公开(公告)号：US20060106181A1

公开(公告)日：2006-05-18

申请号：US11300290

申请日：2005-12-15

申请人： Masaki Takai ,  Yoshiyuki Tanaka

发明人： Masaki Takai ,  Yoshiyuki Tanaka

IPC分类号： C08F20/10 ,  C07C69/52

CPC分类号： C07C41/16 ,  C07C67/10 ,  Y02P20/582 ,  C07C69/78 ,  C07C43/215 ,  C07C43/15 ,  C07C43/1785 ,  C07C43/23

摘要： A method for producing an allyl compound having a compositional formula different from that of an allyl starting material compound, which comprises reacting the allyl starting material compound with an oxygen nucleophilic agent in the presence of a catalyst containing at least one transition metal compound containing a transition metal selected from the group consisting of transition metals belonging to Group 8 to Group 10 of the Periodic Table and a multidentate phosphite compound.

公开(公告)号：US07241857B2

公开(公告)日：2007-07-10

申请号：US11300290

申请日：2005-12-15

申请人： Masaki Takai ,  Yoshiyuki Tanaka

发明人： Masaki Takai ,  Yoshiyuki Tanaka

IPC分类号： C08G65/34 ,  C08F20/10

CPC分类号： C07C41/16 ,  C07C67/10 ,  Y02P20/582 ,  C07C69/78 ,  C07C43/215 ,  C07C43/15 ,  C07C43/1785 ,  C07C43/23

摘要： A method for producing an allyl compound having a compositional formula different from that of an allyl starting material compound, which comprises reacting the allyl starting material compound with an oxygen nucleophilic agent in the presence of a catalyst containing at least one transition metal compound containing a transition metal selected from the group consisting of transition metals belonging to Group 8 to Group 10 of the Periodic Table and a multidentate phosphite compound.

摘要翻译： 一种具有与烯丙基原料化合物不同的组成式的烯丙基化合物的制备方法，该方法包括在含有至少一种含有过渡金属化合物的过渡金属化合物的催化剂存在下，使烯丙基原料化合物与氧亲核剂反应 选自属于元素周期表第8族至第10族的过渡金属的金属和多元亚磷酸酯化合物。

公开(公告)号：US07119222B2

公开(公告)日：2006-10-10

申请号：US10648210

申请日：2003-08-27

申请人： Masaki Takai ,  Yoshiyuki Tanaka

发明人： Masaki Takai ,  Yoshiyuki Tanaka

IPC分类号： C07C69/533 ,  C07C41/06

CPC分类号： C07C41/16 ,  C07C67/10 ,  Y02P20/582 ,  C07C69/78 ,  C07C43/215 ,  C07C43/15 ,  C07C43/1785 ,  C07C43/23

摘要： A method for producing an allyl compound having a compositional formula different from that of an allyl starting material compound, which comprises reacting the allyl starting material compound with an oxygen nucleophilic agent in the presence of a catalyst containing at least one transition metal compound containing a transition metal selected from the group consisting of transition metals belonging to Group 8 to Group 10 of the Periodic Table and a multidentate phosphite compound.

摘要翻译： 一种具有与烯丙基原料化合物不同的组成式的烯丙基化合物的制备方法，该方法包括在含有至少一种含有过渡金属化合物的过渡金属化合物的催化剂存在下，使烯丙基原料化合物与氧亲核剂反应 选自属于元素周期表第8族至第10族的过渡金属的金属和多元亚磷酸酯化合物。

公开(公告)号：US20050075518A1

公开(公告)日：2005-04-07

申请号：US10650697

申请日：2003-08-29

申请人： Masaki Takai ,  Yoshiyuki Tanaka

发明人： Masaki Takai ,  Yoshiyuki Tanaka

IPC分类号： C07C41/16 ,  C07C67/10 ,  C07C209/66 ,  C07C211/35 ,  C08G63/52 ,  C08G63/87 ,  C07C41/06

CPC分类号： C08G63/52 ,  C07C41/16 ,  C07C67/10 ,  C07C209/66 ,  C07C2601/14 ,  C08G63/87 ,  C07C69/78 ,  C07C211/35 ,  C07C43/215 ,  C07C43/15

