公开(公告)号：US08657433B2

公开(公告)日：2014-02-25

申请号：US13377262

申请日：2010-06-08

申请人： Kenji Ooshima ,  Takashi Yoneda ,  Yasuo Kuroda ,  Akira Kawaguchi

发明人： Kenji Ooshima ,  Takashi Yoneda ,  Yasuo Kuroda ,  Akira Kawaguchi

IPC分类号： B41J2/01

CPC分类号： C09B67/0084 ,  C09B47/26 ,  C09D11/328

摘要： Provided is a porphyrazine dye suitable for use in ink-jet recording, the porphyrazine dye giving a cyan ink with a satisfactory hue, having various excellent fastness properties, in particular, ozone resistance, and attaining a high color density. Also provided is an ink composition containing the dye. The porphyrazine dye is a porphyrazine dye represented by formula (1) or a salt thereof. In formula (1), rings A to D each independently represents a benzene ring, a nitrogenous heteroaromatic ring, etc.; E represents an alkylene; X represents sulfoanilino, etc.; R represents a hydrogen atom, sulfo, carboxy, etc.; group F represents phenyl, a nitrogenous heteroaromatic ring, etc.; a is an integer of 1-6; b is 0.00-3.90, excluding 3.90, on average; c is 0.10-4.00, excluding 4.00, on average; and the sum of b and c is 1.00-4.00, excluding 4.00, on average.

摘要翻译： 本发明提供一种适用于喷墨记录的四氮杂卟啉染料，该四氮杂卟啉染料具有令人满意的色调，具有各种优异的牢度特性，特别是耐臭氧性，并获得高色密度的青色墨。 还提供含有该染料的油墨组合物。 四氮杂卟啉染料是由式（1）表示的四氮杂卟啉染料或其盐。 在式（1）中，环A至D各自独立地表示苯环，含氮杂芳环等; E表示亚烷基; X代表磺基苯胺基等。 R代表氢原子，磺基，羧基等; F组表示苯基，含氮杂芳环等; a为1-6的整数; b为0.00-3.90，平均不包括3.90; c为0.10-4.00，平均不包括4.00; b和c的总和平均为1.00-4.00，不包括4.00。

公开(公告)号：US20110090278A1

公开(公告)日：2011-04-21

申请号：US12999436

申请日：2009-06-26

申请人： Takashi Yoneda ,  Yasuo Kuroda ,  Akira Kawaguchi

发明人： Takashi Yoneda ,  Yasuo Kuroda ,  Akira Kawaguchi

IPC分类号： B41J2/015 ,  C09B47/00 ,  C09B47/20 ,  C09D11/02 ,  B32B1/02 ,  B32B3/10 ,  B41J2/175

CPC分类号： C09B47/065 ,  C09B47/0678 ,  C09D11/328 ,  Y10T428/13 ,  Y10T428/24802

摘要： The present invention relates to a porphyrazine coloring matter represented by the following formula (1) or a salt thereof (wherein, the rings A to D are each independently a benzene ring or a 6-membered ring nitrogen-containing heteroaromatic ring, the number of said heteroaromatic rings is more than 0 and less than 1, E is alkylene, X is an anilino group or the like having at least one sulfo group or the like as a substituent, Y is a substituted monoalkylamino group or the like, b is 0 to 3, c is 0.1 to 3, and the sum of b and c is more than 3 and less than 4). By the present invention, a copper porphyrazine coloring matter suitable for inkjet recording which has a good hue as an cyan ink, is excellent in light fastness, ozone fastness and moisture fastness and does not cause bronze phenomenon can be provided.

摘要翻译： 本发明涉及由下式（1）表示的四氮杂卟啉色素或其盐（其中环A至D各自独立地为苯环或6-元环含氮杂芳环，其数目为 所述杂芳环大于0且小于1，E为亚烷基，X为具有至少一个磺基等作为取代基的苯胺基等，Y为取代的单烷基氨基等，b为0 至3，c为0.1至3，b和c之和大于3且小于4）。 通过本发明，可以提供适用于具有良好色调的青色墨水的喷墨记录用铜四氮杂卟啉色素，耐光性，耐臭氧性和耐湿牢度优异，并且不会引起青铜现象。

