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11.发明授权
公开(公告)号：US5024984A
公开(公告)日：1991-06-18
申请号：US382479
申请日：1989-07-19
申请人： Mark P. Kaminsky , Mark S. Kleefisch , George A. Huff , Don M. Washecheck , Aileen E. Alvarado-Swaisgood , Mark K. Barr
发明人： Mark P. Kaminsky , Mark S. Kleefisch , George A. Huff , Don M. Washecheck , Aileen E. Alvarado-Swaisgood , Mark K. Barr
CPC分类号： B01J23/14 , C07C2/84 , C07C2523/02 , C07C2523/10 , C07C2523/14
摘要： An oxidative coupling catalyst composition for converting methane to a higher hydrocarbon comprising a mixed oxide of: a) a Group IIIB metal selected from the group consisting of yttrium, scandium and lanthanum; b) a Group IIA metal selected from the group consisting of barium, calcium and strontium; and c) a Group IVA metal selected from the group consisting of tin, lead and germanium and wherein the cationic species are present in the approximate ratio of 1:0.5-3:2-4, respectively, and an improved process employing same.
摘要翻译： 一种用于将甲烷转化为高级烃的氧化偶联催化剂组合物，其包含以下混合氧化物：a）选自钇，钪和镧的IIIB族金属; b）选自钡，钙和锶的IIA族金属; 和c）选自锡，铅和锗的IVA族金属，并且其中阳离子种类分别以1:0.5-3:2-4的大致比例存在，以及使用其的改进方法。
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公开(公告)号：US20130184509A1
公开(公告)日：2013-07-18
申请号：US13783654
申请日：2013-03-04
CPC分类号： C07C6/00 , C07C5/2708 , C07C6/126 , C07C2529/26 , Y02P20/52 , C07C15/08
摘要： Disclosed herein are methods of making xylene isomers. The methods generally include contacting an aromatics-comprising feed with a non-sulfided catalyst under conditions suitable for converting the feed to a product comprising xylene isomers. The catalyst includes a support impregnated with a hydrogenation component. The support includes a macroporous binder and a sieve selected from the group consisting of a medium pore sieve, a large pore sieve, and mixtures thereof. The selection of the sieve will depend upon the size of the molecules in the feed, intermediate, and product that can be expected from the catalytic reactions. When the molecules are expected to be large, a large pore sieve should be used. In contrast, when the molecules are expected to be smaller, either a large pore sieve, a medium pore sieve, or a mixture thereof may be used. The macropores within the support have been found to be especially beneficial because they help to overcome diffusional limitations observed when utilizing highly-active catalysts lacking such macropores.
摘要翻译： 本文公开了制备二甲苯异构体的方法。 所述方法通常包括在适于将进料转化为包含二甲苯异构体的产物的条件下使包含芳烃的进料与非硫化催化剂接触。 催化剂包括浸渍有氢化组分的载体。 载体包括大孔粘合剂和选自中孔筛，大孔筛及其混合物的筛子。 筛子的选择将取决于催化反应可以预期的进料，中间体和产物中分子的大小。 当分子预期较大时，应使用大孔隙筛。 相反，当分子预期更小时，可以使用大孔隙筛孔，中孔筛或其混合物。 发现载体中的大孔是特别有益的，因为它们有助于克服当使用缺乏这种大孔的高活性催化剂时观察到的扩散限制。
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公开(公告)号：US20080172929A1
公开(公告)日：2008-07-24
申请号：US11869763
申请日：2007-10-10
IPC分类号： C10L1/14
摘要： Disclosed is a process to make environment friendly components for refinery blending of transportation fuels. The process involves contacting a petroleum distillate with an oxygen-containing gas at oxidation conditions in the presence of a heterogeneous catalyst comprising a Group VII metal on a basic support to oxidize any sulfur and/or nitrogen-containing compounds in the distillate. A portion of these sulfur and/or nitrogen-containing compounds is then removed from the oxidation zone effluent.
摘要翻译： 公开了一种制造环境友好组件的方法，用于运输燃料的炼油厂混合。 该方法包括在氧化条件下在含有碱性载体上的第Ⅶ族金属的非均相催化剂存在下使石油馏分与含氧气体接触以氧化馏出物中的任何硫和/或含氮化合物。 然后将这些硫和/或含氮化合物的一部分从氧化区流出物中除去。
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公开(公告)号：US07252756B2
公开(公告)日：2007-08-07
申请号：US10323215
申请日：2002-12-18
IPC分类号： C10G29/22
CPC分类号： C10G21/16 , C10G2400/04
摘要： A process is disclosed for the production of refinery transportation fuel or components for refinery blending of transportation fuels having a reduced amount of sulfur and/or nitrogen-containing impurities. The process involves contacting a hydrocarbon feedstock containing the above impurities with an immiscible phase containing hydrogen peroxide and acetic acid in an oxidation zone to selectively oxidize the impurities. After a gravity phase separation, the hydrocarbon phase containing any remaining oxidized impurities, is passed to an extraction zone wherein aqueous acetic acid is used to extract a portion of any remaining oxidized impurities. A hydrocarbon stream having reduced impurities can then be recovered. The acetic acid phase effluents from the oxidation and the extraction zones can then be passed to a common separation zone for recovery of the acetic acid and for optional recycle back to the oxidation and extraction zones.
摘要翻译： 公开了一种用于生产炼油厂运输燃料或用于精炼混合具有减少量的硫和/或含氮杂质的运输燃料的组分的方法。 该方法包括使含有上述杂质的烃原料与氧化区中含有过氧化氢和乙酸的不混溶相接触以选择性地氧化杂质。 在重力相分离后，将含有任何剩余的氧化杂质的烃相通过萃取区，其中使用乙酸水溶液萃取剩余氧化杂质的一部分。 然后可以回收具有减少的杂质的烃流。 然后可将来自氧化和萃取区域的乙酸相流出物传递至常见的分离区，以回收乙酸，并可任选地再循环回氧化和萃取区。
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公开(公告)号：US06599417B2
公开(公告)日：2003-07-29
申请号：US09489392
申请日：2000-01-21
IPC分类号： C10G4500
CPC分类号： C10G69/00
摘要： A product of reduced sulfur content is produced from an olefin-containing hydrocarbon feedstock which includes sulfur-containing impurities. The feedstock is contacted with an olefin-modification catalyst in a reaction zone under conditions which are effective to produce an intermediate product which has a reduced amount of olefinic unsaturation relative to that of the feedstock as measured by bromine number. The intermediate product is then separated into fractions of different volatility, and the lowest boiling fraction is contacted with a hydrodesulfurization catalyst in the presence of hydrogen under conditions which are effective to convert at least a portion of its sulfur-containing impurities to hydrogen sulfide.
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