摘要： A method for producing an allyl compound having a compositional formula different from that of an allyl starting material compound, which comprises reacting the allyl starting material compound with a nucleophilic agent in the presence of a catalyst containing at least one transitional metal compound containing a transition metal selected from the group consisting of transition metals belonging to Group 8 to Group 10 of the Periodic Table and at least one bidentate coordinated phosphite compound selected from the group consisting of compounds having structures of the following formulae (I) to (III): wherein A1 to A3 are respectively independently a diarylene group having a branched alkyl group at the ortho-position, R1 to R6 are respectively independently an alkyl group which may have a substituent or an aryl group which may have a substituent (including a heterocyclic compound forming an aromatic 6π electron cloud on the upper and lower sides of the ring, hereinafter the same), and Z1 to Z3 are respectively independently an alkylene group which may have a substituent, an arylene group which may have a substituent, an alkylene-arylene group which may have a substituent or a diarylene group which may have a substituent.

摘要翻译： 一种具有与烯丙基原料化合物不同的组成式的烯丙基化合物的制备方法，该方法包括在含有至少一种含有过渡金属的过渡金属化合物的催化剂存在下使烯丙基原料化合物与亲核剂反应 选自属于元素周期表第8族至第10族的过渡金属和至少一种选自下式（I）至（III）的结构的化合物的二齿配位的亚磷酸酯化合物：其中A A 1〜A 3分别独立地为在邻位具有支链烷基的二亚芳基，R 1〜R 6分别独立地为可以具有取代基的烷基或芳基， 可以具有取代基（包括在环的上侧和下侧形成芳香族6pi电子云的杂环化合物，以下相同 ）和Z 1〜Z 3分别独立地为可以具有取代基的亚烷基，可以具有取代基的亚芳基，可以具有取代基的亚芳基 - 亚芳基或可具有取代基的二亚芳基 取代基。

公开(公告)号：US06583324B2

公开(公告)日：2003-06-24

申请号：US09954171

申请日：2001-09-18

申请人： Masaki Takai ,  Iwao Nakajima ,  Tooru Tsukahara ,  Yoshiyuki Tanaka ,  Hisao Urata ,  Akio Nakanishi

发明人： Masaki Takai ,  Iwao Nakajima ,  Tooru Tsukahara ,  Yoshiyuki Tanaka ,  Hisao Urata ,  Akio Nakanishi

IPC分类号： C07C4550

CPC分类号： C07F9/025 ,  B01J31/185 ,  B01J2231/321 ,  B01J2531/822 ,  C07C45/50 ,  Y02P20/584 ,  C07C47/02

摘要： A process for producing an aldehyde, which comprises a reaction step of producing an aldehyde by reacting an olefinic compound with carbon monoxide and hydrogen in the presence of a rhodium complex catalyst comprising at least rhodium and an organic phosphite in a reaction zone, a separation step of obtaining a catalyst solution containing the rhodium complex catalyst by separating the aldehyde from a reaction solution taken from the reaction zone, and a recycling step of recycling the catalyst solution into the reaction zone, wherein the aldehyde is separated from the reaction solution in such a manner as to make an aldehyde concentration from 0.5 to 99 wt % in the catalyst solution.

公开(公告)号：US07423168B2

公开(公告)日：2008-09-09

申请号：US10649767

申请日：2003-08-28

申请人： Masaki Takai ,  Yoshiyuki Tanaka

发明人： Masaki Takai ,  Yoshiyuki Tanaka

IPC分类号： C07C69/76 ,  C07C41/06

CPC分类号： C07C41/16 ,  C07C41/06 ,  C07C67/10 ,  C07C69/78 ,  C07C43/15 ,  C07C43/215

摘要： A method for producing an allyl compound having a compositional formula different from that of an allyl starting material compound, which comprises reacting the allyl starting material compound with an oxygen nucleophilic agent having a structure different from that of the allyl starting material compound in the presence of a catalyst containing at least one transition metal compound containing a transition metal selected from the group consisting of transition metals belonging to Group 8 to Group 10 of the Periodic Table and a monodentate phosphite compound having a structure of the following formula (1): P(OR1)(OR2)(OR3)  (1) wherein R1, R2 and R3 are respectively independently an alkyl group which may have a substituent, carbon chains of R1, R2 and R3 may have at least one carbon-carbon double bond or triple bond, and at least two optional groups of R1, R2 and R3 may bond to each other to form at least one cyclic structure.

