公开(公告)号：US5055527A

公开(公告)日：1991-10-08

申请号：US541078

申请日：1990-06-20

申请人： Klaus Bronstert ,  Hans-Dieter Schwaben ,  Adolf Echte

发明人： Klaus Bronstert ,  Hans-Dieter Schwaben ,  Adolf Echte

IPC分类号： C08L9/00 ,  C08L25/04 ,  C08L35/06 ,  C08L53/02

CPC分类号： C08L25/04 ,  C08L35/06 ,  C08L53/02 ,  C08L9/00

摘要： Impact modified thermoplastic blends of components A, B and optionally C, consisting of:A) from 99 to 60 percent by weight of a polymeric rigid matrix consisting ofa1) 60-99.5 percent by weight of an aromatic vinyl compound present as copolymerized units,a2) 0.5-20 percent by weight of an unsaturated carboxylic anhydride present as copolymerized units anda3) 014 35 percent by weight of an alkenylnitrile present as copolymerized units,B) from 1 to 40 percent by weight of a polymeric flexibilizing component consisting ofb1) 100-60 percent by weight of a monomer from the group of the 1,4-dienes which is present as copolymerized units andb2) 0-40 percent by weight of an aromatic vinyl compound present as copolymerized units. and optionallyC) customary additives in customary amounts, the polymers of flexibilizing component B having amino end groups, are used for producing moldings.

摘要翻译： 组分A，B和任选C的抗冲改性热塑性共混物，由以下组成：A）99-60％重量的由a1）60-99.5％（重量）以共聚单元形式存在的芳族乙烯基化合物组成的聚合刚性基质， a2）0.5-20重量％作为共聚单元存在的不饱和羧酸酐和a3）作为共聚单元存在的作为共聚单元的链烯基腈的重量比为35重量％，B）1〜40重量％的由b1 ）100-60重量％的作为共聚单元存在的1,4-二烯基的单体，和b2）0-40重量％作为共聚单元存在的芳族乙烯基化合物。 和任选的C）常规量的常规添加剂，具有氨基端基的增韧组分B的聚合物用于生产模制品。

公开(公告)号：US5053462A

公开(公告)日：1991-10-01

申请号：US567748

申请日：1990-08-15

申请人： Dietmar Bender ,  Klaus Bronstert

发明人： Dietmar Bender ,  Klaus Bronstert

IPC分类号： C08F8/26 ,  C08F4/06 ,  C08F8/46

CPC分类号： C08F8/46 ,  C08F2810/30 ,  C08F2810/40

摘要： A modified polyisobutene has the general formula I ##STR1## where R.sup.1 is an olefinically unsaturated divalent radical, R.sup.2 is one of the radicals --CH.sub.2 --C(.dbd.CH.sub.2)--CH.sub.2 -- or --CH.sub.2 --C(CH.sub.3).dbd.CH-- or m and n are each a degree of polymerization in particular from 1 to 1000.

摘要翻译： 修饰的聚异丁烯具有通式I（I）其中R 1是烯属不饱和二价基团，R 2是基团-CH 2 -C（= CH 2）-CH 2 - 或-CH 2 -C（CH 3）= CH - 或m和n各自为1〜1000聚合度。

公开(公告)号：US5003010A

公开(公告)日：1991-03-26

申请号：US420710

申请日：1989-10-12

申请人： Klaus Bronstert ,  Wolfgang F. Mueller

发明人： Klaus Bronstert ,  Wolfgang F. Mueller

IPC分类号： C08F8/42 ,  C08F8/44 ,  C08F297/04

CPC分类号： C08F8/44

摘要： Block polymers of vinylaromatics and conjugated dienes which posses acidic terminal groups and are in the form of salts which contain divalent or polyvalent metal cations or cation complexes. A process for the preparation of such salts of block polymers containing acid groups, and the use of these polymers as thermoplastic materials, as thermoplastic elastomers, for modifying thermoplastic materials, as viscosity index improvers in lubricating oils or as components in hot melt adhesives.

