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11.发明申请WATER-SOLUBLE NAPHTHALOCYANINE COLORING MATTER AND WATER- BASED INK CONTAINING THE SAME 有权水溶性萘二甲酰亚胺颜料和含有水的墨水公开(公告)号：US20100236448A1
公开(公告)日：2010-09-23
申请号：US12734038
申请日：2008-10-30
IPC分类号： C09D11/02 , C09B47/04 , C07D487/22
CPC分类号： C09D11/328 , B41M3/14 , C09B47/16
摘要： The present invention relates to an aqueous solution composition (water-based ink composition) containing a water-soluble naphthalocyanine coloring matter represented by the following formula (1): (wherein, M represents a hydrogen atom, a metal atom, a metal oxide, a metal hydroxide or a metal halide, X represents a carbonyl group or a sulfonyl group, W1 to W4 are each independently a hydrogen atom, an ionic hydrophilic group or the like, at least one of W1 to W4 is a group other than a hydrogen atom, and n represents an integer number of 1 to 24, respectively) or a salt thereof, and a novel naphthalocyanine coloring matter; and said compound is useful as a near-infrared ray absorbent because it has a high absorption in the near-infrared region, and it is useful as an near-infrared ray absorbing water-based ink because it has an excellent storage stability in aqueous solution.
摘要翻译： 本发明涉及含有下式（1）表示的水溶性萘酞菁色素的水溶液组合物（水性油墨组合物）：（其中，M表示氢原子，金属原子，金属氧化物， 金属氢氧化物或金属卤化物，X表示羰基或磺酰基，W1至W4各自独立地为氢原子，离子性亲水基等，W1至W4中的至少一个为氢以外的基团 原子，n分别为1〜24的整数）或其盐，和新的萘酞菁色素; 并且所述化合物由于在近红外区域具有高吸收性而可用作近红外线吸收剂，并且作为近红外线吸收水性油墨是有用的，因为它在水溶液中具有优异的储存稳定性 。
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12.发明申请公开(公告)号：US20100126377A1
公开(公告)日：2010-05-27
申请号：US12452102
申请日：2008-07-03
CPC分类号： C07D487/22 , C09B47/16 , C09D11/328
摘要： The present invention relates to an ink composition containing a phthalocyanine coloring matter represented by the following formula (1): (wherein, each of the rings A to D independently represents a benzene ring or a pyridine ring, M represents a metal atom or the like, X represents a carbonyl group or the like, Y represents a hydrogen atom; a nitro group; a hydroxy group; a sulfo group; a carboxy group; an amino group; an alkoxy group, an alkylthio group, an alkylsulfonyl group which may be substituted; an aryloxy group, an arylthio group, an arylsulfonyl group, a heteroaryloxy group, a heteroarylthio group, a heteroarylsulfonyl group or an amino group, which may be substituted; or the like, and L is from 2 to 8) or a salt thereof; and said ink composition gives, in inkjet printing on plain paper, printed matters exhibiting an extremely excellent water fastness.
摘要翻译： 本发明涉及含有下述式（1）表示的酞菁色素的油墨组合物：（其中，各环A〜D各自独立地表示苯环或吡啶环，M表示金属原子等 X表示羰基等，Y表示氢原子，硝基，羟基，磺基，羧基，氨基，烷氧基，烷硫基，烷基磺酰基，可以是 取代的芳氧基，芳氧基，芳硫基，芳基磺酰基，杂芳氧基，杂芳基硫基，杂芳基磺酰基或氨基，可以被取代;等等，L为2至8）或盐 的; 并且所述油墨组合物在普通纸上的喷墨印刷中得到表现出非常优异耐水性的印刷品。
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13.发明授权Porphyrazine coloring matter, ink composition, recording method, and colored object 有权紫菜色素，油墨组成，记录方法和彩色物品公开(公告)号：US08657433B2
公开(公告)日：2014-02-25
申请号：US13377262
申请日：2010-06-08
申请人： Kenji Ooshima , Takashi Yoneda , Yasuo Kuroda , Akira Kawaguchi
发明人： Kenji Ooshima , Takashi Yoneda , Yasuo Kuroda , Akira Kawaguchi
IPC分类号： B41J2/01
CPC分类号： C09B67/0084 , C09B47/26 , C09D11/328
摘要： Provided is a porphyrazine dye suitable for use in ink-jet recording, the porphyrazine dye giving a cyan ink with a satisfactory hue, having various excellent fastness properties, in particular, ozone resistance, and attaining a high color density. Also provided is an ink composition containing the dye. The porphyrazine dye is a porphyrazine dye represented by formula (1) or a salt thereof. In formula (1), rings A to D each independently represents a benzene ring, a nitrogenous heteroaromatic ring, etc.; E represents an alkylene; X represents sulfoanilino, etc.; R represents a hydrogen atom, sulfo, carboxy, etc.; group F represents phenyl, a nitrogenous heteroaromatic ring, etc.; a is an integer of 1-6; b is 0.00-3.90, excluding 3.90, on average; c is 0.10-4.00, excluding 4.00, on average; and the sum of b and c is 1.00-4.00, excluding 4.00, on average.
