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公开(公告)号：US20080067124A1
公开(公告)日：2008-03-20
申请号：US11523315
申请日：2006-09-19
IPC分类号： B01D11/04
CPC分类号： C02F9/00 , B01J2219/00006 , C02F1/001 , C02F1/283 , C02F2101/308 , C02F2209/40
摘要： An apparatus for recovering components of a material system containing dye, water, and solvents such as ethylene glycol monobutyl ether and diethylene glycol is provided. The apparatus comprises in sequence: a first vessel including a cooling device for cooling the material system; a pump; at least one first filter; at least one purifying vessel containing activated carbon; optionally, a second filter; and a second vessel optionally including a probe. Each of the first vessel, purifying vessel, filter housings and baskets, second vessel and interconnecting piping are fabricated of a material which does not absorb dye, such as stainless steel.
摘要翻译： 提供了用于回收含有染料，水和溶剂如乙二醇单丁醚和二甘醇的物质体系的组分的装置。 该装置依次包括：第一容器，包括用于冷却材料系统的冷却装置; 一个泵 至少一个第一过滤器; 至少一个含活性炭的净化容器; 可选地，第二过滤器; 以及任选地包括探针的第二容器。 第一容器，净化容器，过滤器壳体和篮子，第二容器和互连管道中的每一个由不吸收染料的材料制成，例如不锈钢。
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公开(公告)号：US07094263B2
公开(公告)日：2006-08-22
申请号：US11080799
申请日：2005-03-14
申请人： Robert A. Pyles , Rick L. Archey
发明人： Robert A. Pyles , Rick L. Archey
CPC分类号： D06P3/54 , D06P1/613 , D06P1/65131
摘要： A composition of matter (e.g., a molded article) is described. More particularly, the composition of matter includes: (a) a resinous component selected from at least one member of the group consisting of (co)polyester, (co)polycarbonates, acrylonitrile-butadiene-styrene, polyamide, polyurethane, polyalkyl(meth)acrylate and styrene copolymers; (b) at least one water-insoluble dye; (c) a carrier represented by the following formula, R1[—O—(CH2)n]mOR2 wherein R2is butyl, R1 is H, n is 2 or 3, and m is 2–35; (d) an emulsifier that is poly(oxy-1,2-ethanediyl), alpha-phenyl-omega-hydroxy, styrenated; and (e) a particulate or plate-like material, such as metal flakes.
摘要翻译： 描述了一种物质的组成（例如模制品）。 更具体地，物质组成包括：（a）选自（共）聚酯，（共）聚碳酸酯，丙烯腈 - 丁二烯 - 苯乙烯，聚酰胺，聚氨酯，（甲基） 丙烯酸酯和苯乙烯共聚物; （b）至少一种水不溶性染料; （c）由下式表示的载体：<？in-line-formula description =“In-line formula”end =“lead”？> R < - O-（CH
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公开(公告)号：US06749646B2
公开(公告)日：2004-06-15
申请号：US10040178
申请日：2001-11-07
申请人： Robert A. Pyles , Rick L. Archey
发明人： Robert A. Pyles , Rick L. Archey
IPC分类号： D06P700
CPC分类号： D06P3/54 , D06P1/613 , D06P1/65131
摘要： A process for tinting of articles molded from a polymeric resin is disclosed. Preferably, the article is molded from polycarbonate and the process entails immersing the molded article in a dye bath that contains water, dye, a carrier and an optional surfactant. The carrier is a compound conforming to R1[—O—(CH2)n]mOR2 (i) wherein R1 and R2 independently denote H or C1-18 alkyl, benzyl, benzoyl or phenyl radical which may be substituted in the aromatic ring by alkyl and or halogen, preferably R1=butyl, R2=H, n is 2 or 3 and m is 2 to 35. The method is especially useful in the manufacture of tinted lenses.
摘要翻译： 公开了一种用于着色由聚合物树脂模制的制品的方法。 优选地，制品由聚碳酸酯成型，并且该方法需要将模制品浸入含有水，染料，载体和任选的表面活性剂的染浴中。 载体是符合其中R 1和R 2的化合物独立地表示H或C 1-18烷基，苄基，苯甲酰基或苯基，其可以在芳环中被烷基和/或卤素取代，优选R 1， =丁基，R 2 = H，n为2或3，m为2至35.该方法在着色透镜的制造中特别有用。
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14.发明授权Expansion of polymeric microspheres insitu in a rigid PUR/PIR foam formulation using a twin screw extruder 失效使用双螺杆挤出机将刚性PUR / PIR泡沫配制物中的聚合物微球膨胀
公开(公告)号：US6022912A
公开(公告)日：2000-02-08
申请号：US158209
申请日：1998-09-22
IPC分类号： B29B7/46 , B29B7/88 , B29C70/66 , B29K101/00 , B29K105/04 , C08G18/00 , C08G18/08 , C08G18/42 , C08G101/00 , C08J9/224 , C08J9/32 , B29D31/00 , B29C35/00 , C08J3/00 , C08K9/00 , C08L75/00
CPC分类号： C08J9/32 , B29C70/66 , C08G18/0876 , C08G18/4208 , C08J9/224 , C08G2101/0025 , C08J2203/14 , C08J2203/22 , C08J2375/04
摘要： The present invention relates to a process for producing a dispersion of polymeric microspheres in a polyol comprising expanding 1 to 70% by weight of polymeric beads in a polyol with a twin screw extruder to simultaneously mix and expand the beads to create a uniform dispersion of the microspheres in the polyol such that the wetting of the microspheres by the polyol is maximized.