摘要翻译： 乙烯基芳烃和共轭二烯的嵌段聚合物，其具有酸性端基并且为含有二价或多价金属阳离子或阳离子络合物的盐形式。 制备这种含酸基团的嵌段聚合物盐的方法，以及这些聚合物作为热塑性材料的热塑性弹性体用作改性热塑性材料，作为润滑油中的粘度指数改进剂或热熔粘合剂中的组分的用途。

公开(公告)号：US4816520A

公开(公告)日：1989-03-28

申请号：US119492

申请日：1987-11-12

申请人： Klaus Bronstert

发明人： Klaus Bronstert

IPC分类号： C08F8/00 ,  C08C19/44 ,  C08F8/18 ,  C08F8/30 ,  C08F8/46 ,  C08F290/00 ,  C08F299/00

CPC分类号： C08F8/18 ,  C08C19/44 ,  C08F8/30 ,  C08F8/46

摘要： The terminally functionalized polymers are prepared from living polymers obtained by anionic polymerization of olefinically unsaturated monomers by reacting the living polymers first with capping reagents comprising nitrogen compounds of the general formulae I to VII: ##STR1## where R.sup.1 and R.sup.4 are each H, alkyl cycloalkyl or aryl, R.sup.2, R.sup.3 and R.sup.5 are each alkyl, cycloalkyl or aryl and A is a substituted or unsubstituted bridge which, in addition to the C members, can also contain N or O members and ##STR2## where R.sup.6 and R.sup.7 are each alkyl or aryl, A is a single-membered substituted or unsubstituted carbon bridge and B is a 2- to 12-membered bridge of which at least those members adjacent to the nitrogen atom comprise --C(R.sup.8, R.sup.9) radicals, where R.sup.8 and R.sup.9 can be identical or different and are H, alkyl, cycloalkyl or aryl, and the nonadjacent members can be not only --C(R.sup.8, R.sup.9) radicals but also ethyl or N-alkyl or N-aryl-imino groups, and the polymer obtained is then made to react with a terminating agent which contains halogen or acid anhydride groups, suitable capping reagents being compounds of the class of 1,5-diazabicyclo[3,1,0]hexane and suitable terminating agents being chloromethylstyrenes, acryloyl chloride, methacryloyl chloride, epichlorohydrin, acrylic anhydride, methacrylic anhydride or maleic anhydride.

摘要翻译： 通过使活性聚合物首先与包含通式I至VII的氮化合物的封端试剂反应，由通过烯属不饱和单体的阴离子聚合获得的活性聚合物制备末端官能化聚合物：（I）＆lt; IMAGE（II） （IV）其中R 1和R 4各自为H，烷基环烷基或芳基，R 2，R 3和R 5各自为烷基，环烷基或芳基，A为取代或未取代的桥 除了C成员之外，还可以含有N或O成员，其中R 6和R 7各自是烷基或芳基，A是单元取代或未取代的碳桥 并且B是2至12元桥，其中至少与氮原子相邻的那些基团包含-C（R 8，R 9）基团，其中R 8和R 9可以相同或不同，并且是H，烷基，环烷基或芳基 ，并且不相邻的成员不仅可以是-C（R 8，R 9）基团，而且可以是乙基或N-烷基或N-芳基 亚胺基，然后使得到的聚合物与含有卤素或酸酐基团的终止剂反应，合适的封端试剂是1,5-二氮杂双环[3,1,0]己烷类化合物和合适的终止 试剂是氯甲基苯乙烯，丙烯酰氯，甲基丙烯酰氯，表氯醇，丙烯酸酐，甲基丙烯酸酐或马来酸酐。

公开(公告)号：US4786736A

公开(公告)日：1988-11-22

申请号：US22236

申请日：1987-03-05

申请人： Klaus Bronstert

发明人： Klaus Bronstert

IPC分类号： C07D229/02 ,  C07D229/00 ,  C07D487/04

CPC分类号： C07D487/04 ,  C07D229/00

摘要： Process for preparing N,N'-dialkyldiaziridines or bicyclic diaziridines of the general formula I or II: ##STR1## where R.sup.1 and R.sup.2 are each alkyl or aryl, A is a substituted or unsubstituted one-membered carbon bridge and B is a substituted or unsubstituted three-membered methylene bridge, by reacting a mixture of two moles of a monoamine or one mole of a 1,3-diamine with one mole of an aldehyde or ketone at 25.degree.-70.degree. C., preferably 40.degree.-50.degree. C., while thoroughly mixing with one mole of an aqueous solution of an alkali metal or alkaline earth metal salt of hypochlorous acid and extracting with an organic solvent, preferably chloroform, from the reaction mixture, as well as bicyclic diaziridines which have 1,3-diazabicyclo-[3.1.0]-hexane as basic structure and are prepared using 2,2-dimethyl-1,3-propylenediamine.

