公开(公告)号：US5227532A

公开(公告)日：1993-07-13

申请号：US850267

申请日：1992-03-12

申请人： Keiichi Sato ,  Masaki Takai ,  Yuji Kawaragi ,  Tooru Ookoshi

发明人： Keiichi Sato ,  Masaki Takai ,  Yuji Kawaragi ,  Tooru Ookoshi

IPC分类号： B01J31/24 ,  C07B61/00 ,  C07C45/50 ,  C07C47/02 ,  C07F9/145

CPC分类号： C07F9/145 ,  C07C45/50

摘要： A method for producing an aldehyde, which comprises reacting an olefinic compound with carbon monoxide and hydrogen in the presence of a Group VIII metal compound and an organic phosphite compound to produce a corresponding aldehyde, wherein an organic phosphite compound of the formula (I):P(OR.sub.1)(OR.sub.2)(OR.sub.3) (I)wherein each of R.sub.1 and R.sub.2 which may be the same or different, is a 2-naphthyl group which may have a substituent, provided that at least one of R.sub.1 and R.sub.2 is a substituted 2-naphthyl group of the formula (II): ##STR1## wherein R.sub.4 is a C.sub.1-30 organic group, and each of R.sub.5, R.sub.6, R.sub.7, R.sub.8 and R.sub.9 which may be the same or different, is a hydrogen atom or an organic group, and R.sub.3 is 1 a 2-naphthyl group which may have a substituent, 2 a phenyl group which may have a substituent, or 3 an alkyl group which may have a substituent, is used as said organic phosphite compound.

公开(公告)号：US20080076822A1

公开(公告)日：2008-03-27

申请号：US11898147

申请日：2007-09-10

申请人： Yuji Yoshinari ,  Masaki Takai ,  Yuki Okamoto ,  Tomomi Fujimura

发明人： Yuji Yoshinari ,  Masaki Takai ,  Yuki Okamoto ,  Tomomi Fujimura

IPC分类号： A01N37/00 ,  A01N25/02 ,  A01P1/00

CPC分类号： A01N37/06 ,  A01N37/02

摘要： The disinfectant capable of realizing effective sterilization by using a surfactant contains water, from which polyvalent cations are removed and to which a sodium ion is added, and a surfactant. An example of the surfactant is a fatty acid salt. When the disinfectant is applied to an object to be treated, fungi and bacteria adhering thereto are sterilized by the action of the surfactant. The surfactant contained in the disinfectant hardly remains on the object owing to the effect of the water from which polyvalent cations are removed and to which a sodium ion is added, and then is not likely to be a source of nutrient for fungi and bacteria. Accordingly, on the object to which the disinfectant is applied, fungi and bacteria are sterilized and propagation thereof is suppressed, and thus a hygienic state of the object is easily maintained. The disinfectant is particularly effective when it is used for, for example, bathrooms, tabs of washing machines, kitchens, toilets, washstands, drainpipes and daily commodities.

摘要翻译： 能够通过使用表面活性剂实现有效灭菌的消毒剂含有除去多价阳离子并加入钠离子的水和表面活性剂。 表面活性剂的实例是脂肪酸盐。 当将消毒剂施用于待处理物体时，附着于其上的真菌和细菌通过表面活性剂的作用而灭菌。 由于消除了多价阳离子的水的作用并且添加了钠离子，因此消毒剂中所含的表面活性剂几乎不残留在物体上，因此不可能是真菌和细菌的营养源。 因此，在使用消毒剂的物体上，真菌和细菌被灭菌并且抑制其传播，从而容易地保持物体的卫生状态。 当消毒剂用于例如浴室，洗衣机，厨房，卫生间，洗手盆，排水管和日常商品的标签时，消毒剂特别有效。

公开(公告)号：US07241857B2

公开(公告)日：2007-07-10

申请号：US11300290

申请日：2005-12-15

申请人： Masaki Takai ,  Yoshiyuki Tanaka

发明人： Masaki Takai ,  Yoshiyuki Tanaka

IPC分类号： C08G65/34 ,  C08F20/10

CPC分类号： C07C41/16 ,  C07C67/10 ,  Y02P20/582 ,  C07C69/78 ,  C07C43/215 ,  C07C43/15 ,  C07C43/1785 ,  C07C43/23

摘要： A method for producing an allyl compound having a compositional formula different from that of an allyl starting material compound, which comprises reacting the allyl starting material compound with an oxygen nucleophilic agent in the presence of a catalyst containing at least one transition metal compound containing a transition metal selected from the group consisting of transition metals belonging to Group 8 to Group 10 of the Periodic Table and a multidentate phosphite compound.

