公开(公告)号：US5428121A

公开(公告)日：1995-06-27

申请号：US272868

申请日：1994-07-08

申请人： Tadashi Asanuma ,  Tsutomu Iwatani ,  Ryuichi Sugimoto ,  Norihide Inoue ,  Masahiro Kouno ,  Tetsunosuke Shiomura

发明人： Tadashi Asanuma ,  Tsutomu Iwatani ,  Ryuichi Sugimoto ,  Norihide Inoue ,  Masahiro Kouno ,  Tetsunosuke Shiomura

IPC分类号： C08F110/06 ,  C08F4/60 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F8/00 ,  C08F210/06 ,  C08F10/06

CPC分类号： C08F210/06 ,  C08F4/65912 ,  C08F4/65927 ,  Y10S526/903

摘要： A method for preparing a propylene (co)polymer having a substantially high syndiotactic structure and a desired molecular weight which comprises the step of (co)polymerizing propylene or propylene and a small amount of another olefin by the use of a transition metal compound catalyst having asymmetric ligands in the presence of a specific internal olefin.

摘要翻译： 一种制备具有基本上高的间同立构结构和所需分子量的丙烯（共）聚合物的方法，该方法包括通过使用过渡金属化合物催化剂（共）聚合丙烯或丙烯和少量另一种烯烃的步骤 在特定的内烯烃存在下的不对称配体。

公开(公告)号：US5658999A

公开(公告)日：1997-08-19

申请号：US543823

申请日：1995-10-16

申请人： Norihide Inoue ,  Masahiro Kouno ,  Yoshiho Sonobe ,  Kazumi Mizutani ,  Tetsunosuke Shiomura ,  Nobuhiro Hirayama

发明人： Norihide Inoue ,  Masahiro Kouno ,  Yoshiho Sonobe ,  Kazumi Mizutani ,  Tetsunosuke Shiomura ,  Nobuhiro Hirayama

IPC分类号： C08F4/659 ,  C08F4/6592 ,  C08F110/06

CPC分类号： C08F110/06 ,  C08F4/65916 ,  C08F4/65912 ,  C08F4/65922 ,  C08F4/65927 ,  Y10T436/148888 ,  Y10T436/172307

摘要： Described herein are propylene waxes and a production process thereof. The waxes are each produced by polymerizing propylene in a reaction vessel while using a solid catalyst in the presence or absence of an organoaluminum compound. A hydrogen partial pressure of a gas phase in the reaction vessel, said gas phase being formed of the propylene and hydrogen, is maintained at 10% or higher. The solid catalyst is formed of a transition metal compound or a reaction product between the transition metal compound and an organometallic compound, an aluminoxane and a fine particulate carrier. Also described herein is a heating-roll fixing type toner composition composed essentially of a binder resin or a binder resin composition, a colorant and, as a releasing agent, the wax.

公开(公告)号：US5439994A

公开(公告)日：1995-08-08

申请号：US277570

申请日：1994-07-20

申请人： Norihide Inoue ,  Tetsunosuke Shiomura ,  Masahiro Kouno ,  Yoshiho Sonobe ,  Kazumi Mizutani

发明人： Norihide Inoue ,  Tetsunosuke Shiomura ,  Masahiro Kouno ,  Yoshiho Sonobe ,  Kazumi Mizutani

IPC分类号： C08F4/642 ,  C07F17/00 ,  C08F4/60 ,  C08F4/64 ,  C08F4/646 ,  C08F4/659 ,  C08F4/6592 ,  C08F4/76 ,  C08F8/00 ,  C08F10/00 ,  C08F10/06

CPC分类号： C07F17/00 ,  C08F10/00 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65927 ,  Y10S526/943

摘要： A novel transition metal compound represented by the formula ##STR1## (wherein each of A.sup.1, A.sup.2, A.sup.3 and A.sup.4 is a cyclopentadienyl group, an indenyl group, a fluorenyl group or their derivative; A.sup.5 is a hydrocarbondiylidene group having 4 to 30 carbon atoms; a pair of A.sup.1 and A.sup.2 as well as a pair of A.sup.3 and A.sup.4 is respectively bonded to the identical carbon atom in A.sup.5 to form a crosslinking structure; each of R.sup.1 and R.sup.2 is a halogen atom, a hydrogen atom, an alkyl group or a silicon-containing alkyl group having 1 to 10 carbon atoms, an aryl group, an alkylaryl group, an arylalkyl group or a halogenated aryl group having 6 to 20 carbon atoms; R.sup.1 and R.sup.2 may be identical or different; each of M.sup.1 and M.sup.2 is titanium, zirconium or hafnium; and M.sup.1 and M.sup.2 may be mutually identical or different), and a method for polymerizing an olefin in the presence of this compound and a co-catalyst. The employment of the combination of the above-mentioned compound and another known transition metal compound as the transition metal compounds permits preparing a polyolefin having a wide molecular weight distribution.