摘要翻译： 制备通式I或II的N，N'-二烷基二氮吡啶或双环二氮丙啶的方法：其中R 1和R 2各自为烷基或芳基，A为取代或未取代的 通过使2摩尔单胺或1摩尔1,3-二胺与1摩尔醛或酮的混合物在25 -70℃下反应，B是取代或未取代的三元亚甲基桥。 ℃，优选40℃-50℃，同时与1摩尔次氯酸的碱金属或碱土金属盐水溶液充分混合，并用有机溶剂，优选氯仿从反应混合物中萃取， 以及具有1,3-二氮杂双环[3.1.0] - 己烷作为碱性结构并使用2,2-二甲基-1,3-丙二胺制备的双环二氮吡啶。

公开(公告)号：US4599433A

公开(公告)日：1986-07-08

申请号：US717109

申请日：1985-03-28

申请人： Klaus Bronstert ,  Hans-Henning Vogel ,  Hans P. Rath

发明人： Klaus Bronstert ,  Hans-Henning Vogel ,  Hans P. Rath

IPC分类号： C07D307/60 ,  B01J31/00 ,  B01J31/02 ,  C07B61/00 ,  C07C51/567 ,  C10M129/26 ,  C10M129/93 ,  C23F11/12 ,  C23F11/173

CPC分类号： C07C51/567 ,  C08F8/46 ,  C10M129/26 ,  C10M129/93 ,  C23F11/126 ,  C08F2810/30 ,  C10M2207/123 ,  C10M2207/129 ,  C10M2207/22

摘要： Olefinically unsaturated hydrocarbons, in particular dimeric or polymeric isobutene derivatives, which have a mean number average molecular weight M.sub.n of from 100 to 3000, are reacted with maleic anhydride in a molar ratio of maleic anhydride to olefin of from 0.2 to 3.0, in the presence of from 1 to 5000 ppm by weight of an alkoxide of titanium, of zirconium, of vanadium or of aluminum, at from 150.degree. to 280.degree. C., with formation of the corresponding succinic anhydride. These products are used for the preparation of anticorrosive agents or oil additives.

摘要翻译： 在具有0.2至3.0的马来酸酐与烯烃的摩尔比的情况下，具有100至3000的平均数均分子量Mn为100至3000的烯属不饱和烃，特别是二聚或聚合异丁烯衍生物与马来酸酐反应， 1至5000重量ppm的钛，锆，钒或铝的醇盐，在150-280℃下，形成相应的琥珀酸酐。 这些产品用于制备防腐剂或油添加剂。

公开(公告)号：US4587307A

公开(公告)日：1986-05-06

申请号：US657383

申请日：1984-10-03

申请人： Klaus Bronstert ,  Waldhelm Hochstein ,  Hans-Henning Vogel ,  Hans P. Rath

发明人： Klaus Bronstert ,  Waldhelm Hochstein ,  Hans-Henning Vogel ,  Hans P. Rath

IPC分类号： C08F6/00 ,  C08F6/06 ,  C08F8/00 ,  C08F10/00 ,  C08F10/10

CPC分类号： C08F10/00

摘要： The processing properties of isobutene polymers when reacted with maleic anhydride are improved by a method in which these polymers are brought into contact, for an effective period,with aluminum oxide and/or a completely or partially hydrated aluminum oxide at 50.degree.-280.degree. C., and/orwith boron oxide and/or a completely or partially hydrated boron oxide and/or with titanium dioxide and/or a partially hydrated titanium dioxide and/or with a completely or partially hydrated silicon dioxide at 0.degree.-280.degree. C.

