摘要:
This invention relates to a welded line pipe structure for transporting corrosive petroleum or natural gas. It is constituted by martensitic stainless steel pipes containing 8-16% Cr and at most 0.05% C. By suitably controlling the welding conditions at the time of girth welding of the steel pipes so as to ensure that the Cr concentration in grain boundary Cr-depleted portions existing immediately beneath a weld oxide scale is at least 5%, the occurrence of SCC in a high temperature CO2 environment can be prevented.
摘要:
A martensitic stainless steel pipe comprises, on the weight basis, C: 0.005 to 0.2%, Si: 1% or below, Mn: 0.1 to 5%, Cr: 7 to 15%, and Ni: 0 to 8%, wherein a wall thickness t (mm) and contents of C and Cr satisfy the relationship represented by the following equation (1).t(mm).ltoreq.exp{5.21-18.1C(%)-0.0407Cr(%)} (1)The steel pipe can be made by employing water quenching as a quenching method.
摘要:
A process for producing a seamless steel pipe wherein pipe manufacturing steps and the heat treatment steps are carried out in one production line. The properties of the pipe are comparative or superior to those of the pipe manufactured in the conventional reheating, quenching and tempering process. The process is characterized by using the billet of a low alloy steel containing C: 0.15-0.50%, Cr: 0.1-1.5%, Mo: 0.1-1.5%, Al: 0.005-0.50%, Ti: 0.005-0.50% and Nb: 0.003-0.50%, and comprising the following steps (1) to (5).(1) hot rolling with 40% or more of cross sectional reduction ratio,(2) finishing the hot rolling in a temperature range of 800-1100.degree. C.,(3) putting the manufactured steel pipe promptly in a complementary heating apparatus after the finish rolling, and complementarily heating at the temperature and time satisfying the following formula (a).(4) quenching the steel pipe immediately after taking out of the complementary heating apparatus, and(5) tempering the pipe at a temperature not higher than the Ac.sub.1 transformation point as the last heat treatment.23500.ltoreq.(T+273).times.(21+log t).ltoreq.26000 (a)where, T (.degree.C.) is a temperature of not lower than 850.degree. C., and t is time (hr). Further, an intermediate heat treatment consisting of quenching or combination of quenching and tempering may be applied between the steps (4) and (5).
摘要:
A martensitic stainless steel having a resistance to sulfide stress corrosion cracking superior to Super 13 Cr steel and having a strength and corrosion resistance comparable to dual phase stainless steels has a chemical composition consisting essentially of, in mass %, C: 0.001-0.1%, Si: 0.05-1.0%, Mn: 0.05-2.0%, P: at most 0.025%, S: at most 0.010%, Cr: 11-18%, Ni: 1.5-10%, sol. Al: 0.001-0.1%, N: at most 0.1%, O: at most 0.01%, Cu: 0-5%, solid solution Mo: 3.5-7%, the composition satisfying the following Equation (1), optionally at least one element selected from at least one of the following Groups A-C, and a remainder of Fe and impurities and undissolved Mo, if undissolved Mo is present. Ni-bal.=30(C+N)+0.5(Mn+Cu)+Ni+8.2−1.1(Cr+Mo+1.5Si)≧−4.5 Equation (1) Group A—W: 0.2-5% Group B—V: 0.001-0.50%, Nb: 0.001-0.50%, Ti: 0.001-0.50%, and Zr: 0.001-0.50% Group C—Ca: 0.0005-0.05%, Mg: 0.0005-0.05%, REM: 0.0005-0.05%, and B: 0.0001-0.01%.
摘要翻译:具有优于超级13Cr钢的具有耐硫化应力腐蚀开裂性且具有与双相不锈钢相当的强度和耐腐蚀性的马氏体不锈钢的化学成分基本上以质量%计含有C:0.001-0.1% Si:0.05〜1.0%,Mn:0.05〜2.0%,P:0.025%以下,S:0.010%以下,Cr:11〜18%,Ni:1.5〜10% Al:0.001-0.1%,N:0.1%以下,O:0.01%以下,Cu:0-5%,固溶Mo:3.5〜7%,满足下述式(1)的组成, 选自以下组AC中的至少一个的元素,以及余量的Fe和杂质以及未溶解的Mo,如果不溶解的Mo存在。 Ni-bal = 30(C + N)+0.5(Mn + Cu)+ Ni + 8.2-1.1(Cr + Mo + 1.5Si)≥-4.5等式(1)组A-W:0.2-5% -V:0.001-0.50%,Nb:0.001-0.50%,Ti:0.001-0.50%,Zr:0.001-0.50%C-Ca:0.0005-0.05%,Mg:0.0005-0.05%,REM: 0.05%,B:0.0001-0.01%。
摘要:
This invention relates to a welded line pipe structure for transporting corrosive petroleum or natural gas. It is constituted by martensitic stainless steel pipes containing 8–16% Cr and at most 0.05% C. By suitably controlling the welding conditions at the time of girth welding of the steel pipes so as to ensure that the Cr concentration in grain boundary Cr-depleted portions existing immediately beneath a weld oxide scale is at least 5%, the occurrence of SCC in a high temperature CO2 environment can be prevented.
