公开(公告)号：US20200299421A1

公开(公告)日：2020-09-24

申请号：US15780498

申请日：2016-11-28

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Bandar Abdullah Almohammadi ,  Akhlaq Moman ,  Ahmad Abdullah Alshaiban ,  Inaamul Haq Siddiqui ,  Sudhakar R. Padmanabhan

IPC: C08F10/06

Abstract: A procatalyst for polymerization of olefins, based on a magnesium compound of the formula MgR′R″ wherein R′ is an alkoxide or aryloxide group and R″ is an alkoxide or aryloxide group or halogen that has been reacted with a tetravalent titanium halide, an activator being a monoester and an internal donor of formula B: as described herein. Also described is a polymerization catalyst system comprising the procatalyst, a co-catalyst and optionally an external electron donor; a process of making a polyolefin by contacting an olefin with the catalyst system; a polyolefinobtained by or obtainable by the process; and a polyolefin, preferably a polypropylene, having a molecular weight distribution of between 3 and 15, a molecular weight (Mw) of between 200,000 to 1,000,000 g/mol, a melting temperature of more than 145° C., a value for the xylene solubles of less than 4 wt. % and a shaped article therefrom.

公开(公告)号：US20200048378A1

公开(公告)日：2020-02-13

申请号：US16337036

申请日：2017-09-14

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Akhlaq Moman ,  Inaamul Haq Siddiqui ,  Sudhakar R. Padmanabhan ,  Osamah Al-Humaidan ,  Haitham Al-Enazi

IPC: C08F110/06

Abstract: The present invention relates to a process for the preparation of a procatalyst suitable for preparing a catalyst composition for olefin polymerization, said process comprising the steps of: Step A) providing or preparing a Grignard compound; Step B) contacting in the Grignard compound with a silane compound to give a first intermediate reaction product being a solid support; Step C) activating said solid support, comprising two sub steps: Step C1) contacting the solid support obtained in step B) with at least one first activating compound and a second activating compound; and Step C2) a second activation step by contacting the activated solid support obtained in step C1) with an activating electron donor; to obtain a second intermediate reaction product; Step D) reacting the second intermediate reaction product obtained in step C) with a halogen-containing Ti-compound, optionally an activator and at least one internal electron donor in several sub steps to obtain said procatalyst. The invention moreover relates to a procatalyst, a catalytic system comprising said procatalyst and to a process to prepare polyolefins using said catalyst system and the polyolefins obtained therewith.

公开(公告)号：US20190225718A1

公开(公告)日：2019-07-25

申请号：US16337177

申请日：2017-09-29

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Jaiprakash Brijlal Sainani ,  Akhlaq Moman

IPC: C08F10/06 ,  C07C233/69

Abstract: The present invention relates to a procatalyst comprising the compound represented by formula A as an internal electron donor (Formula A), wherein R is hydrogen or a methyl group, N is nitrogen atom; O is oxygen atom; and C is carbon atom. The present invention also relates to a process for preparing said polymerization procatalyst and to a polymerization catalyst system comprising said procatalyst, a co-catalyst and optionally an external electron donor. Furthermore, the present invention relates to a polyolefin obtainable by the process according to the present invention and to the use of the compound of formula A as in internal electron donor in catalysts for polymerization of olefins.

公开(公告)号：US10882929B2

公开(公告)日：2021-01-05

申请号：US16337177

申请日：2017-09-29

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Jaiprakash Brijlal Sainani ,  Akhlaq Moman

IPC: C08F10/06 ,  C08F110/06 ,  C07C233/69

Abstract: The present invention relates to a procatalyst comprising the compound represented by formula A as an internal electron donor (Formula A), wherein R is hydrogen or a methyl group, N is nitrogen atom; O is oxygen atom; and C is carbon atom. The present invention also relates to a process for preparing said polymerization procatalyst and to a polymerization catalyst system comprising said procatalyst, a co-catalyst and optionally an external electron donor. Furthermore, the present invention relates to a polyolefin obtainable by the process according to the present invention and to the use of the compound of formula A as in internal electron donor in catalysts for polymerization of olefins.

公开(公告)号：US10882924B2

公开(公告)日：2021-01-05

申请号：US16337138

申请日：2017-09-29

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Jaiprakash Brijlal Sainani ,  Akhlaq Moman

IPC: C08F4/651 ,  C08F110/06 ,  C07C271/16 ,  C07C271/22 ,  C08F4/654 ,  C08F4/659

Abstract: The present invention relates to a procatalyst comprising the compound represented by formula A as an internal electron donor, Formula A wherein R is hydrogen or a methyl group, N is nitrogen atom; O is oxygen atom; and C is carbon atom. The present invention also relates to a process for preparing said polymerization procatalyst and to a polymerization catalyst system comprising said procatalyst, a co-catalyst and optionally an external electron donor. Furthermore, the present invention relates to a polyolefin obtainable by the process according to the present invention and to the use of the compound of formula A as in internal electron donor in catalysts for polymerization of olefins.

公开(公告)号：US20200332102A1

公开(公告)日：2020-10-22

申请号：US16956187

申请日：2018-12-18

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Henrica Norberta Alberta Maria Steenbakkers-Menting ,  Patrick Elisabeth Luc Voets ,  Martin Alexander Zuideveld ,  Akhlaq Moman

IPC: C08L23/12

Abstract: The invention relates to a polypropylene composition comprising a propylene homopolymer or propylene-ethylene copolymer having an ethylene content of at most (1.0) wt % based on the propylene-ethylene copolymer, wherein the amount of propylene homopolymer or propylene-ethylene copolymer is at least (98) wt %, for example at least (98.5) wt %, preferably at least (99) wt %, more preferably at least (99.5), for example at least (99.75) wt % based on the polypropylene composition, wherein the polypropylene composition has a melt flow rate in the range of (0.10) to less than (0.70) dg/min as measured according to ISO1133 (2.16 kg/230° C.), an Mw/Mn in the range from (7.0) to (13.0), wherein Mw stands for the weight average molecular weight and Mn stands for the number average weight, an Mz/Mn is in the range from (20) to (50), wherein Mz stands for the z-average molecular weight and wherein Mw, Mn and Mz are measured according to ASTM (D6474-12).

