公开(公告)号：US6143479A

公开(公告)日：2000-11-07

申请号：US449072

申请日：1999-11-24

申请人： Ulrich Fiebag ,  Hans-Joachim Timpe

发明人： Ulrich Fiebag ,  Hans-Joachim Timpe

IPC分类号： G03F7/32

CPC分类号： G03F7/322

摘要： An aqueous alkaline composition comprising at least one phosphonic acid, at least one polyglycol derivative and at least one glycol. The composition can be used as either a developer or a replenisher for either positive-working or negative-working alkaline developable lithographic printing plates, including thermal plates.

摘要翻译： 一种包含至少一种膦酸，至少一种聚乙二醇衍生物和至少一种二醇的含水碱性组合物。 该组合物可用作用于正性或负性碱性可显影平版印刷版（包括热敏板）的显影剂或补充剂。

公开(公告)号：US20080160444A1

公开(公告)日：2008-07-03

申请号：US11573793

申请日：2005-08-25

申请人： Ulrich Fiebag ,  Hans-Joachim Timpe ,  Ursula Muller

发明人： Ulrich Fiebag ,  Hans-Joachim Timpe ,  Ursula Muller

IPC分类号： G03F7/004 ,  B05D5/04 ,  C08G77/30

CPC分类号： B41N3/038 ,  B41C1/1008 ,  B41C1/1058 ,  B41C1/1066 ,  B41C1/1091 ,  B41C2210/02 ,  B41C2210/04 ,  B41C2210/06 ,  B41C2210/22 ,  B41C2210/24 ,  C09D183/08

摘要： Lithographic substrate comprising (a) a dimensionally stable plate- or foil-shaped support, (b) an aluminum oxide layer provided on at least one side of the support (a), and (c) a hydrophilic layer applied onto the aluminum oxide layer comprising at least one phosphono-substituted siloxane of the general formula (I)

摘要翻译： 平版印刷基材包括（a）尺寸稳定的板状或箔状载体，（b）设置在载体（a）的至少一侧的氧化铝层，和（c）施加到氧化铝层上的亲水层 包含至少一种通式（I）的膦酰取代的硅氧烷，

公开(公告)号：US06759185B2

公开(公告)日：2004-07-06

申请号：US09992688

申请日：2001-11-14

申请人： Ulrich Fiebag ,  Hans-Joachim Timpe ,  Uwe Tondock ,  Andreas Vihs

发明人： Ulrich Fiebag ,  Hans-Joachim Timpe ,  Uwe Tondock ,  Andreas Vihs

IPC分类号： G03C531

CPC分类号： G03F7/3092

摘要： A method for the refreshment and reuse of loaded developers used in lithographic printing is disclosed. A polyoxyalkylene derivative is added to a silicate-containing loaded developer. Insoluble material is separated and the alkalinity level of the resulting essentially colorless liquid adjusted to produce a refreshed developer. The refreshed developer may be used to develop additional exposed imageable elements.

摘要翻译： 公开了一种用于平版印刷中使用的加载显影剂的刷新和再利用的方法。 将聚氧化烯衍生物加入到含硅酸盐的负载显影剂中。 分离不溶物，调节所得到的基本无色液体的碱度水平以产生刷新的显影剂。 刷新的显影剂可用于开发额外的可曝光可成像元件。

公开(公告)号：US06569609B2

公开(公告)日：2003-05-27

申请号：US10075661

申请日：2002-02-14

申请人： Hans-Joachim Timpe ,  Ulrich Fiebag

发明人： Hans-Joachim Timpe ,  Ulrich Fiebag

IPC分类号： G03F730

CPC分类号： G03F7/3071

摘要： A replenisher composition developing exposed radiation-sensitive printing plate precursors for plate/developer systems in which the electrical conductivity of the developer does not decrease to the same extend as the activity of the developer decreases or even increases is disclosed. A method for developing exposed radiation-sensitive printing plates using the replenisher composition is also disclosed.

公开(公告)号：US06482578B2

公开(公告)日：2002-11-19

申请号：US10085823

申请日：2002-02-27

申请人： Ulrich Fiebag ,  Harald Baumann ,  Hans-Joachim Timpe

发明人： Ulrich Fiebag ,  Harald Baumann ,  Hans-Joachim Timpe

IPC分类号： G03F732

CPC分类号： G03F7/322

摘要： An aqueous developer for imageable elements that contain a radiation-sensitive initiator system and at least one free radical polymerizable material is disclosed. The developer develops these plates quickly, with high throughput, but with no sludge formation in the developing process. The developer contains water, a buffer, and one or more filter dyes and/or one of more free radical inhibitors. The imageable elements are useful as printing plates.