摘要:
A martensitic stainless steel comprising C: 0.01-0.10%, Si: 0.05-1.0%, Mn: 0.05-1.5%, P: not more than 0.03%, S: not more than 0.01%, Cr: 9-15%, Ni: 0.1-4.5%, Al: not more than 0.05% and N: not more than 0.1% in mass %, and further comprising at least one of Cu: 0.05-5% and Mo: 0.05-5%, the residual being Fe and impurities, is provided, wherein the contents of Cu and Mo satisfy the following formula (a) or (b), 0.2%≦Mo+Cu/4≦5% (a) 0.55%≦Mo+Cu/4≦5% (b) and wherein the hardness is 30-45 in HRC and the carbide amount in grain boundaries of the prior austenite is not more than 0.5 volume %. The marensitic stainless steel has excellent properties regarding the sulfide stress cracking resistance, the resistance to corrosive wear and the localized corrosion.
摘要翻译:一种马氏体不锈钢,其包含C:0.01〜0.10%,Si:0.05〜1.0%,Mn:0.05〜1.5%,P:0.03%以下,S:0.01%以下,Cr:9〜15%,Ni :0.1-4.5%,Al:0.05%以下,N:0.1质量%以下,进一步含有Cu:0.05〜5%和Mo:0.05〜5%中的至少一种,残留物为Fe 和杂质,其中Cu和Mo的含量满足下式(a)或(b),0.2%<= Mo + Cu / 4 <= 5%(a)0.55%<= Mo + Cu / 4 <= 5%(b),其中HRC中的硬度为30-45,并且原奥氏体的晶界中的碳化物量不大于0.5体积%。 锰矿不锈钢具有耐硫化物应力开裂性,耐腐蚀性和局部腐蚀性等优异性能。
摘要:
(1) A steel pipe that is expanded radially in a state wherein it was inserted in a well such as an oil well, characterized in that the non-uniform wall thickness ratio E0 (%) before expanding satisfies the following expression {circle around (1)}. E0≦30/(1+0.018α) {circle around (1)} Wherein α is the pipe expansion ratio (%) calculated by the following expression {circle around (2)}. α=[(inner diameter of the pipe after expanding−inner diameter of the pipe before expanding)/inner diameter of the pipe before expanding]×100 {circle around (2)} (2) A steel pipe that should be expanded radially in a state wherein it is inserted in a well, such as an oil well, characterized in that the eccentric non-uniform wall thickness ratio is 10% or less.When the embedding-expanding method is performed with use of the steel pipe of (1) or (2), lowering of collapse strength of the expanded steel pipe is prevented and bending thereof can be decreased.
摘要:
(1) A steel pipe that is expanded radially in a state wherein it was inserted in a well such as an oil well, characterized in that the non-uniform wall thickness ratio E0 (%) before expanding satisfies the following expression {circle around (1)}. E0≦30 /(1+0.018α) {circle around (1)}Wherein α is the pipe expansion ratio (%) calculated by the following expression {circle around (2)}. α=[(inner diameter of the pipe after expanding−inner diameter of the pipe before expanding)/inner diameter of the pipe before expanding]×100 {circle around (2)}(2) A steel pipe that should be expanded radially in a state wherein it is inserted in a well, such as an oil well, characterized in that the eccentric non-uniform wall thickness ratio is 10% or less. When the embedding-expanding method is performed with use of the steel pipe of (1) or (2), lowering of collapse strength of the expanded steel pipe is prevented and bending thereof can be decreased.
摘要:
(1) A steel pipe that is expanded radially in a state wherein it was inserted in a well such as an oil well, characterized in that the non-uniform wall thickness ratio E0 (%) before expanding satisfies the following expression {circle around (1)}. E0≦30/(1+0.018α){circle around (1)} Wherein α is the pipe expansion ratio (%) calculated by the following expression {circle around (2)}. α=[(inner diameter of the pipe after expanding−inner diameter of the pipe before expanding)/inner diameter of the pipe before expanding]×100{circle around (2)} (2) A steel pipe that should be expanded radially in a state wherein it is inserted in a well, such as an oil well, characterized in that the eccentric non-uniform wall thickness ratio is 10% or less.When the embedding-expanding method is performed with use of the steel pipe of (1) or (2), lowering of collapse strength of the expanded steel pipe is prevented and bending thereof can be decreased.
摘要:
A martensitic stainless steel oil country tubular good contains, by mass, 0.005% to 0.1% C, 0.05% to 1% Si, 1.5% to 5% Mn, at most 0.05% P, at most 0.01% S, 9% to 13% Cr, at most 0.5% Ni, at most 2% Mo, at most 2% Cu, 0.001% to 0.1% Al, and 0.001% to 0.1% N, with the balance being Fe and impurities, and the pipe has a Cr-depleted region under the surface. The martensitic stainless steel oil country tubular good according to the present invention does not have a passive film on the surface and corrodes wholly at low speed. In addition, the Ni content is reduced, which allows uneven corrosion to be prevented. Therefore, SCC can be prevented from being generated in spite of the presence of a Cr-depleted region.