摘要翻译： 本发明涉及在多元醇中制备聚合物微球分散体的方法，该方法包括用双螺杆挤出机在多元醇中使1-70重量％的聚合物珠膨胀，同时混合和膨胀珠粒以产生均匀的分散体 多元醇中的微球，使得多元醇对微球的润湿最大化。
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公开(公告)号：US5399658A
公开(公告)日：1995-03-21
申请号：US146284
申请日：1993-10-29
CPC分类号： C08G64/42 , C08G64/081 , C08L69/00
摘要： A gamma radiation-resistant polycarbonate-disulfide resin is disclosed. The incorporation of disulfide linkages in the structure of polycarbonate was found to enhance the resistance of the resin to the discoloration caused by exposure to gamma radiation. Accordingly, processes for the incorporation of disulfide linkages in the molecular backbone, as end-groups or as side chains are disclosed. The polycarbonate-disulfide resin may be used as a molding resin in the context of thermoplastic molding compositions as well as a stabilizing additive in polycarbonate resin.
摘要翻译： 公开了一种耐伽马辐射的聚碳酸酯 - 二硫化物树脂。 发现在聚碳酸酯结构中引入二硫键增加了树脂对由于暴露于γ辐射引起的变色的抵抗力。 因此，公开了在分子主链中作为端基或作为侧链引入二硫键的方法。 聚碳酸酯 - 二硫化物树脂可以在热塑性模塑组合物和聚碳酸酯树脂中的稳定添加剂的情况下用作模制树脂。
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公开(公告)号：US5294729A
公开(公告)日：1994-03-15
申请号：US97743
申请日：1993-07-27
CPC分类号： C07C69/96
摘要： A process for preparing a block oligocarbonate is disclosed. The oligocarbonate conforms to ##STR1## where R denotes hydrogen or ##STR2## and where A denotes an aromatic carbonate structure conforming to ##STR3## where Ar is an aromatic radical, n is 2-6 and where B is the residue of an aliphatic polyol is disclosed. In the process a high molecular weight aromatic polycarbonate is reacted, in the melt and in the presence of a catalyst, with an aliphatic polyol. The block oligocarbonate is useful as a reactant in a process for the preparation of copolymers.
摘要翻译： 公开了制备低聚碳酸酯嵌段的方法。 低聚碳酸酯符合RABAR或者IMAGE，其中R表示氢或“IMAGE”，其中A表示符合
的芳族碳酸酯结构，其中Ar是芳族基团，n是2-6，其中B是 公开了脂族多元醇。 在此过程中，高分子量芳族聚碳酸酯在熔体和催化剂存在下与脂族多元醇反应。 在制备共聚物的方法中，低聚碳酸酯嵌段可用作反应物。 -
17.发明申请POLYCARBONATE COMPOSITIONS HAVING IMPROVED WATER RESISTANCE AND RELATED METHODS 审中-公开具有改善的耐水性和相关方法的聚碳酸酯组合物公开(公告)号：US20130090419A1
公开(公告)日：2013-04-11
申请号：US13253213
申请日：2011-10-05
摘要： The present invention relates to compositions containing a polycarbonate including a bisphenol compound and an effective amount of a bishaloformate component present in an amount sufficient to reduce the average unbound bisphenol compound level found in water after immersion in deionized water for two weeks at 40° C. of the composition to less than about 20 ppb. Also provided are methods for increasing the water resistance of a polycarbonate composition. The method involves adding an effective amount of a bishaloformate component to the polycarbonate composition such that the polycarbonate composition has an average unbound bisphenol compound level found in water after immersion in deionized water for two weeks at 40° C. of less than about 20 ppb.