公开(公告)号：US6060217A

公开(公告)日：2000-05-09

申请号：US922190

申请日：1997-09-02

申请人： My T. Nguyen ,  Nishith Merchant ,  Ken-Ichi Shimazu ,  S. Peter Pappas ,  Robert Hallman ,  Jerome Philip Kesselman ,  Celin Savariar-Hauck ,  Gerhard Hauck ,  Hans-Joachim Timpe ,  Omkar J. Natu ,  Ajay Shah

发明人： My T. Nguyen ,  Nishith Merchant ,  Ken-Ichi Shimazu ,  S. Peter Pappas ,  Robert Hallman ,  Jerome Philip Kesselman ,  Celin Savariar-Hauck ,  Gerhard Hauck ,  Hans-Joachim Timpe ,  Omkar J. Natu ,  Ajay Shah

IPC分类号： B41C1/10 ,  B41M5/36 ,  G03F7/30

CPC分类号： B41C1/1008 ,  B41M5/368 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/24 ,  B41C2210/262 ,  B41M5/36 ,  Y10S430/107 ,  Y10S430/145

摘要： A method for directly imaging a lithographic printing surface using infrared radiation without the requirement of pre- or post-UV-light exposure, or heat treatment employs a printing plate which contains a support with a hydrophilic surface overcoated with an imaging layer. The imaging layer contains at least one polymer having bonded pendent groups which are hydroxy, carboxylic acid, tert-butyl-oxycarbonyl, sulfonamide, amide, nitrile, urea, or combinations thereof; as well as an infrared absorbing compound. The imaging layer may contain a second polymer which has bonded pendent groups which are 1,2-napthoquinone diazide, hydroxy, carboxylic acid, sulfonamide, hydroxymethyl amide, alkoxymethyl amide, nitrile, maleimide, urea, or combinations thereof. The imaging layer may also contain a visible absorption dye, a solubility inhibiting agent, or both. In practice, the imaging layer is imagewise exposed to infrared radiation to produce exposed image areas in the imaged layer which have transient solubility in aqueous alkaline developing solution, so that solubility is gradually lost over a period of time until the imaged areas become as insoluble as non-imaged areas. Within a short time period of the imaging exposure, the imaged layer is developed with an aqueous alkaline developing solution to form the lithographic printing surface. In this method, the infrared radiation preferably is laser radiation which is digitally controlled.

摘要翻译： 使用红外线辐射直接对平版印刷表面进行成像的方法，而不需要进行紫外线照射之前或之后的曝光或热处理，使用包含具有用成像层涂覆的亲水表面的载体的印刷版。 成像层含有至少一种具有键合的侧基的聚合物，其为羟基，羧酸，叔丁基 - 氧羰基，磺酰胺，酰胺，腈，脲或其组合; 以及红外线吸收剂。 成像层可以含有具有键合的侧基的第二聚合物，其为1,2-萘醌二叠氮，羟基，羧酸，磺酰胺，羟甲基酰胺，烷氧基甲基酰胺，腈，马来酰亚胺，脲或其组合。 成像层还可以含有可见吸收染料，溶解性抑制剂，或两者。 在实践中，成像层被成像地暴露于红外辐射，以在成像层中产生在含水碱性显影液中具有瞬时溶解度的曝光图像区域，使得溶解度在一段时间内逐渐丧失，直到成像区域变得不溶于 非成像区域。 在成像曝光的短时间内，用含水碱性显影液显影成像层以形成平版印刷表面。 在该方法中，红外辐射优选为数字控制的激光辐射。

公开(公告)号：US06391524B2

公开(公告)日：2002-05-21

申请号：US09444126

申请日：1999-11-19

申请人： Michael Yates ,  Celin Savariar-Hauck ,  Gerhard Hauck ,  Hans-Joachim Timpe

发明人： Michael Yates ,  Celin Savariar-Hauck ,  Gerhard Hauck ,  Hans-Joachim Timpe

IPC分类号： G03F7105

CPC分类号： B41C1/1008 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/262 ,  Y10S430/145

摘要： A heat-sensitive composition, for example a coating on a lithographic printing plate, comprises a carboxylic acid derivative of a cellulosic polymer. The composition may contain a radiation absorbing compound and suitable electromagnetic radiation, preferably infra-red radiation, may be used to heat the composition imagewise. The presence of the cellulosic polymer enhances resistance to certain organic liquids.

摘要翻译： 热敏组合物，例如平版印刷版上的涂层，包含纤维素聚合物的羧酸衍生物。 组合物可以含有辐射吸收化合物，并且可以使用合适的电磁辐射，优选红外辐射来成像地加热组合物。 纤维素聚合物的存在增强了对某些有机液体的抵抗力。

公开(公告)号：US06309792B1

公开(公告)日：2001-10-30

申请号：US09690898

申请日：2000-10-17

申请人： Gerhard Hauck ,  Celin Savariar-Hauck ,  Hans-Joachim Timpe ,  Paul R. West ,  Heidi M. Munnelly

发明人： Gerhard Hauck ,  Celin Savariar-Hauck ,  Hans-Joachim Timpe ,  Paul R. West ,  Heidi M. Munnelly

IPC分类号： G03C176

CPC分类号： B41C1/1016 ,  B41C1/1008 ,  B41C2201/02 ,  B41C2210/04 ,  B41C2210/06 ,  B41C2210/22 ,  B41C2210/24 ,  B41M5/368 ,  C08K5/175

摘要： The present invention relates to IR-sensitive compositions containing an initiator system comprising: (a) at least one compound capable of absorbing IR light (b) at least one compound capable of producing radicals and (c) at least one polycarboxylic acid comprising an aromatic moiety substituted with a heteroatom selected from N, O and S and also at least two carboxyl groups wherein at least one of the carboxyl groups is bonded to the heteroatom via a methylene group. These compositions are inter alia extraordinarily suitable for the manufacture of printing plates.