摘要翻译： 本发明提供一种适用于喷墨记录的四氮杂卟啉染料，该四氮杂卟啉染料具有令人满意的色调，具有各种优异的牢度特性，特别是耐臭氧性，并获得高色密度的青色墨。 还提供含有该染料的油墨组合物。 四氮杂卟啉染料是由式（1）表示的四氮杂卟啉染料或其盐。 在式（1）中，环A至D各自独立地表示苯环，含氮杂芳环等; E表示亚烷基; X代表磺基苯胺基等。 R代表氢原子，磺基，羧基等; F组表示苯基，含氮杂芳环等; a为1-6的整数; b为0.00-3.90，平均不包括3.90; c为0.10-4.00，平均不包括4.00; b和c的总和平均为1.00-4.00，不包括4.00。
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公开(公告)号：US20110090278A1
公开(公告)日：2011-04-21
申请号：US12999436
申请日：2009-06-26
申请人： Takashi Yoneda , Yasuo Kuroda , Akira Kawaguchi
发明人： Takashi Yoneda , Yasuo Kuroda , Akira Kawaguchi
CPC分类号： C09B47/065 , C09B47/0678 , C09D11/328 , Y10T428/13 , Y10T428/24802
摘要： The present invention relates to a porphyrazine coloring matter represented by the following formula (1) or a salt thereof (wherein, the rings A to D are each independently a benzene ring or a 6-membered ring nitrogen-containing heteroaromatic ring, the number of said heteroaromatic rings is more than 0 and less than 1, E is alkylene, X is an anilino group or the like having at least one sulfo group or the like as a substituent, Y is a substituted monoalkylamino group or the like, b is 0 to 3, c is 0.1 to 3, and the sum of b and c is more than 3 and less than 4). By the present invention, a copper porphyrazine coloring matter suitable for inkjet recording which has a good hue as an cyan ink, is excellent in light fastness, ozone fastness and moisture fastness and does not cause bronze phenomenon can be provided.
摘要翻译： 本发明涉及由下式（1）表示的四氮杂卟啉色素或其盐（其中环A至D各自独立地为苯环或6-元环含氮杂芳环，其数目为 所述杂芳环大于0且小于1，E为亚烷基，X为具有至少一个磺基等作为取代基的苯胺基等，Y为取代的单烷基氨基等，b为0 至3，c为0.1至3，b和c之和大于3且小于4）。 通过本发明，可以提供适用于具有良好色调的青色墨水的喷墨记录用铜四氮杂卟啉色素，耐光性，耐臭氧性和耐湿牢度优异，并且不会引起青铜现象。
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公开(公告)号：US08394186B2
公开(公告)日：2013-03-12
申请号：US12999436
申请日：2009-06-26
申请人： Takashi Yoneda , Yasuo Kuroda , Akira Kawaguchi
发明人： Takashi Yoneda , Yasuo Kuroda , Akira Kawaguchi
CPC分类号： C09B47/065 , C09B47/0678 , C09D11/328 , Y10T428/13 , Y10T428/24802
摘要： The present invention relates to a porphyrazine coloring matter represented by the following formula (1) or a salt thereof (wherein, the rings A to D are each independently a benzene ring or a 6-membered ring nitrogen-containing heteroaromatic ring, the number of said heteroaromatic rings is more than 0 and less than 1, E is alkylene, X is an anilino group or the like having at least one sulfo group or the like as a substituent, Y is a substituted monoalkylamino group or the like, b is 0 to 3, c is 0.1 to 3, and the sum of b and c is more than 3 and less than 4). By the present invention, a copper porphyrazine coloring matter suitable for inkjet recording which has a good hue as an cyan ink, is excellent in light fastness, ozone fastness and moisture fastness and does not cause bronze phenomenon can be provided.