摘要翻译： 本发明涉及包含双酚化合物的聚碳酸酯和有效量的双卤代甲酸酯组分的组合物，其量足以降低在40℃下浸入去离子水中2周后在水中发现的平均未结合双酚化合物水平。 的组成小于约20ppb。 还提供了增加聚碳酸酯组合物的耐水性的方法。 该方法包括向聚碳酸酯组合物中加入有效量的双卤代甲酸酯组分，使得聚碳酸酯组合物在40℃下浸入去离子水中两周后，在水中发现的平均未结合双酚化合物水平小于约20ppb。
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公开(公告)号：US5986019A
公开(公告)日：1999-11-16
申请号：US926271
申请日：1997-09-05
申请人： Rick L. Archey , James P. Mason , Leslie J. Vescio
发明人： Rick L. Archey , James P. Mason , Leslie J. Vescio
IPC分类号： C08G64/18 , C08G77/448 , C08G81/00
CPC分类号： C08G77/448 , C08G64/18
摘要： A process for making a copolymeric resin is disclosed. Accordingly, component (a) and component (b) are introduced into an extruder under conditions designed to promote reactive blending therebetween in the presence of a transesterification catalyst. Component (a) is a wet aromatic polycarbonate resin containing moisture in an amount greater than 0.02 weight percent and having units conforming to ##STR1## wherein D is a divalent residue of a dihydroxy compound. Component (b) is a lactone-siloxane block copolymer having structural units conforming to ##STR2## wherein m is 1-90, n is 60-150, R is an alkyl or a phenyl radical, p is 2-12 and q is 2-20. Surprisingly, use of moisture-containing polycarbonate in the process yields a copolymer having good properties, although a corresponding process where the lactone-siloxane block copolymer reactant has a smaller number of repeating units yields inferior product.
摘要翻译： 公开了制备共聚树脂的方法。 因此，在酯交换催化剂存在下，在设计为促进其间的反应性共混的条件下，将组分（a）和组分（b）引入挤出机中。 组分（a）是含有大于0.02重量％的水分并且具有符合其中D是二羟基化合物的二价残基的单元的湿芳族聚碳酸酯树脂。 组分（b）是具有符合其结构单元的内酯 - 硅氧烷嵌段共聚物，其中m为1-90，n为60-150，R为烷基或苯基，p为2-12，q为2-20。 令人惊奇的是，在该方法中使用含水分的聚碳酸酯产生具有良好性能的共聚物，尽管内酯 - 硅氧烷嵌段共聚物反应物具有较少数量的重复单元的相应方法产生较差的产物。
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公开(公告)号：US5187211A
公开(公告)日：1993-02-16
申请号：US305301
申请日：1989-02-01
摘要： The invention relates to thermoplastic polycarbonate molding compositions which are rendered resistant to gamma-radiation by incorporating therewith about 0.1 to about 5 percent by weight of a stabilizing agent selected from the group consisting of ##STR1## wherein R is a hydrogen or a halogen atom or a C.sub.1 -C.sub.10 alkyl, a C.sub.6 -C.sub.10 alkyl, a C.sub.6 -C.sub.10 aryl, C.sub.1 -C.sub.22 acyl, C.sub.6 -C.sub.18 alkylaryl or a C.sub.4 -C.sub.10 cycloalkyl radical, n is an integer of at least 1 and preferably 1 to about 100 and Y and Y.sup.1 independently are a hydrogen atom, a C.sub.6 -C.sub.10 aryl, C.sub.1 -C.sub.10 alkyl or a C.sub.6 -C.sub.18 alkylaryl or a C.sub.6 -C.sub.18 arylalkyl radical or ##STR2## wherein m is 1 or 3-6, R.sub.1, R.sub.2 and R.sub.3 independently are a hydrogen atom or a C.sub.1 -C.sub.10 alkyl, C.sub.6 -C.sub.10 aryl or a C.sub.6 -C.sub.18 alkylaryl radical.
摘要翻译： 本发明涉及热塑性聚碳酸酯模塑组合物，其通过加入约0.1至约5重量％的选自下组的稳定剂，使其具有抗γ辐射的抗性。 其中R是氢或卤素原子或C 1 -C 10烷基，C 6 -C 10烷基，C 6 -C 10芳基，C 1 -C 22酰基，C 6 -C 18烷基芳基或C 4 -C 10环烷基，n是 至少1，优选1至约100，Y和Y 1独立地为氢原子，C 6 -C 10芳基，C 1 -C 10烷基或C 6 -C 18烷基芳基或C 6 -C 18芳烷基或III。 或
IV。 或 V.或 VI。 其中m为1或3-6，R 1，R 2和R 3独立地为氢原子或C 1 -C 10烷基，C 6 -C 10芳基或C 6 -C 18烷基芳基。 -
20.发明授权公开(公告)号：US06174959B1
公开(公告)日：2001-01-16
申请号：US09132575
申请日：1998-08-11
申请人： Jane F. Ciebien , Rick L. Archey , H. Lee Noble
发明人： Jane F. Ciebien , Rick L. Archey , H. Lee Noble
IPC分类号： C08L7508
CPC分类号： C08G18/758 , C08G18/0895 , C08L75/08 , C08L23/00
摘要： A thermoplastic molding composition comprising a thermoplastic polyurethane and an olefinic copolymer is disclosed. The polyurethane component contains ether structural units and units derived from an aliphatic isocyanate. The molecular structure of the copolymer contains units derived from monomers containing olefinic unsaturation. The composition is characterized in the compatibility of its resinous components and in the improved mechanical properties.
摘要翻译： 公开了一种包含热塑性聚氨酯和烯烃共聚物的热塑性模塑组合物。 聚氨酯组分含有醚结构单元和衍生自脂族异氰酸酯的单元。 共聚物的分子结构包含衍生自含有烯属不饱和单体的单体。 该组合物的特征在于其树脂组分的相容性和改进的机械性能。
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