摘要翻译： 本发明涉及含有引发剂体系的IR敏感组合物，其包含：（a）至少一种能够吸收IR光的化合物（b）至少一种能够产生自由基的化合物，和（c）至少一种包含芳族化合物的多元羧酸 部分被选自N，O和S的杂原子以及至少两个羧基基团取代，其中至少一个羧基通过亚甲基与杂原子结合。这些组合物特别适用于制造印版 。

公开(公告)号：US06352812B1

公开(公告)日：2002-03-05

申请号：US09301866

申请日：1999-04-29

申请人： Ken-Ichi Shimazu ,  Jayanti Patel ,  Shashikant Saraiya ,  Nishith Merchant ,  Celin Savariar-Hauck ,  Hans-Joachim Timpe ,  Christopher D. McCullough

发明人： Ken-Ichi Shimazu ,  Jayanti Patel ,  Shashikant Saraiya ,  Nishith Merchant ,  Celin Savariar-Hauck ,  Hans-Joachim Timpe ,  Christopher D. McCullough

IPC分类号： G03F709

CPC分类号： B41M5/42 ,  B41C1/1016 ,  B41C2201/04 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/14 ,  B41C2210/24 ,  B41C2210/26 ,  B41C2210/262 ,  B41C2210/264 ,  B41C2210/266 ,  B41M5/368 ,  B41M5/44 ,  B41M5/465

摘要： A thermal lithographic printing plate, which can be imaged by thermal energy typically by imagewise exposure with an infrared emitting laser, a thermal printing head, etc., is made up of a hydrophilic substrate, and a composite layer structure composed of two layer coatings. Preferably, the first layer of the composite is composed of an aqueous developable polymer mixture containing a photothermal conversion material which is contiguous to the hydrophilic substrate. The second layer of the composite is composed of one or more non-aqueous soluble polymers which are soluble or dispersible in a solvent which does not dissolve the first layer. The plate is exposed with an infrared laser or a thermal print head, and upon aqueous development of the imaged plate, the exposed portions are removed exposing hydrophilic substrate surfaces receptive to conventional aqueous fountain solutions. The unexposed portions contain the ink-receptive image areas. The second layer may also contain a photothermal conversion material. Alternatively, the composite layer may be free of photothermal conversion material when thermal imaging is carried out using a thermal printing head.

摘要翻译： 可以通过热能成像通过用红外发射激光成像曝光，热打印头等来成像的热平版印刷版由亲水基材和由两层涂层组成的复合层结构构成。 优选地，复合材料的第一层由包含与亲水基底邻接的光热转换材料的水性可显影聚合物混合物组成。 复合材料的第二层由一种或多种可溶于或不溶于不溶于第一层的溶剂中的非水溶性聚合物组成。 该板用红外激光或热打印头曝光，并且在成像板的水性显影时，去除曝光部分，暴露接受常规水性喷泉溶液的亲水底物表面。 未曝光部分包含吸墨图像区域。 第二层也可以含有光热转换材料。 或者，当使用热敏打印头进行热成像时，复合层可以不含光热转换材料。

公开(公告)号：US6051366A

公开(公告)日：2000-04-18

申请号：US450968

申请日：1995-05-25

申请人： Harald Baumann ,  Hans-Joachim Timpe ,  Hans-Peter Herting

发明人： Harald Baumann ,  Hans-Joachim Timpe ,  Hans-Peter Herting

IPC分类号： G03F7/029

CPC分类号： G03F7/029 ,  Y10S430/115 ,  Y10S430/12 ,  Y10S430/121 ,  Y10S430/127 ,  Y10S430/148

摘要： A visible radiation sensitive composition is described which comprises a binder, one or more polymerizable compounds containing at least one polymerizable group, and one or more dyes having an absorption range in the emission range of the radiation source, characterized in that said composition comprises as an initiator an initiator system consisting of a metallocene as a photoinitiator and an onium compound as a coinitiator. The visible radiation sensitive composition shows an increased radiation sensitivity compared to the known radiation sensitive compositions and is especially suitable for recording materials such as printing plates, which can, in particular, also be exposed by means of laser radiation in the visible range.

摘要翻译： 描述了一种可见的辐射敏感组合物，其包含粘合剂，含有至少一个可聚合基团的一种或多种可聚合化合物和一种或多种在辐射源的发射范围内具有吸收范围的染料，其特征在于所述组合物包含作为 引发剂由作为光引发剂的茂金属和作为共引发剂的鎓化合物组成的引发剂体系。 可见的辐射敏感组合物显示与已知的辐射敏感组合物相比增加的辐射敏感性，并且特别适用于记录诸如印刷板的材料，其特别是也可以通过在可见光范围内的激光辐射曝光。