公开(公告)号：US08394186B2

公开(公告)日：2013-03-12

申请号：US12999436

申请日：2009-06-26

申请人： Takashi Yoneda ,  Yasuo Kuroda ,  Akira Kawaguchi

发明人： Takashi Yoneda ,  Yasuo Kuroda ,  Akira Kawaguchi

IPC分类号： C09D11/02 ,  C09B47/00

CPC分类号： C09B47/065 ,  C09B47/0678 ,  C09D11/328 ,  Y10T428/13 ,  Y10T428/24802

摘要： The present invention relates to a porphyrazine coloring matter represented by the following formula (1) or a salt thereof (wherein, the rings A to D are each independently a benzene ring or a 6-membered ring nitrogen-containing heteroaromatic ring, the number of said heteroaromatic rings is more than 0 and less than 1, E is alkylene, X is an anilino group or the like having at least one sulfo group or the like as a substituent, Y is a substituted monoalkylamino group or the like, b is 0 to 3, c is 0.1 to 3, and the sum of b and c is more than 3 and less than 4). By the present invention, a copper porphyrazine coloring matter suitable for inkjet recording which has a good hue as an cyan ink, is excellent in light fastness, ozone fastness and moisture fastness and does not cause bronze phenomenon can be provided.

摘要翻译： 本发明涉及由下式（1）表示的四氮杂卟啉色素或其盐（其中环A至D各自独立地为苯环或6-元环含氮杂芳环，其数目为 所述杂芳环大于0且小于1，E为亚烷基，X为具有至少一个磺基等作为取代基的苯胺基等，Y为取代的单烷基氨基等，b为0 至3，c为0.1至3，b和c之和大于3且小于4）。 通过本发明，可以提供适用于具有良好色调的青色墨水的喷墨记录用铜四氮杂卟啉色素，耐光性，耐臭氧性和耐湿牢度优异，并且不会引起青铜现象。

公开(公告)号：US20120081457A1

公开(公告)日：2012-04-05

申请号：US13377262

申请日：2010-06-08

申请人： Kenji Ooshima ,  Takashi Yoneda ,  Yasuo Kuroda ,  Akira Kawaguchi

发明人： Kenji Ooshima ,  Takashi Yoneda ,  Yasuo Kuroda ,  Akira Kawaguchi

IPC分类号： B41J2/175 ,  C09B47/00 ,  C09D11/02

CPC分类号： C09B67/0084 ,  C09B47/26 ,  C09D11/328

摘要： Provided is a porphyrazine dye suitable for use in ink-jet recording, the porphyrazine dye giving a cyan ink with a satisfactory hue, having various excellent fastness properties, in particular, ozone resistance, and attaining a high color density. Also provided is an ink composition containing the dye. The porphyrazine dye is a porphyrazine dye represented by formula (1) or a salt thereof. In formula (1), rings A to D each independently represents a benzene ring, a nitrogenous heteroaromatic ring, etc.; E represents an alkylene; X represents sulfoanilino, etc.; R represents a hydrogen atom, sulfo, carboxy, etc.; group F represents phenyl, a nitrogenous heteroaromatic ring, etc.; a is an integer of 1-6; b is 0.00-3.90, excluding 3.90, on average; c is 0.10-4.00, excluding 4.00, on average; and the sum of b and c is 1.00-4.00, excluding 4.00, on average.

摘要翻译： 本发明提供一种适用于喷墨记录的四氮杂卟啉染料，该四氮杂卟啉染料具有令人满意的色调，具有各种优异的牢度特性，特别是耐臭氧性，并获得高色密度的青色墨。 还提供含有该染料的油墨组合物。 四氮杂卟啉染料是由式（1）表示的四氮杂卟啉染料或其盐。 在式（1）中，环A至D各自独立地表示苯环，含氮杂芳环等; E表示亚烷基; X代表磺基苯胺基等。 R代表氢原子，磺基，羧基等; F组表示苯基，含氮杂芳环等; a为1-6的整数; b为0.00-3.90，平均不包括3.90; c为0.10-4.00，平均不包括4.00; b和c的总和平均为1.00-4.00，不包括4.00。