摘要翻译： 一种具有与烯丙基原料化合物不同的组成式的烯丙基化合物的制备方法，该方法包括使烯丙基原料化合物与具有与烯丙基原料化合物不同的结构的氧亲核剂在存在 含有至少一种含有选自属于周期表第8族至第10族的过渡金属的过渡金属的过渡金属化合物和具有下式（1）的结构的单齿亚磷酸酯化合物的催化剂： 在线公式描述=“在线公式”end =“lead”？> P（OR ^{2 ）（OR 2 < / SUP>）（1）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中R 1，R 2，和 R 3分别独立地是可以具有取代基的烷基，R 1，R 2和R 3的碳链， / SUP>可能在l 东一个碳 - 碳双键或三键，并且R 1，R 2和R 3的至少两个任选基团可以键合到 彼此形成至少一个循环结构。}

公开(公告)号：US07173157B2

公开(公告)日：2007-02-06

申请号：US10650697

申请日：2003-08-29

申请人： Masaki Takai ,  Yoshiyuki Tanaka

发明人： Masaki Takai ,  Yoshiyuki Tanaka

IPC分类号： C07C41/06 ,  C07C69/76

CPC分类号： C08G63/52 ,  C07C41/16 ,  C07C67/10 ,  C07C209/66 ,  C07C2601/14 ,  C08G63/87 ,  C07C69/78 ,  C07C211/35 ,  C07C43/215 ,  C07C43/15

摘要： An allyl compound having a formula different from that of an allyl starting compound is prepared by a process of reacting the allyl starting compound with a nucleophilic agent in the presence of a catalyst containing at least one transition metal compound containing a transition metal selected from the group consisting of elements belonging to Group 8 to Group 10 of the Periodic Table and at least one bidentate coordinated phosphite compound selected from the group consisting of compounds having the following formulae (I) to (III): wherein A1 to A3 are respectively independently a diarylene group having a branched alkyl group at the ortho-position, R1 to R6 are respectively independently an alkyl group which may have a substituent or an aryl group which may have a substituent (including a heterocyclic compound forming an aromatic 6Π electron cloud on the upper and lower sides of the ring, hereinafter the same), and Z1 to Z3 are respectively independently an optionally substituted alkylene group, an optionally substituted arylene group, an optionally substituted alkylene-arylene group or an optionally substituted diarylene group.

摘要翻译： 通过使烯丙基起始化合物与亲核剂在含有至少一种含有过渡金属的过渡金属的催化剂存在下反应的方法来制备具有与烯丙基起始化合物不同的烯丙基化合物， 由属于元素周期表第8至10族的元素和至少一种选自具有下式（I）至（III）的化合物的二齿配位的亚磷酸酯化合物组成：其中A 1〜 分别独立地为在邻位具有支链烷基的二亚芳基，R 1至R 6分别独立地为 可以具有取代基的烷基或可具有取代基的芳基（包括在环的上侧和下侧形成芳香族6Pi电子云的杂环化合物，以下相同），Z 1 到Z 3 分别独立地为任选取代的亚烷基，任选取代的亚芳基，任选取代的亚烷基 - 亚芳基或任选取代的亚芳基。

公开(公告)号：US06291717B1

公开(公告)日：2001-09-18

申请号：US09457742

申请日：1999-12-10

申请人： Masaki Takai ,  Iwao Nakajima ,  Tooru Tsukahara ,  Yoshiyuki Tanaka ,  Hisao Urata ,  Akio Nakanishi

发明人： Masaki Takai ,  Iwao Nakajima ,  Tooru Tsukahara ,  Yoshiyuki Tanaka ,  Hisao Urata ,  Akio Nakanishi

