Method for preparing molded articles of syndiotactic polypropylene
    14.
    发明授权
    Method for preparing molded articles of syndiotactic polypropylene 失效
    间规聚丙烯的制备方法

    公开(公告)号:US5759469A

    公开(公告)日:1998-06-02

    申请号:US719514

    申请日:1996-09-25

    摘要: A molded article of a syndiotactic polypropylene having excellent transparency in which a melting point attributed to the polypropylene having the syndiotactic structure measured at a heating rate of 10.degree. C./minute by differential scanning thermal analysis is represented by a substantially single peak, the aforesaid molded article being prepared by heating, melting and then hot-molding a homopolymer of propylene or a copolymer of propylene and a small amount of another olefin, which have a substantially syndiotactic structure, or a mixture of the homopolymer or the copolymer and a small amount of a polypropylene having a substantially isotactic structure, followed by quenching, or, after these steps, additionally subjecting the above molded article to a heat treatment at a temperature of less than its melting point. A method for preparing the above molded article is also disclosed here.

    摘要翻译: 间隔立构聚丙烯的模塑制品具有优异的透明性,其中通过差示扫描热分析以10℃/分钟的加热速率测量的具有间同立构结构的聚丙烯的熔点由基本上单峰表示,上述 通过将具有基本上间同立构结构的丙烯或丙烯与少量的另一种烯烃的共聚物或均聚物或共聚物的混合物和少量的均聚物进行加热,熔融,然后热模塑, 的具有基本上全同立构结构的聚丙烯,然后淬火,或者在这些步骤之后,另外对上述模塑制品在低于其熔点的温度进行热处理。 此处也公开了制备上述模制品的方法。

    Olefin polymerization catalyst system
    17.
    发明授权
    Olefin polymerization catalyst system 失效
    烯烃聚合催化剂体系

    公开(公告)号:US6063725A

    公开(公告)日:2000-05-16

    申请号:US743374

    申请日:1996-11-04

    摘要: An olefin polymerization catalyst system comprising an organic transition metal compound and a support, wherein an organic transition metal compound is soluble in an inert organic solvent and a support which is insoluble in the inert organic solvent, and the support comprises an organic high molecular weight compound which contains a specific carbonyl-containing group. The catalyst system can polymerize an olefin in a high activity, provides polymer with high stereoregularity, prevents adhesion or fouling of the polymer generated in the course of polymerization or an organic aluminum oxy compound on the inner wall of the reactor, leads to high bulk density of the polymer and very reduced level of fisheye and/or gel generation on the processed item, can maintain high productivity, can manufacture high quality product, and thus provides extremely high contribution in industry.

    摘要翻译: 一种包含有机过渡金属化合物和载体的烯烃聚合催化剂体系,其中有机过渡金属化合物可溶于惰性有机溶剂和不溶于惰性有机溶剂的载体,载体包含有机高分子量化合物 其含有特定的含羰基。 催化剂体系可以以高活性聚合烯烃,提供具有高立构规整性的聚合物,防止在聚合过程中产生的聚合物的粘附或结垢或反应器内壁上的有机铝氧化合物导致高堆积密度 的聚合物,并且处理物品上的鱼眼和/或凝胶生成水平非常降低,可以保持高生产率,可以制造高品质的产品,从而在工业中提供极高的贡献。

    Polyimide resin composition
    18.
    发明授权
    Polyimide resin composition 失效
    聚酰亚胺树脂组合物

    公开(公告)号:US5494996A

    公开(公告)日:1996-02-27

    申请号:US277568

    申请日:1994-07-20

    CPC分类号: C08L79/08 C08L79/04

    摘要: A polyimide resin composition substantially comprising 1 99.9.about.50 parts by weight of polyimide having recurring structural units of the formula ##STR1## and 2 0.1.about.50 parts by weight of a polyimide which improved melt flowability and is prepared by using 1,3-bis(3-aminophenoxy)benzene or 6,6'-bis(3-aminophenoxy)-3,3,3',3'-tetramethyl-1,1'-spirobiindane as essential diamine component, or polyether pyridine having recurring structural units of the formula: ##STR2## is disclosed. Further, a polyimide based resin composition comprising the polyimide resin composition or a polyimide copolymer obtained by using the above diamines and a fibrous reinforcement is disclosed. These compositions have remarkably good processability, excellent heat stability and repeated fatigue characteristics.

    摘要翻译: 一种聚酰亚胺树脂组合物,其基本上包含+ E,crc / 1 / 99.9差异50重量份具有式(1)的重复结构单元的聚酰亚胺和+ E,crc / 2 / 0.1差异50重量份的 通过使用1,3-双(3-氨基苯氧基)苯或6,6'-双(3-氨基苯氧基)-3,3,3',3'-四甲基-1,1' - 螺环丁烷作为必需二胺组分,或具有下式重复结构单元的聚醚吡啶:。 此外,公开了一种聚酰亚胺系树脂组合物,其包含使用上述二胺和纤维增强剂而得到的聚酰亚胺树脂组合物或聚酰亚胺共聚物。 这些组合物具有非常好的加工性能,优异的热稳定性和重复的疲劳特性。

    Polypropylene fiber and a preparation process thereof
    19.
    发明授权
    Polypropylene fiber and a preparation process thereof 失效
    聚丙烯纤维及其制备方法

    公开(公告)号:US5478646A

    公开(公告)日:1995-12-26

    申请号:US15056

    申请日:1993-02-08

    IPC分类号: D01F6/06 D02G3/00

    摘要: A fiber excellent in strength and having an average size of 10,000-0.1 denier can be obtained by extruding a raw material composed mainly of a polypropylene having a syndiotactic pentad fraction of 0.7 or more and optionally stretching the resulting extruded material.By using as the raw material a composition consisting of two kinds of polypropylenes each having an intrinsic viscosity .eta..sub.1 or .eta..sub.2, the log(.eta..sub.2 /.eta..sub.1) being more than 0.05 or less than -0.05, and a syndiotactic pentad fraction of 0.7 or more at a weight ratio of 95:5-5:95 or a composition consisting of at least 50 parts by weight of a syndiotactic polypropylene having the intrinsic viscosity .eta..sub.1 and a syndiotactic pentad fraction of 0.7 or above and at most 50 parts by weight of an isotactic polypropylene having the intrinsic viscosity .eta..sub.2, the extrudability is improved and the fiber stretching conditions are broadened.

    摘要翻译: 通过将主要由间同立构五单元组分为0.7以上的聚丙烯组成的原料挤出并任选地拉伸所得的挤出材料,可以获得强度优异且平均粒径为10,000-0.1旦尼尔的纤维。 通过使用由两种各自具有特性粘度eta 1或eta 2的聚丙烯组成的组合物,log(eta 2 / eta 1)大于0.05或小于-0.05,并且间同立构五单元组分数 0.7重量%以上,重量比为95:5.5:95的组合物或由至少50重量份的特性粘度η1和间同立构五单元组分数为0.7以上至多50份的间同立构聚丙烯组成的组合物 的特性粘度等于2的全同立构聚丙烯,可挤出性提高,纤维拉伸条件变宽。