15061 , F25J3/067 , F25J2205/20 , F25J2205/40 , F25J2205/80 , F25J2210/04 , F25J2210/70 , F25J2215/04 , F25J2220/82 , F25J2230/08 , F25J2230/30 , F25J2230/80 , F25J2235/80 , F25J2240/80 , F25J2240/90 , F25J2245/02 , F25J2270/02 , F25J2270/06 , Y02C10/10 , Y02C10/12 , Y02C20/20 , Y02E20/326 , Y02E20/363
摘要： Disclosed are methods of obtaining carbon dioxide from a CO2-containing gas mixture. The methods combine the benefits of gas membrane separation with cryogenic temperatures.
摘要翻译： 公开了从含CO 2的气体混合物中获得二氧化碳的方法。 该方法结合了气膜分离与低温温度的优点。
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