摘要翻译： 本发明涉及由下式（1）表示的四氮杂卟啉色素或其盐（其中环A至D各自独立地为苯环或6-元环含氮杂芳环，其数目为 所述杂芳环大于0且小于1，E为亚烷基，X为具有至少一个磺基等作为取代基的苯胺基等，Y为取代的单烷基氨基等，b为0 至3，c为0.1至3，b和c之和大于3且小于4）。 通过本发明，可以提供适用于具有良好色调的青色墨水的喷墨记录用铜四氮杂卟啉色素，耐光性，耐臭氧性和耐湿牢度优异，并且不会引起青铜现象。
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16.发明申请PORPHYRAZINE COLORING MATTER, INK COMPOSITION, RECORDING METHOD, AND COLORED OBJECT 有权磷杂环颜料，墨水组合物，记录方法和色彩对象公开(公告)号：US20120081457A1
公开(公告)日：2012-04-05
申请号：US13377262
申请日：2010-06-08
申请人： Kenji Ooshima , Takashi Yoneda , Yasuo Kuroda , Akira Kawaguchi
发明人： Kenji Ooshima , Takashi Yoneda , Yasuo Kuroda , Akira Kawaguchi
CPC分类号： C09B67/0084 , C09B47/26 , C09D11/328
摘要： Provided is a porphyrazine dye suitable for use in ink-jet recording, the porphyrazine dye giving a cyan ink with a satisfactory hue, having various excellent fastness properties, in particular, ozone resistance, and attaining a high color density. Also provided is an ink composition containing the dye. The porphyrazine dye is a porphyrazine dye represented by formula (1) or a salt thereof. In formula (1), rings A to D each independently represents a benzene ring, a nitrogenous heteroaromatic ring, etc.; E represents an alkylene; X represents sulfoanilino, etc.; R represents a hydrogen atom, sulfo, carboxy, etc.; group F represents phenyl, a nitrogenous heteroaromatic ring, etc.; a is an integer of 1-6; b is 0.00-3.90, excluding 3.90, on average; c is 0.10-4.00, excluding 4.00, on average; and the sum of b and c is 1.00-4.00, excluding 4.00, on average.
摘要翻译： 本发明提供一种适用于喷墨记录的四氮杂卟啉染料，该四氮杂卟啉染料具有令人满意的色调，具有各种优异的牢度特性，特别是耐臭氧性，并获得高色密度的青色墨。 还提供含有该染料的油墨组合物。 四氮杂卟啉染料是由式（1）表示的四氮杂卟啉染料或其盐。 在式（1）中，环A至D各自独立地表示苯环，含氮杂芳环等; E表示亚烷基; X代表磺基苯胺基等。 R代表氢原子，磺基，羧基等; F组表示苯基，含氮杂芳环等; a为1-6的整数; b为0.00-3.90，平均不包括3.90; c为0.10-4.00，平均不包括4.00; b和c的总和平均为1.00-4.00，不包括4.00。
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公开(公告)号：US08927219B2
公开(公告)日：2015-01-06
申请号：US12744064
申请日：2008-11-25
IPC分类号： G01N33/53 , G01N33/74 , G01N33/558 , G01N33/94
CPC分类号： G01N33/54366 , G01N33/558 , G01N33/9493
摘要： A method for evaluating the quality of a blood sample, comprising the steps of: mixing labeled anti-cortisol antibodies with a blood sample to be subjected, to conduct the antigen-antibody reaction of the labeled anti-cortisol antibody with cortisol contained in the blood sample, developing a mixture obtained in the above step on an immunochromatographic test strip having a substrate on which cortisol is immobilized to cause the antigen-antibody reaction of the labeled anti-cortisol antibodies which are free in the mixture with the cortisol immobilized on the substrate, thereby bonding the antibody to the cortisol, determining the amount of the labeled anti-cortisol antibodies bonded to the cortisol in the above step, and evaluating whether or not the blood sample has a quality suitable for suprarenal vein sampling test on the basis of the amount of the labeled anti-cortisol antibodies determined in the above step.
摘要翻译： 一种用于评估血液样品质量的方法，包括以下步骤：将标记的抗皮质醇抗体与待进行血液样品混合，进行标记的抗皮质醇抗体与血液中含有的皮质醇的抗原 - 抗体反应 样品，将在上述步骤中获得的混合物在具有固定有皮质醇的底物的免疫色谱试纸上培养，引起与固定在底物上的皮质醇混合物中游离的标记抗皮质醇抗体的抗原 - 抗体反应 从而将抗体结合到皮质醇上，确定在上述步骤中与皮质醇结合的标记的抗皮质醇抗体的量，并且基于上述步骤评估血液样品是否具有适合于肾上静脉取样试验的质量 在上述步骤中测定的标记的抗皮质醇抗体的量。
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公开(公告)号：US20120202019A1
公开(公告)日：2012-08-09
申请号：US13498431
申请日：2010-09-21
申请人： Takahiko Matsui , Takashi Yoshimoto , Hiroaki Ohno , Koji Hirota , Takashi Yoneda , Akira Kawaguchi
发明人： Takahiko Matsui , Takashi Yoshimoto , Hiroaki Ohno , Koji Hirota , Takashi Yoneda , Akira Kawaguchi
CPC分类号： C09B43/16 , C09D11/328 , Y10T428/24802
摘要： Azo compounds represented by general formula (1) or salts thereof are provided as highly water-soluble colorants which have hues of yellow, orange, brown or red, and excellent color development properties and which, when used in various recording processes, particularly in an inkjet recording process, ensure various excellent fastnesses such as light fastness, ozone fastness, and fading balance. Ink compositions containing the colorants are also provided. In general formula (1), R1 to R8 are each independently a hydrogen atom, C1-4 alkyl, C1-4 alkoxy, or the like; and X is C1-8 alkylenediamino, xylylenediamino, or the like.