摘要翻译： 由式（I）表示的新型过渡金属化合物（其中，A1，A2，A3和A4各自为环戊二烯基，茚基，芴基或其衍生物; A5为烃基亚乙基， 30个碳原子;一对A1和A2以及一对A3和A4分别与A5中的相同碳原子键合以形成交联结构; R1和R2各自为卤素原子，氢原子， 烷基或碳原子数为1〜10的含硅烷基，芳基，烷芳基，芳烷基或碳原子数为6〜20的卤代芳基; R 1和R 2可以相同或不同， M1和M2是钛，锆或铪; M1和M2可以相互相同或不同），以及在该化合物和助催化剂存在下使烯烃聚合的方法。 使用上述化合物和另一种已知的过渡金属化合物作为过渡金属化合物的组合可以制备具有宽分子量分布的聚烯烃。

公开(公告)号：US5359102A

公开(公告)日：1994-10-25

申请号：US941056

申请日：1992-10-08

申请人： Norihide Inoue ,  Tetsunosuke Shiomura ,  Masahiro Kouno ,  Yoshiho Sonobe ,  Kazumi Mizutani

发明人： Norihide Inoue ,  Tetsunosuke Shiomura ,  Masahiro Kouno ,  Yoshiho Sonobe ,  Kazumi Mizutani

IPC分类号： C08F4/642 ,  C07F17/00 ,  C08F4/60 ,  C08F4/64 ,  C08F4/646 ,  C08F4/659 ,  C08F4/6592 ,  C08F4/76 ,  C08F8/00 ,  C08F10/00 ,  C08F10/06 ,  C07F7/00 ,  C07F7/28

CPC分类号： C07F17/00 ,  C08F10/00 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65927 ,  Y10S526/943

摘要： A transition metal compound represented by the formula ##STR1## (wherein each of A.sup.1, A.sup.2, A.sup.3 and A.sup.4 is a cyclopentadienyl group, an indenyl group, a fluorenyl group or their derivative; A.sup.5 is a hydrocarbondiylidene group having 4 to 30 carbon atoms; a pair of A.sup.1 and A.sup.2 as well as a pair of A.sup.3 and A.sup.4 is respectively bonded to the identical carbon atom in A.sup.5 to form a crosslinking structure; each of R.sup.1 and R.sup.2 is a halogen atom, a hydrogen atom, an alkyl group or a silicon-containing alkyl group having 1 to 10 carbon atoms, an aryl group, an alkylaryl group, an arylalkyl group or a halogenated aryl group having 6 to 20 carbon atoms; R.sup.1 and R.sup.2 may be identical or different; each of M.sup.1 and M.sup.2 is titanium, zirconium or hafnium; and M.sup.1 and M.sup.2 may be mutually identical or different), and a method for polymerizing an olefin in the presence of this compound and a co-catalyst. A combination of the above-mentioned compound and another known transition metal compound as the transition metal compounds permits preparation of a polyolefin having a wide molecular weight distribution.

摘要翻译： PCT No.PCT / JP92 / 00080 Sec。 371日期：1992年10月8日 102（e）日期1992年10月8日PCT提交1992年1月29日PCT公布。 出版物WO92 / 15596 1，由式（I）表示的过渡金属化合物（其中A1，A2，A3和A4各自为环戊二烯基，茚基，芴基或其衍生物; A5为 具有4-30个碳原子的亚烃基亚基;一对A1和A2以及一对A3和A4分别与A5中的相同碳原子键合形成交联结构; R1和R2各自为卤素原子 具有1〜10个碳原子的氢原子，烷基或含硅烷基，芳基，烷芳基，芳烷基或碳原子数为6〜20的卤代芳基; R1和R2可以是 相同或不同; M1和M2各自为钛，锆或铪; M1和M2可以相互相同或不同），以及在该化合物和助催化剂存在下使烯烃聚合的方法。 作为过渡金属化合物的上述化合物和另一种已知的过渡金属化合物的组合可以制备具有宽分子量分布的聚烯烃。