公开(公告)号：US20190225716A1

公开(公告)日：2019-07-25

申请号：US16337138

申请日：2017-09-29

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Jaiprakash Brijlal Sainani ,  Akhlaq Moman

IPC: C08F4/651 ,  C08F4/659 ,  C08F4/654 ,  C07C271/22

Abstract: The present invention relates to a procatalyst comprising the compound represented by formula A as an internal electron donor, Formula A wherein R is hydrogen or a methyl group, N is nitrogen atom; O is oxygen atom; and C is carbon atom. The present invention also relates to a process for preparing said polymerization procatalyst and to a polymerization catalyst system comprising said procatalyst, a co-catalyst and optionally an external electron donor. Furthermore, the present invention relates to a polyolefin obtainable by the process according to the present invention and to the use of the compound of formula A as in internal electron donor in catalysts for polymerization of olefins.

公开(公告)号：US20190153126A1

公开(公告)日：2019-05-23

申请号：US16066442

申请日：2016-12-23

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Akhlaq Moman ,  Ian Blackmore

IPC: C08F4/656 ,  C08F4/659 ,  C08F4/651 ,  C08F110/02

CPC classification number: C08F4/6565 ,  C08F2/34 ,  C08F4/651 ,  C08F4/6546 ,  C08F4/65916 ,  C08F110/02 ,  C08F210/02 ,  Y02P20/52 ,  C08F4/6567 ,  C08F2500/02 ,  C08F2500/12 ,  C08F110/06 ,  C08F4/025

Abstract: The present invention relates to a process for preparing a solid catalyst component suitable for producing polyethylene and its copolymers, said process comprising the steps of: (a) contacting a dehydrated support having hydroxyl groups with a magnesium compound having the general formula MgR1R2; (b) contacting the product obtained in step (a) with modifying compounds (A) and/or (B) and/or (C), wherein: (A) is at least one oxygen and/or nitrogen comprising organic compound; (B) is a compound having the general formula R11f(R12O)gSiXh, (C) is a compound having the general formula (R13O)4M, and (c) contacting the product obtained in step (b) with a titanium halide compound having the general formula TiX4, wherein Ti is a titanium atom and X is a halide atom, wherein an organometallic compound is added either before step (a) and/or after step (c). The invention also relates to a solid catalyst component obtainable by said process. The invention further relates to a process for producing polyethylene and its copolymers in the presence of the solid catalyst component and a co-catalyst.

公开(公告)号：US20180362680A1

公开(公告)日：2018-12-20

申请号：US15780538

申请日：2016-11-23

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Akhlaq Moman ,  Abdulaziz Al-Humydi ,  Inaamul Haq Siddiqui ,  Sudhakar R. Padmanabhan ,  Bandar Abdullah Almohammadi ,  Ahmad Abdullah Alshaiban

IPC: C08F110/06

CPC classification number: C08F110/06 ,  C08F4/651 ,  C08F4/6548 ,  C08F2500/04 ,  C08F2500/15 ,  C08F2500/18 ,  C08F2500/01

Abstract: A procatalyst for polymerization of olefins, which procatalyst is based on a magnesium compound of the formula MgR′R″ wherein R′ is an alkoxide or aryloxide group and R″ is an alkoxide or aryloxide group or halogen, an activator being a monoester and an internal donor represented by a compound according to formula A: as described herein. Also described is a polymerization catalyst system comprising the procatalyst, a co-catalyst and optionally an external electron donor; a process of making a polyolefin, by contacting an olefin with the catalyst system; a polyolefin, obtained by or obtainable by the process; and a polyolefin, having a molecular weight distribution of between 4 and 15, a molecular weight (Mw) of between 300,000 to 1,500,000 g/mol, a melting temperature of more than 150° C., a value for the xylene solubles of less than 4 wt. % and a shaped article therefrom.

公开(公告)号：US11879026B2

公开(公告)日：2024-01-23

申请号：US17260669

申请日：2019-07-22

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Henrica Norberta Alberta Maria Steenbakkers-Menting ,  Patrick Elisabeth Luc Voets ,  Desiree Marie Louise Seegers ,  Erik Delsman ,  Ibrahim Mohammad Alsugai ,  Musaad Al-Sadhan ,  Martin Alexander Zuideveld ,  Akhlaq Moman

IPC: C08F210/16 ,  C08L23/16 ,  C08F210/06 ,  C08F210/02 ,  C08F210/14 ,  F16L9/12

CPC classification number: C08F210/06 ,  C08F210/02 ,  C08F210/14 ,  C08F210/16 ,  F16L9/12 ,  C08F2500/36 ,  C08L23/16

Abstract: The invention relates to a polypropylene composition comprising a terpolymer containing propylene, ethylene and 1-hexene wherein the polypropylene composition (i) has a content of ethylene derived units of at least 1.5 wt %; (ii) has a content of 1-hexene derived units of at least 1.5 wt %; (iii) has a melt flow rate of 0.10 to 0.70 g/10 min determined by ISO 1133-1:2011 (230° C., 2.16 kg); and (iv) has a ratio of weight average molecular weight (Mw) to numeric average molecular (Mn) weight of the terpolymer of 7.0 to 20.0, wherein Mw and Mn are measured according to ASTM D6474-12.