摘要翻译： 一种具有与烯丙基原料化合物不同的组成式的烯丙基化合物的制备方法，该方法包括在含有至少一种含有过渡金属化合物的过渡金属化合物的催化剂存在下，使烯丙基原料化合物与氧亲核剂反应 选自属于元素周期表第8族至第10族的过渡金属的金属和多元亚磷酸酯化合物。

公开(公告)号：US07119222B2

公开(公告)日：2006-10-10

申请号：US10648210

申请日：2003-08-27

申请人： Masaki Takai ,  Yoshiyuki Tanaka

发明人： Masaki Takai ,  Yoshiyuki Tanaka

IPC分类号： C07C69/533 ,  C07C41/06

CPC分类号： C07C41/16 ,  C07C67/10 ,  Y02P20/582 ,  C07C69/78 ,  C07C43/215 ,  C07C43/15 ,  C07C43/1785 ,  C07C43/23

摘要： A method for producing an allyl compound having a compositional formula different from that of an allyl starting material compound, which comprises reacting the allyl starting material compound with an oxygen nucleophilic agent in the presence of a catalyst containing at least one transition metal compound containing a transition metal selected from the group consisting of transition metals belonging to Group 8 to Group 10 of the Periodic Table and a multidentate phosphite compound.

摘要翻译： 一种具有与烯丙基原料化合物不同的组成式的烯丙基化合物的制备方法，该方法包括在含有至少一种含有过渡金属化合物的过渡金属化合物的催化剂存在下，使烯丙基原料化合物与氧亲核剂反应 选自属于元素周期表第8族至第10族的过渡金属的金属和多元亚磷酸酯化合物。

公开(公告)号：US20050075518A1

公开(公告)日：2005-04-07

申请号：US10650697

申请日：2003-08-29

申请人： Masaki Takai ,  Yoshiyuki Tanaka

发明人： Masaki Takai ,  Yoshiyuki Tanaka

IPC分类号： C07C41/16 ,  C07C67/10 ,  C07C209/66 ,  C07C211/35 ,  C08G63/52 ,  C08G63/87 ,  C07C41/06

CPC分类号： C08G63/52 ,  C07C41/16 ,  C07C67/10 ,  C07C209/66 ,  C07C2601/14 ,  C08G63/87 ,  C07C69/78 ,  C07C211/35 ,  C07C43/215 ,  C07C43/15

摘要： A method for producing an allyl compound having a compositional formula different from that of an allyl starting material compound, which comprises reacting the allyl starting material compound with a nucleophilic agent in the presence of a catalyst containing at least one transitional metal compound containing a transition metal selected from the group consisting of transition metals belonging to Group 8 to Group 10 of the Periodic Table and at least one bidentate coordinated phosphite compound selected from the group consisting of compounds having structures of the following formulae (I) to (III): wherein A1 to A3 are respectively independently a diarylene group having a branched alkyl group at the ortho-position, R1 to R6 are respectively independently an alkyl group which may have a substituent or an aryl group which may have a substituent (including a heterocyclic compound forming an aromatic 6π electron cloud on the upper and lower sides of the ring, hereinafter the same), and Z1 to Z3 are respectively independently an alkylene group which may have a substituent, an arylene group which may have a substituent, an alkylene-arylene group which may have a substituent or a diarylene group which may have a substituent.

摘要翻译： 一种具有与烯丙基原料化合物不同的组成式的烯丙基化合物的制备方法，该方法包括在含有至少一种含有过渡金属的过渡金属化合物的催化剂存在下使烯丙基原料化合物与亲核剂反应 选自属于元素周期表第8族至第10族的过渡金属和至少一种选自下式（I）至（III）的结构的化合物的二齿配位的亚磷酸酯化合物：其中A A 1〜A 3分别独立地为在邻位具有支链烷基的二亚芳基，R 1〜R 6分别独立地为可以具有取代基的烷基或芳基， 可以具有取代基（包括在环的上侧和下侧形成芳香族6pi电子云的杂环化合物，以下相同 ）和Z 1〜Z 3分别独立地为可以具有取代基的亚烷基，可以具有取代基的亚芳基，可以具有取代基的亚芳基 - 亚芳基或可具有取代基的二亚芳基 取代基。

