摘要:
Secondary batteries capable of improving cycle characteristics are provided. The secondary battery includes a cathode, an anode, and an electrolytic solution. A separator provided between the cathode and the anode is impregnated with the electrolytic solution. The electrolytic solution contains a solvent and an electrolyte salt. The solvent contains a cyclic compound having a disulfonic acid anhydride group (—S(═O)2-O—S(═O)2-) and at least one of a nitrile compound. Compared to a case that the solvent does not contain both the cyclic compound having the disulfonic acid anhydride group and succinonitrile or a case that that the solvent contains at least one thereof, chemical stability of the electrolytic solution is improved. Thus, even if charge and discharge are repeated, electrolytic solution decomposition is inhibited.
摘要:
A secondary battery includes: a cathode; an anode; and a gel electrolyte. The gel electrolyte includes an electrolytic solution and a polymer compound. The electrolytic solution includes an unsaturated cyclic ester carbonate represented by the following Formula (1), where X is a divalent group in which m number of >C═CR1-R1 and n number of >CR3R4 are bonded in any order; each of R1 to R4 is one of a hydrogen group, a halogen group, a monovalent hydrocarbon group, a monovalent halogenated hydrocarbon group, a monovalent oxygen-containing hydrocarbon group, and a monovalent halogenated oxygen-containing hydrocarbon group; any two or more of the R1 to the R4 are allowed to be bonded to one another; and m and n satisfy m≧1 and n≧0.
摘要:
A secondary battery includes: a cathode; an anode; and an electrolytic solution. The anode includes an anode active material layer on an anode current collector. The anode active material layer includes a carbon material. The anode active material layer has a thickness from about 30 micrometers to about 100 micrometers both inclusive. The electrolytic solution includes an unsaturated cyclic ester carbonate represented by the following Formula (1) (X is a divalent group in which m-number of >C═CR1R2 and n-number of >CR3R4 are bonded in any order. Each of R1 to R4 is one of a hydrogen group, a halogen group, a monovalent hydrocarbon group, a monovalent halogenated hydrocarbon group, a monovalent oxygen-containing hydrocarbon group, and a monovalent halogenated oxygen-containing hydrocarbon group. Any two or more of the R1 to the R4 are allowed to be bonded to one another. m and n satisfy m≧1 and n≧0).
摘要:
An electrolytic solution including a solvent including 4,5-difluoro-1,3-dioxolane-2-one. The content of 4,5-difluoro-1,3-dioxolane-2-one is preferably within a range from 5 wt % to 50 wt % In the case where 4,5-difluoro-1,3-dioxolane-2-one is mixed and used with 4-fluoro-1,3-dioxolane-2-one, the content of 4,5-difluoro-1,3-dioxolane-2-one is preferably within a range from 5 vol ppm to 2000 vol ppm.
摘要:
A secondary battery includes: a cathode; an anode; and an electrolytic solution. The electrolytic solution includes an unsaturated cyclic ester carbonate and one or more selected from a group configured of aromatic compounds, dinitrile compounds, sulfinyl compounds, and lithium salts.
摘要:
An electrolytic solution including a solvent including 4,5-difluoro-1,3-dioxolane-2-one. The content of 4,5-difluoro-1,3-dioxolane-2-one is preferably within a range from 5 wt % to 50 wt % In the case where 4,5-difluoro-1,3-dioxolane-2-one is mixed and used with 4-fluoro-1,3-dioxolane-2-one, the content of 4,5-difluoro-1,3-dioxolane-2-one is preferably within a range from 5 vol ppm to 2000 vol ppm.
摘要:
A battery capable of improving the storage characteristics and the cycle characteristics is provided. The battery includes a cathode, an anode, and an electrolytic solution. The electrolytic solution is impregnated in a separator provided between the cathode and the anode. A solvent of the electrolytic solution contains a given sulfone compound such as bis(trimethylsilyl)-2,2-difluorosulfoacetate. Compared to a case that a solvent does not contain the foregoing sulfone compound, the chemical stability of the electrolytic solution is improved, and the decomposition reaction of the electrolytic solution is suppressed.
摘要:
A secondary battery capable of improving cycle characteristics, conservation characteristics, and load characteristics is provided. The secondary battery includes a cathode, an anode, and an electrolytic solution. A separator provided between the cathode and the anode is impregnated with an electrolytic solution. The electrolytic solution includes one or more of a dicarbonic ester compound, a dicarboxylic compound, a disulfonic compound, a monofluoro lithium phosphate, and difluoro lithium phosphate and one or more of fluorinated lithium phosphate, fluorinated lithium borate, and imide lithium.
摘要:
A secondary battery includes: a cathode including a lithium-oxygen-containing compound; an anode; and non-aqueous electrolytic solution including one or more first anions represented by Formula (1). B(XY)xFyRz- (1) where X is one of a divalent chain hydrocarbon group, a divalent fluorinated chain hydrocarbon group, and nothing; Y is one of a cyano group (—C≡N) and an isocyano group (—N+≡C—); R is one of a monovalent fluorinated chain hydrocarbon group and a monovalent fluorinated cyclic hydrocarbon group; and x to z are integers that satisfy x>0, y≥0, z≥0, (x+y+z)=4, and (y+z)>0.
摘要:
A secondary battery capable of improving cycle characteristics, conservation characteristics, and load characteristics is provided. The secondary battery includes a cathode, an anode, and an electrolytic solution. A separator provided between the cathode and the anode is impregnated with an electrolytic solution. The electrolytic solution includes one or more of a dicarbonic ester compound, a dicarboxylic compound, a disulfonic compound, a monofluoro lithium phosphate, and difluoro lithium phosphate and one or more of fluorinated lithium phosphate, fluorinated lithium borate, and imide lithium.