公开(公告)号：US07854797B2

公开(公告)日：2010-12-21

申请号：US12450127

申请日：2008-03-13

申请人： Takafumi Fujii ,  Takashi Yoneda ,  Yasuo Kuroda ,  Yoshiaki Kawaida

发明人： Takafumi Fujii ,  Takashi Yoneda ,  Yasuo Kuroda ,  Yoshiaki Kawaida

IPC分类号： C09D11/02 ,  C07D487/22 ,  B41J2/01

CPC分类号： C09D11/328 ,  B41M5/0023 ,  C07D487/22 ,  C09B47/26 ,  C09D11/32

摘要： The present invention relates to a porphyrazine coloring matter represented by the following formula (1) or a salt thereof; wherein, each of the rings A to D independently represents a benzene ring or a 6-membered nitrogen-containing heteroaromatic ring, at least one or more thereof is a benzene ring, at least one of the rest is a nitrogen-containing heteroaromatic ring, E represents alkylene, X is an anilino group having a substituent and the like, Y represents an amino group; a hydroxy group; a mono- or di-alkylamino group or a nitrogen-containing heterocyclic group which may have a substituent, excepting for the combination in which Y is an amino group or a hydroxy group and X is a substituted anilino group, b is 0 to 2.9, c is 0.1 to 3, and the sum of b and c is 1 to 3. According to the present invention, a porphyrazine coloring matter suitable for inkjet recording which has a good hue as a cyan ink, is excellent in light fastness, ozone fastness and moisture fastness, and causes no bronze phenomenon can be provided.

摘要翻译： 本发明涉及由下式（1）表示的四氮杂卟啉色素或其盐; 其中，环A至D各自独立地表示苯环或6元含氮杂芳环，其中至少一个为苯环，其余至少一个为含氮杂芳环， E表示亚烷基，X表示具有取代基的苯胺基等，Y表示氨基。 羟基; 除了Y为氨基或羟基，X为取代苯胺基的组合外，b为0〜2.9，可以具有取代基的单 - 或二 - 烷基氨基或含氮杂环基， c为0.1〜3，b和c之和为1〜3。根据本发明，适用于具有良好色调的青色墨水的喷墨记录用四氮杂卟啉色素具有优异的耐光性，耐臭氧性 并具有耐湿牢度，并且不会产生青铜现象。

公开(公告)号：US20100112218A1

公开(公告)日：2010-05-06

申请号：US12450127

申请日：2008-03-13

申请人： Takafumi Fujii ,  Takashi Yoneda ,  Yasuo Kuroda ,  Yoshiaki Kawaida

发明人： Takafumi Fujii ,  Takashi Yoneda ,  Yasuo Kuroda ,  Yoshiaki Kawaida

IPC分类号： C09B67/50 ,  B05D5/00 ,  C09D11/02 ,  C09B47/04

CPC分类号： C09D11/328 ,  B41M5/0023 ,  C07D487/22 ,  C09B47/26 ,  C09D11/32

摘要： The present invention relates to a porphyrazine coloring matter represented by the following formula (1) or a salt thereof; (wherein, each of the rings A to D independently represents a benzene ring or a 6-membered nitrogen-containing heteroaromatic ring, at least one or more thereof is a benzene ring, at least one of the rest is a nitrogen-containing heteroaromatic ring, E represents alkylene, X is an anilino group having a substituent and the like, Y represents an amino group; a hydroxy group; a mono- or di-alkylamino group or a nitrogen-containing heterocyclic group which may have a substituent, excepting for the combination in which Y is an amino group or a hydroxy group and X is a substituted anilino group, b is 0 to 2.9, c is 0.1 to 3, and the sum of b and c is 1 to 3). According to the present invention, a porphyrazine coloring matter suitable for inkjet recording which has a good hue as a cyan ink, is excellent in light fastness, ozone fastness and moisture fastness, and causes no bronze phenomenon can be provided.

摘要翻译： 本发明涉及由下式（1）表示的四氮杂卟啉色素或其盐; （其中，环A至D各自独立地表示苯环或6元含氮杂芳环，其中至少一个或多个为苯环，其余至少一个为含氮杂芳环 E表示亚烷基，X表示具有取代基的苯胺基等，Y表示氨基，羟基，可以具有取代基的单 - 或二 - 烷基氨基或含氮杂环基，除了 Y为氨基或羟基，X为取代苯胺基的组合，b为0〜2.9，c为0.1〜3，b与c的和为1〜3）。 根据本发明，适用于喷墨记录的四氮杂卟啉色素具有良好的色相作为青色油墨，耐光性，耐臭氧性和耐湿牢度优异，不会产生青铜现象。

公开(公告)号：US5068376A

公开(公告)日：1991-11-26

申请号：US464671

申请日：1990-01-10

申请人： Hiroyoshi Nowatari ,  Hiroshi Hayami ,  Yasuo Kuroda ,  Sumio Yoda ,  Katsutoshi Takahashi

发明人： Hiroyoshi Nowatari ,  Hiroshi Hayami ,  Yasuo Kuroda ,  Sumio Yoda ,  Katsutoshi Takahashi

IPC分类号： C07F15/00

CPC分类号： C07F15/0093

摘要： A diamine platinum (II) complex represented by the general formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each a hydrogen atom or a lower alkyl group; and two X's are each a halogen atom or jointly form a group represented by ##STR2## wherein R.sub.5 and R.sub.6 are each a hydrogen atom or a lower alkyl group of a group represented by ##STR3## wherein m is 1 or 2.