公开(公告)号：US5677409A

公开(公告)日：1997-10-14

申请号：US436832

申请日：1995-05-08

申请人： Norihide Inoue ,  Masahiro Kouno ,  Yoshiho Sonobe ,  Kazumi Mizutani ,  Tetsunosuke Shiomura ,  Nobuhiro Hirayama

发明人： Norihide Inoue ,  Masahiro Kouno ,  Yoshiho Sonobe ,  Kazumi Mizutani ,  Tetsunosuke Shiomura ,  Nobuhiro Hirayama

IPC分类号： C08F4/659 ,  C08F4/6592 ,  C08F110/06

CPC分类号： C08F110/06 ,  C08F4/65916 ,  C08F4/65912 ,  C08F4/65922 ,  C08F4/65927 ,  Y10T436/148888 ,  Y10T436/172307

摘要： Described herein are propylene waxes and a production process thereof. The waxes are each produced by polymerizing propylene in a reaction vessel while using a solid catalyst in the presence or absence of an organoaluminum compound. A hydrogen partial pressure of a gas phase in the reaction vessel, said gas phase being formed of the propylene and hydrogen, is maintained at 10% or higher. The solid catalyst is formed of a transition metal compound or a reaction product between the transition metal compound and an organometallic compound, an aluminoxane and a fine particulate carrier. Also described herein is a heating-roll fixing type toner composition composed essentially of a binder resin or a binder resin composition, a colorant and, as a releasing agent, the wax.

摘要翻译： 本文描述的是丙烯蜡及其制备方法。 所述蜡各自通过在存在或不存在有机铝化合物的同时使用固体催化剂的同时在反应容器中聚合丙烯来制备。 反应容器中气相的氢分压，所述气相由丙烯和氢气形成，保持在10％以上。 固体催化剂由过渡金属化合物或过渡金属化合物与有机金属化合物，铝氧烷和细颗粒载体之间的反应产物形成。 本文还描述了基本上由粘合剂树脂或粘合剂树脂组合物，着色剂和作为脱模剂的蜡组成的加热辊定影型调色剂组合物。

公开(公告)号：US5652315A

公开(公告)日：1997-07-29

申请号：US663596

申请日：1996-06-14

申请人： Norihide Inoue ,  Tetsunosuke Shiomura ,  Masahiro Kouno

发明人： Norihide Inoue ,  Tetsunosuke Shiomura ,  Masahiro Kouno

IPC分类号： C08F4/64 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F210/02

CPC分类号： C08F210/02 ,  C08F4/65912 ,  C08F4/65927 ,  Y10S526/943

摘要： A method for preparing an ethylene copolymer which comprises the step of copolymerizing ethylene with an aromatic vinyl compound in the presence of a catalyst comprising (A) a specific transition metal compound represented by the formula I ##STR1## and (B) a cocatalyst such as an aluminoxane.

摘要翻译： 一种制备乙烯共聚物的方法，其包括在催化剂存在下使乙烯与芳族乙烯基化合物共聚的步骤，所述催化剂包含（A）由式I 表示的特定过渡金属化合物。

公开(公告)号：US06664365B2

公开(公告)日：2003-12-16

申请号：US09366046

申请日：1999-09-03

申请人： Tadahito Nobori ,  Masahiro Kouno ,  Toshiaki Suzuki ,  Kazumi Mizutani ,  Shinji Kiyono ,  Yoshiho Sonobe ,  Usaji Takaki

发明人： Tadahito Nobori ,  Masahiro Kouno ,  Toshiaki Suzuki ,  Kazumi Mizutani ,  Shinji Kiyono ,  Yoshiho Sonobe ,  Usaji Takaki

IPC分类号： C08G6510

CPC分类号： C07F9/065 ,  C07F9/067 ,  C08G65/2675

摘要： The present invention provides a novel salt useful as an active species in an organic reaction and represented by the following chemical formula (1): wherein n stands for an integer of from 1 to 8, Zn− represents an n-valent anion of an active hydrogen compound, a, b, c and d each stands for a positive integer, and Rs represent the same or different hydrocarbon groups. Also disclosed is a simple and efficient process for producing a poly(alkylene oxide) by polymerizing an alkylene oxide compound in the presence of the salt represented by the chemical formula (1).