公开(公告)号：US06583324B2

公开(公告)日：2003-06-24

申请号：US09954171

申请日：2001-09-18

申请人： Masaki Takai ,  Iwao Nakajima ,  Tooru Tsukahara ,  Yoshiyuki Tanaka ,  Hisao Urata ,  Akio Nakanishi

发明人： Masaki Takai ,  Iwao Nakajima ,  Tooru Tsukahara ,  Yoshiyuki Tanaka ,  Hisao Urata ,  Akio Nakanishi

IPC分类号： C07C4550

CPC分类号： C07F9/025 ,  B01J31/185 ,  B01J2231/321 ,  B01J2531/822 ,  C07C45/50 ,  Y02P20/584 ,  C07C47/02

摘要： A process for producing an aldehyde, which comprises a reaction step of producing an aldehyde by reacting an olefinic compound with carbon monoxide and hydrogen in the presence of a rhodium complex catalyst comprising at least rhodium and an organic phosphite in a reaction zone, a separation step of obtaining a catalyst solution containing the rhodium complex catalyst by separating the aldehyde from a reaction solution taken from the reaction zone, and a recycling step of recycling the catalyst solution into the reaction zone, wherein the aldehyde is separated from the reaction solution in such a manner as to make an aldehyde concentration from 0.5 to 99 wt % in the catalyst solution.

公开(公告)号：US5177228A

公开(公告)日：1993-01-05

申请号：US742481

申请日：1991-08-05

申请人： Keiichi Sato ,  Yuji Kawaragi ,  Masaki Takai

发明人： Keiichi Sato ,  Yuji Kawaragi ,  Masaki Takai

IPC分类号： C07C45/49 ,  C07C45/50 ,  C07C51/14 ,  C07C67/347 ,  C07C255/17

CPC分类号： C07C255/17 ,  C07C45/49 ,  C07C45/50 ,  C07C51/14 ,  C07C67/347

摘要： Hydroformylation process, wherein an olefinic compound is reacted with hydrogen and carbon dioxide in the presence of a Group VIII precious metal complex catalyst containing an organic phosphorus compound as a ligand, the process being characterized by use of trialkyl phosphine, as the organic phosphorus compound, having the total carbon atom number of 27 or more in its alkyl groups.

摘要翻译： 加氢甲酰化方法，其中烯烃化合物与氢和二氧化碳在含有有机磷化合物作为配体的VIII族贵金属配合物催化剂存在下反应，该方法的特征在于使用三烷基膦作为有机磷化合物， 其烷基中的总碳原子数为27以上。

公开(公告)号：US20080103203A1

公开(公告)日：2008-05-01

申请号：US11976565

申请日：2007-10-25

申请人： Yuji Yoshinari ,  Masaki Takai ,  Makoto Hatori ,  Yuki Okamoto

发明人： Yuji Yoshinari ,  Masaki Takai ,  Makoto Hatori ,  Yuki Okamoto

IPC分类号： A61K31/201 ,  A61K47/04 ,  A61K47/12 ,  A61P31/10

CPC分类号： A61K8/361 ,  A01N37/02 ,  A01N37/06 ,  A01N59/00 ,  A61K8/19 ,  A61Q17/005 ,  A61Q19/10 ,  A01N25/30 ,  A01N2300/00

摘要： The skin disinfectant, which is able to sterilize skin by the action of a surfactant without damaging skin health conditions, contains water, from which polyvalent cations are removed and to which a sodium ion is added, and a surfactant. The surfactant is, for example, a fatty acid salt. When the skin disinfectant is applied onto skin, fungi and bacteria adhered or parasitic onto skin is sterilized by the action of the surfactant. At this time, the surfactant is not likely to give an irritation to skin due to the action of the water, from which polyvalent cations are removed and to which a sodium ion is added, and thus the skin health conditions tend not to be damaged. Accordingly, the skin disinfectant is useful as a remedy for, for example, a ringworm infectious disease.