公开(公告)号：US4864043A

公开(公告)日：1989-09-05

申请号：US87045

申请日：1987-08-19

申请人： Hiroyoshi Nowatari ,  Hiroshi Hayami ,  Yasuo Kuroda ,  Sumio Yoda ,  Katsutoshi Takahashi

发明人： Hiroyoshi Nowatari ,  Hiroshi Hayami ,  Yasuo Kuroda ,  Sumio Yoda ,  Katsutoshi Takahashi

IPC分类号： C07F15/00

CPC分类号： C07F15/0093

摘要： A diamine platinum (II) complex represented by the general formula ##STR1## [wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each a hydrogen atom or a lower alkyl group; and two X's are each a halogen atom or jointly form a group represented by ##STR2## (wherein R.sub.5 and R.sub.6 are each a hydrogen atom or a lower alkyl group) or a group represented by ##STR3## (wherein m is 1 or 2)].

公开(公告)号：US3998867A

公开(公告)日：1976-12-21

申请号：US520165

申请日：1974-11-01

申请人： Shigeo Takenaka ,  Hitoshi Shimizu ,  Akira Iwamoto ,  Yasuo Kuroda

发明人： Shigeo Takenaka ,  Hitoshi Shimizu ,  Akira Iwamoto ,  Yasuo Kuroda

IPC分类号： B01J23/887 ,  C07C5/48 ,  C07C120/14 ,  C07C11/12

CPC分类号： C07C253/26 ,  B01J23/8876 ,  C07C5/48 ,  Y02P20/52

摘要： This invention relates to a process for simultaneously preparing methacrylonitrile and 1,3-butadiene from a mixture of butanes and butenes (hereinafter referred to as a mixed butane-butene) consisting of isobutane, n-butane, isobutylene, 1-butene, cis-2-butene and trans-2-butene, in excellent selectivity and single pass yield. More particularly, this invention relates to a process for the simultaneous preparation of methacrylonitrile and 1,3-butadiene which comprises subjecting the mixed butane-butene, at high temperatures and in vapor phase, to ammoxidation and oxidative dehydrogenation with a gas containing ammonia and either air or oxygen, using a catalyst of the general formula:CO.sub.a Fe.sub.b Bi.sub.c Mg.sub.d Q.sub.h Mo.sub.f O.sub.gwherein Co is cobalt, Fe is iron, Bi is bismuth, Mg is magnesium, Mo is molybdenum, Q is at least one element selected from the group consisting of potassium, rubidium and cesium, O is oxygen, and a, b, c, d, f, g, and h are the number of atoms of Co, Fe, Bi, Mg, Mo, O and Q respectively, with a being a value of from 1 to 15, b from 0.5 to 7, c from 0.1 to 4, d from 0 to 4, f being 12, g being a value of from 39 to 72 determined naturally from the valences of other metal atoms and h from 0.01 to 1.0.

公开(公告)号：US4921984A

公开(公告)日：1990-05-01

申请号：US372248

申请日：1989-06-27

申请人： Hiroyoshi Nowatari ,  Hiroshi Hayami ,  Yasuo Kuroda ,  Sumio Yoda ,  Katsutoshi Takahashi

发明人： Hiroyoshi Nowatari ,  Hiroshi Hayami ,  Yasuo Kuroda ,  Sumio Yoda ,  Katsutoshi Takahashi

IPC分类号： C07F15/00

CPC分类号： C07F15/0093

摘要： A diamine platinum (II) complex represented by the general formula ##STR1## [wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each a hydrogen atom or a lower alkyl group; and two X's are each a halogen atom or jointly form a group represented by ##STR2## (wherein R.sub.5 and R.sub.6 are each a hydrogen atom or a lower alkyl group) or a group represented by ##STR3## (wherein m is 1 or 2)].