Abstract:
The invention includes fibrous nonwoven multiple layer mats having at least two layers with a body portion layer and a surface portion layer having fine fibers and/or particles therein, both layers being bonded together and to each other with a same resin binder. Preferably most or essentially all of the particles and/or fibers in the surface layer are larger than openings between the fibers in the body portion of the mat. The mats produced according to this invention are useful as a facer for all types of boards such as wood boards, wood product boards, insulating boards and hard boards of all types, and also as reinforcement and dimensional stabilizers for making a large number of novel laminate products and for a myriad of other uses. These mats are made on a wet laid nonwoven mat machine with a modification to the binder preparation system, an inventive step in the preparation of the binder and in the selection of ingredients for a binder slurry.
Abstract:
Fire resistant glass fiber products are produced by coating the glass fibers with at least one nitrogen containing compound and at least 10 weight percent of at least one boron containing compound, drying the glass fibers and curing a binder that is in the coating. The nitrogen containing compound(s) are present in sufficient amounts that there is at least one mol or atom of nitrogen present for each mol or atom of boron present in the boron containing compound(s). When the product is exposed to a fire or high temperatures, such as about 1000 degrees F. or higher, the nitrogen released from the nitrogen containing compound(s) reacts with boron or boron oxide to form a sheath of refractory material around the fibers that protects the fibers and allows the fibers to maintain integrity to higher temperatures and/or for longer times than untreated fibers.
Abstract:
Fire resistant glass fiber products are produced by coating the glass fibers with at least one nitrogen containing compound and at least 10 weight percent of at least one boron containing compound, drying the glass fibers and curing a binder that is in the coating. The nitrogen containing compound(s) are present in sufficient amounts that there is at least one mol or atom of nitrogen present for each mol or atom of boron present in the boron containing compound(s). When the product is exposed to a fire or high temperatures, such as about 1000 degrees F. or higher, the nitrogen released from the nitrogen containing compound(s) reacts with boron or boron oxide to form a sheath of refractory material around the fibers that protects the fibers and allows the fibers to maintain integrity to higher temperatures and/or for longer times than untreated fibers.
Abstract:
A method of making a nonwoven fibrous mat that retains good strength and recovery after scoring and folding, properties making the mat useful in making collapsible ceiling tile. The mat comprises a majority of glass fibers and a minority of polymer fibers, the fibers being bound together with up to 35 wt. percent of a polyacrylic acid and polyol polymer binder based on the dry weight of the mat. The mat can be cured to “B stage”, thermoformed into the desired shape and then heated further to complete the cure of the binder.
Abstract:
Coated and uncoated fibrous mats, and laminates containing the mat, having one or more surfactants on the fibers and binder holding the fibers together in only a portion of the thickness of the mat are disclosed. The mat contains a major portion of non-cellulosic fibers and a minor portion of cured resinous binder with the most typical fibers being glass fibers. The surfactant on the surface of the fibers causes a slurry or other liquid applied to the mat in a later process to form a board or laminate like faced gypsum board, a faced foam board, etc. to uniformly penetrate the mat to the desired distance. Also disclosed are methods of applying the surfactant(s) to the hot, coated or uncoated, mat soon after the coated or uncoated mat exits a drying oven used in the process of making, or coating, the mat.
Abstract:
New coated nonwoven fibrous mats having properties particularly suited for a facer on gypsum wallboard and other substrates and in laminates of various types, and the method of making the coated mat is disclosed. The mat preferably contains a major portion of glass fibers and a minor portion of a resinous binder. The coating is preferably permeable and reduces fiber dust and abrasion experienced in the past with relatively coarse, relatively inexpensive glass fibers in the mat. Contrary to previous coating methods, the coated fibrous mat is made in-line on a wet mat forming production line by applying a wet foam binder onto a wet, fibrous web followed by drying and curing in-line.
Abstract:
A new foam coated nonwoven fibrous mat having properties particularly suited for a facer on gypsum wallboard, laminates made therefrom and the method of making the mat is disclosed. The mat preferably contains a major portion of glass fibers and a minor portion of a resinous binder. The foam coating is permeable and reduces fiber dust and abrasion experienced in the past with relatively coarse, relatively inexpensive glass fibers in the mat. Contrary to previous methods, the foam coated fibrous mat is made in-line on a wet mat forming production line by applying a wet foam binder onto a wet, fibrous web followed by drying and curing in-line.
Abstract:
A bond is created between a gypsum matrix formed from an aqueous acidic gypsum slurry comprising a monomer mixture. The monomer mixture is composed of a monomer having acidic functionality and a monomer having hydroxyl or amine functionality. A silane-based sizing composition is coated onto glass fibers causing a cross-linking network of silane and monomer mixture to form during curing of the gypsum board. Hydrophilic water extraction at the gypsum matrix-sizing interface reduces void formation and promotes bonding with the crosslinked monomer mixture and growth of smaller gypsum crystals within larger crystals in microstructurally identifiable regions adjacent to the glass fiber. A bond is created between a gypsum matrix formed from an aqueous acidic gypsum slurry comprising a monomer mixture. The monomer mixture is composed of a monomer having acidic functionality and a monomer having hydroxyl or amine functionality. A silane-based sizing composition is coated onto glass fibers causing a cross-linking network of silane and monomer mixture to form during curing of the gypsum board. Hydrophilic water extraction at the gypsum matrix-sizing interface reduces void formation and promotes bonding with the crosslinked monomer mixture and growth of smaller gypsum crystals within larger crystals in microstructurally identifiable regions adjacent to the glass fiber. Alternatively, the silane based sizing composition has branched chains that diffuse into a wet gypsum mix containing the monomer mixture. During gypsum cure, the diffusion and crosslinking of monomer mixture triggers formation of interpenetrating pseudo polymeric networks within a microstructurally identifiable region adjacent to the glass fiber. Bonds formed between the gypsum matrix and the silane based sizing composition increase the strength, flexure resistance and nail pull out resistance of the gypsum board.
Abstract:
A new foam coated nonwoven fibrous mat having properties particularly suited for a facer on gypsum wallboard, laminates made therefrom and the method of making the mat is disclosed. The mat preferably contains a major portion of glass fibers and a minor portion of a resinous binder. The foam coating is permeable and reduces fiber dust and abrasion experienced in the past with relatively coarse, relatively inexpensive glass fibers in the mat. Contrary to previous methods, the foam coated fibrous mat is made in-line on a wet mat forming production line by applying a wet foam binder onto a wet, fibrous web followed by drying and curing in-line.
Abstract:
Methods of making nonwoven mats having good strength after being scored and folded and particularly useful in making lightweight, compressible ceiling panels are disclosed. The mats also have excellent flame resistance. The mats include a blend comprising a major portion of glass fibers and a minor portion of man-made polymer fibers, the fibers being bound together with a cured binder containing a homopolymer or copolymer of polyacrylic acid and a polyol. The binder bonding the mat together can be cured to only a “B” stage to produce thermoformable mats or more fully cured to produce mats having the properties described above.