摘要翻译： 提供由通式（1）表示的偶氮化合物或其盐作为具有黄色，橙色，棕色或红色色调的高度水溶性着色剂，并具有优异的显色性，并且当用于各种记录方法时，特别是在 喷墨记录工艺，确保耐光性，耐臭氧性和褪色平衡等各种优异的牢度。 还提供含有着色剂的油墨组合物。 在通式（1）中，R 1至R 8各自独立地为氢原子，C 1-4烷基，C 1-4烷氧基等; X是C 1-8亚烷基二氨基，亚二甲苯基二氨基等。
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19.发明申请PROCESSING SIMULATION METHOD AND APPARATUS, AND PROGRAM MAKING COMPUTER EXECUTE THE METHOD 审中-公开处理模拟方法和装置，程序计算机执行方法公开(公告)号：US20120016507A1
公开(公告)日：2012-01-19
申请号：US13259004
申请日：2009-05-20
IPC分类号： G05B13/04
CPC分类号： G05B19/4069 , G05B2219/49157
摘要： A processing simulation method and apparatus is provided, which can appropriately detect interference between a tool processing area and a shape model of a material without being affected by the accuracy of expression of a tool movement path and the shape model. A tool shape model for processing a material, that includes a strict tool shape, and a tool shape model for checking interference, that is included in the strict tool shape, are generated by tool model setting unit according to an error range set in consideration of the tool movement path and the expression accuracy of the shape model, and the processed material shape model is generated by generating a tool processing area shape model from the tool movement path during processing feed and the tool shape model for processing the material and removing the tool processing area shape model from the material shape model. The tool processing area shape model is generated from a tool movement path during fast feed and the tool shape model for detecting the interference, and the interference between the tool processing area shape model and the material shape model is detected.
摘要翻译： 提供一种处理模拟方法和装置，其可以适当地检测工具处理区域和材料的形状模型之间的干扰，而不受工具移动路径和形状模型的表达精度的影响。 由工具模型设定单元根据考虑到的设定的误差范围，生成包含在严格的工具形状中的用于处理材料的工具形状模型（包括严格的工具形状）和用于检查干涉的工具形状模型 通过在处理进给期间从工具移动路径生成工具处理区域形状模型和用于处理材料并移除工具的工具形状模型来生成工具移动路径和形状模型的表达精度以及加工材料形状模型 加工区域形状模型从材料形状模型。 刀具加工区域形状模型由快速进给期间的刀具运动路径和用于检测干涉的刀具形状模型产生，并且检测刀具加工区域形状模型与材料形状模型之间的干涉。
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20.发明申请公开(公告)号：US20120013678A1
公开(公告)日：2012-01-19
申请号：US13258124
申请日：2010-04-14
CPC分类号： C09B47/26 , B41M5/5218 , C09B47/064 , C09D11/328
摘要： The present invention relates to a porphyrazine coloring matter or a salt thereof represented by the following formula (1) [wherein, the rings of A to D are each independently a benzene ring or a 6-membered nitrogen-containing heteroaromatic ring, E is alkylene, X is a sulfo-substituted anilino group or the like which may further have a substituent, R1 is a C1-C6 alkyl group, b is 0.00 or more and less than 3.90 as an average value, c is 0.10 or more and less than 4.00 as an average value, and the sum of b and c is 1.00 or more and less than 4.00 as an average value]. The ink composition containing the porphyrazine coloring matter of the present invention has a good hue as a cyan ink, is excellent in various fastness properties, particularly in ozone fastness, allows a high print density, has properties hardly causing bronze phenomenon, and can provide a porphyrazine coloring matter suitable for inkjet recording and an ink composition containing this.
摘要翻译： 本发明涉及由下式（1）表示的四氮杂卟啉色素或其盐[其中，A至D的环各自独立地为苯环或6元含氮杂芳环，E为亚烷基 X为可以进一步具有取代基的磺基取代的苯胺基等，R 1为C 1〜C 6烷基，b为0.00以上且小于3.90，作为平均值，c为0.10以上且小于 4.00作为平均值，b和c之和为1.00以上且小于4.00作为平均值]。 含有本发明的四氮杂卟啉色素的油墨组合物作为青色油墨具有良好的色相，具有优异的各种牢度性能，特别是耐臭氧性，允许高印刷密度，具有几乎不引起青铜现象的性质，并且可以提供 适用于喷墨记录的四氮杂卟啉色素和含有它的油墨组合物。
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