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    METHOD FOR MANUFACTURING KETONE
    3.
    发明申请
    METHOD FOR MANUFACTURING KETONE 审中-公开
    制造酮的方法

    公开(公告)号：US20120197036A1

    公开(公告)日：2012-08-02

    申请号：US13500677

    申请日：2010-10-08

    申请人： Kiyotomi Kaneda ,  Hisashi Sone

    发明人： Kiyotomi Kaneda ,  Hisashi Sone

    IPC分类号： C07C253/30 ,  C07C67/29 ,  C07C45/34

    CPC分类号： C07C253/30 ,  C07C45/34 ,  C07C45/36 ,  C07C45/38 ,  C07C67/29 ,  C07C2601/14 ,  C07C49/303 ,  C07C49/175 ,  C07C49/17 ,  C07C69/14 ,  C07C69/716 ,  C07C255/17

    摘要： A method for manufacturing a ketone, includes oxidizing an internal olefin or a cyclic olefin having a functional group containing a hetero atom and one carbon-carbon double bond or more at a position other than terminals of a molecule thereof in an amide-based solvent in the presence of water, a palladium catalyst, and molecular oxygen, without oxidizing the functional group, thereby bonding an oxo group to at least one of the carbon atoms constituting the carbon-carbon double bond. The amide-based solvent is represented by formula (1): wherein R1 represents an alkyl group having 1 to 4 carbon atoms; R2 and R3 each independently represent an alkyl group having 1 to 4 carbon atoms or an aryl group; and when R1 and R2 are alkyl groups, R1 and R2 may be bonded to each other to form a ring structure.

    摘要翻译： 一种制造酮的方法包括在酰胺类溶剂中，在其分子末端以外的位置，在酰胺类溶剂中氧化含有杂原子和1个碳 - 碳双键的官能团的内烯烃或环状烯烃 存在水，钯催化剂和分子氧，而不氧化官能团，从而将氧代基键合到构成碳 - 碳双键的至少一个碳原子上。 酰胺类溶剂由式（1）表示：其中R 1表示具有1至4个碳原子的烷基; R2和R3各自独立地表示具有1至4个碳原子的烷基或芳基; 并且当R 1和R 2是烷基时，R 1和R 2可以彼此键合以形成环结构。

    Process for producing β-oxonitrile compound or alkali metal salt thereof
    4.
    发明授权
    Process for producing β-oxonitrile compound or alkali metal salt thereof 有权
    制备β-氧腈化合物或其碱金属盐的方法

    公开(公告)号：US07141693B2

    公开(公告)日：2006-11-28

    申请号：US10485495

    申请日：2002-08-02

    申请人： Akio Matsushita ,  Kiyotaka Yoshii ,  Masayoshi Oue ,  Taku Nakamura ,  Shuji Yamada

    发明人： Akio Matsushita ,  Kiyotaka Yoshii ,  Masayoshi Oue ,  Taku Nakamura ,  Shuji Yamada

    IPC分类号： C07C255/03

    CPC分类号： C07C253/30 ,  C07C255/17

    摘要： The present invention relates to a process for preparing a β-oxonitrile compound or an alkali metal salt thereof which comprises reacting a carboxylic ester represented by the formula (1): R1CO2R2  (1) wherein R1 and R2 each represent a group which does not participate in a reaction, provided that R2 excludes a hydrogen atom, with a nitrile compound represented by the formula (2): R3CH2CN  (2) wherein R3 represents an alkyl group, and a base at 145 to 300° C. in a sealed vessel to obtain an alkali metal salt of a β-oxonitrile compound represented by the formula (3): wherein R1 and R3 have the same meanings as defined above, and neutralizing the same with an acid, if necessary.

    摘要翻译： 本发明涉及一种制备β-氧腈化合物或其碱金属盐的方法，包括使由式（1）表示的羧酸酯：<？in-line-formula description =“In-line Formula”end =“lead”？> R <1> 2 2（1）<？in-line-formula description =“在线公式 “末端”“尾”→其中R 1和R 2各自表示不参与反应的基团，条件是R 2 O >不包括氢原子与式（2）表示的腈化合物：<？in-line-formula description =“In-line formula”end =“lead”？> R 3 CN（2）<βin-line-formula description =“In-line Formulas”end =“tail”？>其中R 3表示烷基，和 在密封容器中在145-300℃的碱，得到由式（3）表示的β-氧腈化合物的碱金属盐：其中R 1和R 3， / SUP>与定义的含义相同 如果需要，用酸中和酸。