摘要翻译： 异丁烯聚合物与马来酐反应时的加工性能通过这样一种方法得到改善：使聚合物在50〜-280℃与氧化铝和/或完全或部分水合的氧化铝接触有效的时间 和/或与氧化硼和/或完全或部分水合的氧化硼和/或与二氧化钛和/或部分水合的二氧化钛和/或完全或部分水合的二氧化硅在0-280℃下 。

公开(公告)号：US4152499A

公开(公告)日：1979-05-01

申请号：US863914

申请日：1977-12-23

申请人： Paul Boerzel ,  Klaus Bronstert ,  Friedrich Hovemann

发明人： Paul Boerzel ,  Klaus Bronstert ,  Friedrich Hovemann

IPC分类号： C08F8/32 ,  C08F10/10 ,  C08F4/14 ,  C08F8/46 ,  C08F110/10

CPC分类号： C08F10/10 ,  C08F8/32 ,  C08F8/46 ,  C08F2810/30

摘要： Isobutene polymers having a mean degree of polymerization P of from 10 to 100 and a proportion E of double bonds, capable of reaction with maleic anhydride, of from 60 to 90%, where E=100% corresponds to the calculated theoretical value for the case where each molecule of the isobutene polymer contains such a reactive double bond.

摘要翻译： 平均聚合度P为10〜100，能与马来酸酐反应的双键的比例E为60〜90％的异丁烯聚合物，其中E = 100％对应于该情况的计算理论值 其中异丁烯聚合物的每个分子含有这样的反应性双键。

公开(公告)号：US4090946A

公开(公告)日：1978-05-23

申请号：US701116

申请日：1976-06-30

申请人： Guenther Nottes ,  Klaus Bronstert ,  Peter Klaerner

发明人： Guenther Nottes ,  Klaus Bronstert ,  Peter Klaerner

IPC分类号： C08F8/32 ,  C10L1/22 ,  C10G9/16 ,  C10L10/04

CPC分类号： C08F8/32 ,  C10L1/22 ,  C10L1/2222 ,  C10L1/2364

摘要： The method of stabilizing mineral oil and its refinery products by addition thereto of a small stabilizing amount of alternating copolymers of the type. . . A -- B -- A -- B -- A . . .in which A denotes the structural unit of the general formula--C(R.sup.1)(R.sup.2) - CH.sub.2 --where R.sup.1 denotes hydrogen or alkyl of from 1 to 8 carbon atoms and R.sup.2 has the meanings stated for R.sup.1 or denotes a phenyl group, and in which B stands for structural units of the general formulae ##STR1## where R.sup.3 denotes a saturated hydrocarbon radical of from 8 to 20 carbon atoms and R.sup.4 denotes hydrogen or alkyl of from 8 to 20 carbon atoms.

摘要翻译： 通过添加其稳定矿物油及其炼油产品的方法，该稳定量的这种类型的交替共聚物。 。 。 A - B - A - B - A。 。 。

公开(公告)号：US4089824A

公开(公告)日：1978-05-16

申请号：US733525

申请日：1976-10-18

申请人： Klaus Bronstert ,  Volker Ladenberger ,  Wolfgang Druschke ,  Wolfgang Groh ,  Helmut Mueller

发明人： Klaus Bronstert ,  Volker Ladenberger ,  Wolfgang Druschke ,  Wolfgang Groh ,  Helmut Mueller

IPC分类号： C09J125/00 ,  C09J153/02 ,  C08L9/00 ,  C08L9/06 ,  C08L45/02 ,  C08L93/04

CPC分类号： C09J125/00 ,  C09J153/025

摘要： Hot-melt pressure-sensitive adhesive composition based on a rubbery block copolymer of a monovinyl-aromatic compound or monovinylidene-aromatic compound and butadiene.The composition contains a selectively hydrogenated radial block copolymer with terminal polymer blocks of the monovinyl- or mono-vinylidene-aromatic compound and, in the middle position, butadiene-based polymer blocks which had a 1,2-vinyl content of from 30 to 70 per cent by weight prior to hydrogenation. The compositions may be used, in particular, for the production of self-adhesive materials.

摘要翻译： 基于单乙烯基 - 芳族化合物或单亚乙烯基芳族化合物和丁二烯的橡胶嵌段共聚物的热熔压敏粘合剂组合物。