摘要翻译： 本发明提供了可用作有机反应中的活性物质的新型盐，其由以下化学式（1）表示：其中n表示1至8的整数，Z n表示n价阴离子 的活性氢化合物，a，b，c和d分别表示正整数，Rs表示相同或不同的烃基。 还公开了通过在化学式（1）表示的盐的存在下聚合烯化氧化合物来制备聚（环氧烷）的简单和有效的方法。

公开(公告)号：US4795795A

公开(公告)日：1989-01-03

申请号：US828530

申请日：1986-02-12

申请人： Masahiro Kouno ,  Kazumi Mizutani ,  Masanori Osawa ,  Kohei Shizuka ,  Toshihiro Toyoda ,  Hiromi Nakano

发明人： Masahiro Kouno ,  Kazumi Mizutani ,  Masanori Osawa ,  Kohei Shizuka ,  Toshihiro Toyoda ,  Hiromi Nakano

IPC分类号： C08G18/34 ,  C08G69/26 ,  C08G73/10

CPC分类号： C08G69/26 ,  C08G18/34 ,  C08G73/1035

摘要： A polyamide and/or polyimide is prepared by using N,N'-dimethylethyleneurea or N,N'-dimethylpropyleneurea as a solvent upon polycondensation of a polycarboxylic acid and a diisocyanate at a temperature above 100.degree. C. in the presence of an alkali metal carbonate, alkali metal hydrogencarbonate, alkali metal hydroxide or an alkali metal salt of a polycarboxylic acid.

摘要翻译： 聚酰胺和/或聚酰亚胺是通过使用N，N'-二甲基亚乙基脲或N，N'-二甲基亚丙基脲作为溶剂在多元羧酸和二异氰酸酯在100℃以上的温度下在碱金属 碳酸盐，碱金属碳酸氢盐，碱金属氢氧化物或多元羧酸的碱金属盐。

公开(公告)号：US07232608B2

公开(公告)日：2007-06-19

申请号：US11122138

申请日：2005-05-04

申请人： Masahito Fujihara ,  Masahiro Kouno ,  Kazuya Edamura

发明人： Masahito Fujihara ,  Masahiro Kouno ,  Kazuya Edamura

IPC分类号： B32B9/00

CPC分类号： H05K3/1283 ,  B82Y30/00 ,  H05K3/102 ,  H05K3/107 ,  H05K3/1208 ,  H05K2201/0116 ,  H05K2201/0376 ,  H05K2203/0557 ,  H05K2203/082 ,  Y10T428/25 ,  Y10T428/30

摘要： The present invention provides a conductive material having superior bending property and superior bending resistant property and a method for manufacturing the same. This object is achieved by a conductive material comprising a substrate and a conductive portion formed within the substrate, wherein a change ratio in the electric resistance values before and after a bending resistant property test, in which the conductive portion is bent by 180 degrees and a load of 1 kg/cm2 is imposed on the bent portion for one hour, is set within a range of ±10%.

摘要翻译： 本发明提供具有优异的弯曲性和优异的抗弯曲性的导电材料及其制造方法。 该目的通过包括基板和形成在基板内的导电部分的导电材料来实现，其中导电部分弯曲180度的抗弯曲性试验之前和之后的电阻值的变化率和 在弯曲部分施加1kg / cm 2的负荷1小时，设定在±10％的范围内。

公开(公告)号：US20050255312A1

公开(公告)日：2005-11-17

申请号：US11122138

申请日：2005-05-04

申请人： Masahito Fujihara ,  Masahiro Kouno ,  Kazuya Edamura

发明人： Masahito Fujihara ,  Masahiro Kouno ,  Kazuya Edamura

IPC分类号： H05K1/09 ,  B32B9/00 ,  B32B15/00 ,  H01B5/14 ,  H01Q1/00 ,  H05K3/10 ,  H05K3/12

CPC分类号： H05K3/1283 ,  B82Y30/00 ,  H05K3/102 ,  H05K3/107 ,  H05K3/1208 ,  H05K2201/0116 ,  H05K2201/0376 ,  H05K2203/0557 ,  H05K2203/082 ,  Y10T428/25 ,  Y10T428/30

摘要： The present invention provides a conductive material having superior bending property and superior bending resistant property and a method for manufacturing the same. This object is achieved by a conductive material comprising a substrate and a conductive portion formed within the substrate, wherein a change ratio in the electric resistance values before and after a bending resistant property test, in which the conductive portion is bent by 180 degrees and a load of 1 kg/cm2 is imposed on the bent portion for one hour, is set within a range of ±10%.

摘要翻译： 本发明提供具有优异的弯曲性和优异的抗弯曲性的导电材料及其制造方法。 该目的通过包括基板和形成在基板内的导电部分的导电材料来实现，其中导电部分弯曲180度的抗弯曲性试验之前和之后的电阻值的变化率和 在弯曲部分施加1kg / cm 2的负荷1小时，设定在±10％的范围内。