IPC分类号： C07C4550

CPC分类号： C07F9/025 ,  B01J31/185 ,  B01J2231/321 ,  B01J2531/822 ,  C07C45/50 ,  Y02P20/584 ,  C07C47/02

摘要： A process for producing an aldehyde, which comprises a reaction step of producing an aldehyde by reacting an olefinic compound with carbon monoxide and hydrogen in the presence of a rhodium complex catalyst comprising at least rhodium and an organic phosphite in a reaction zone, a separation step of obtaining a catalyst solution containing the rhodium complex catalyst by separating the aldehyde from a reaction solution taken from the reaction zone, and a recycling step of recycling the catalyst solution into the reaction zone, wherein the aldehyde is separated from the reaction solution in such a manner as to make an aldehyde concentration from 0.5 to 99 wt % in the catalyst solution.

摘要翻译： 一种生产醛的方法，其包括在反应区中在至少包含铑和有机亚磷酸酯的铑络合物催化剂的存在下使烯属化合物与一氧化碳和氢气反应制备醛的反应步骤，分离步骤 通过从取自反应区的反应溶液中分离醛获得含有铑络合物催化剂的催化剂溶液，以及将催化剂溶液再循环到反应区中的再循环步骤，其中醛与反应溶液分离 以使催化剂溶液中醛浓度为0.5〜99重量％。

公开(公告)号：US08897200B2

公开(公告)日：2014-11-25

申请号：US13121931

申请日：2009-10-28

申请人： Shoji Fukuzawa ,  Yoshiyuki Tanaka

发明人： Shoji Fukuzawa ,  Yoshiyuki Tanaka

IPC分类号： H04B7/14 ,  H04J1/10 ,  H04J3/08 ,  H04B7/155 ,  H04W24/04 ,  H04J3/06 ,  H04W88/08

CPC分类号： H04B7/155 ,  H04J3/0641 ,  H04W24/04 ,  H04W88/085

摘要： When no synchronization signal is transmitted over a system bus (115), a master repeater is arbitrarily selected from a plurality of repeaters (1112 to 111n), starts transmitting a synchronization signal over the system bus (115), and transmits information to the system bus (115) in synchronization with the synchronization signal. Other slave repeaters transmit information to the system bus (115) in synchronization with the synchronization signal transmitted by the master repeater.

摘要翻译： 当没有通过系统总线（115）发送同步信号时，从多个中继器（1112至111n）中任意选择主中继器，开始通过系统总线（115）发送同步信号，并向系统发送信息 总线（115）与同步信号同步。 其他从属中继器与主中继器发送的同步信号同步地向系统总线（115）发送信息。

公开(公告)号：US08867429B2

公开(公告)日：2014-10-21

申请号：US13121947

申请日：2009-10-28

申请人： Shoji Fukuzawa ,  Yoshiyuki Tanaka

发明人： Shoji Fukuzawa ,  Yoshiyuki Tanaka

IPC分类号： H04B7/14 ,  H04W48/20 ,  H04W72/04 ,  H04W88/08 ,  H04B7/26 ,  H04W48/08

CPC分类号： H04W48/20 ,  H04B7/2606 ,  H04W48/08 ,  H04W72/0493 ,  H04W88/08

摘要： Plural repeaters (1111 to 111n) are connected one another via a system bus (115), and each of which detects the state of another repeater by checking a signal transmitted over the system bus (115). When stopping the operation of home repeater (e.g., the repeater (1111)) which performs relaying process among wireless terminal devices (TA) to (TH), a secondary repeater (e.g., the repeater (1112)) set beforehand detects that the home repeater breaks down as the secondary repeater becomes unable to detect the signal over the system bus (115). The secondary repeater responds to the detection and bears the relaying process instead of the home repeater.

摘要翻译： 多个中继器（1111至111n）经由系统总线（115）彼此连接，并且每个中继器通过检查通过系统总线（115）发送的信号来检测另一中继器的状态。 当停止在无线终端装置（TA）至（TH）中执行中继处理的本地中继器（例如，中继器（1111））的操作时，预先设置的次级中继器（例如，中继器（1112））检测到家庭 中继器因次级中继器无法通过系统总线（115）检测到信号而中断。 次级中继器响应检测并承担中继过程，而不是本地中继器。