摘要翻译： 能够通过表面活性剂的作用对皮肤进行消毒而不损害皮肤健康状况的皮肤消毒剂含有除去多价阳离子并加入钠离子的水和表面活性剂的水。 表面活性剂是例如脂肪酸盐。 当将皮肤消毒剂施用到皮肤上时，通过表面活性剂的作用对附​​着或寄生在皮肤上的真菌和细菌进行灭菌。 此时，由于除去多价阳离子并添加了钠离子的水的作用，表面活性剂不易对皮肤产生刺激，因此皮肤健康状况往往不被损坏。 因此，皮肤消毒剂可用作例如癣感染性疾病的补救措施。

公开(公告)号：US20080103079A1

公开(公告)日：2008-05-01

申请号：US11976416

申请日：2007-10-24

申请人： Yuji Yoshinari ,  Masaki Takai ,  Makoto Hatori ,  Daisuke Yamamoto ,  Yuki Okamoto

发明人： Yuji Yoshinari ,  Masaki Takai ,  Makoto Hatori ,  Daisuke Yamamoto ,  Yuki Okamoto

IPC分类号： C11D17/00

CPC分类号： C11D3/046 ,  A61K8/19 ,  A61K8/361 ,  A61Q19/10

摘要： The cleaning agent, which is less likely to retain a surfactant on an object to be cleaned and not to restrict applicable objects to be cleaned, contains water from which polyvalent cations are removed and to which a sodium ion is added, and a surfactant. An example of the surfactant is a fatty acid salt. When the cleaning agent is applied to an object to be cleaned, stain adhered on the object is removed from the object by action of the surfactant. The surfactant hardly remains on the object due to the action of the water from which polyvalent cations are removed and to which a sodium ion is added. Accordingly, the cleaning agent can effectively wash a wide variety of objects, such as kitchens, tableware, food, washstands, bathrooms, toilets, vehicles, clothes and body skin, without damaging texture and deteriorating quality.

摘要翻译： 不易于将待清洁物体保持表面活性剂并且不限制可清洁物体的清洁剂含有除去多价阳离子并添加了钠离子的水和表面活性剂。 表面活性剂的实例是脂肪酸盐。 当将清洁剂施加到待清洁的物体上时，通过表面活性剂的作用将附着在物体上的污渍从物体上除去。 由于去除了多价阳离子的水的作用并且添加了钠离子，表面活性剂几乎不残留在物体上。 因此，清洁剂可以有效地洗涤诸如厨房，餐具，食品，洗手盆，浴室，卫生间，车辆，衣服和身体皮肤的各种物品，而不会损坏质地和劣化质量。

公开(公告)号：US20080058242A1

公开(公告)日：2008-03-06

申请号：US11892769

申请日：2007-08-27

申请人： Yuji Yoshinari ,  Masaki Takai ,  Makoto Hatori ,  Daisuke Yamamoto

发明人： Yuji Yoshinari ,  Masaki Takai ,  Makoto Hatori ,  Daisuke Yamamoto

IPC分类号： C11D17/08

CPC分类号： C11D7/10

摘要： The cleaning fluid, which is easily mass-produced, low priced, and safe and is also free from chemical substances contains water from which polyvalent cations are removed and to which sodium ions are added. When the cleaning fluid is applied to an object to be cleaned, stain adhered onto the object can be removed by action of the water. The object washed with the cleaning fluid is free from remnant of chemical substances, as is often not the case when washed with a cleaning fluid using chemical-substances such as a surfactant, and is therefore safe. Furthermore, since water stain or scale hardly remains on the object washed, new stain is not easily attached. Accordingly, the cleaning fluid is particularly effective when it is used as a cleaning fluid for kitchen sinks, tableware, foods, washstands, bathrooms, toilets, vehicles and clothes.

摘要翻译： 容易批量生产，低价格且安全且不含化学物质的清洗液含有从其中除去多价阳离子并加入钠离子的水。 当将清洁流体施加到待清洁物体上时，通过水的作用可以去除粘附到物体上的污渍。 用清洗液清洗的物体没有残留的化学物质，因为使用化学物质如表面活性剂用清洁液洗涤时通常不是这种情况，因此是安全的。 此外，由于洗涤物体上几乎不残留有水渍或鳞屑，所以新的污渍不容易附着。 因此，当清洗液被用作厨房水槽，餐具，食品，洗手盆，浴室，卫生间，车辆和衣物的清洁液时，清洁液特别有效。