-
公开(公告)号：US06342552B1
公开(公告)日：2002-01-29
申请号：US09723674
申请日：2000-11-28
IPC分类号： C08K524
CPC分类号： C08K5/5419 , B60C1/0016 , C08K3/36 , C08K5/0008 , C08K5/103 , C08K5/151 , C08K5/1535 , C08K9/12 , Y10T152/10855 , C08L21/00
摘要： The present invention provides silica-filled, vulcanized elastomeric compounds comprising an elastomer mixed with at least a silica filler, a processing aid, and a curing agent, and processes for the preparation of the same. Generally, the present invention provides processing aids which effectively reduce or replace the amount (i.e., about 10 percent by weight based upon the silica filler) of the processing aid bis[3-triethyoxysilyl)propyl]tetrasulfide (“Si69”) used in the production of silica-filled rubber stocks. These new processing aids include alkyl alkoxysilanes, fatty acid esters of hydrogenated and non-hydrogenated sugars and the polyoxyethylene derivatives thereof, and combinations thereof, with or without various non-reinforcing fillers such as mineral fillers. The processing aids do not hinder the physical properties of the compounds and have been found to be excellent substitutes for Si69. The processing aids may be supported on the silica filler or any of the other fillers employed in the composition for improved handling, safety and performance. Processes for the preparation of the silica filled vulcanizable elastomers are provided as well as pneumatic tires employing tread stock comprising the novel vulcanizable elastomers.
摘要翻译： 本发明提供二氧化硅填充的硫化弹性体化合物，其包含与至少二氧化硅填料混合的弹性体，加工助剂和固化剂，及其制备方法。 通常，本发明提供加工助剂，其有效地减少或替代加工助剂双[3-三乙氧基甲硅烷基]丙基]四硫化物（“Si69”）的量（即，基于二氧化硅填料的约10重量％） 生产二氧化硅填充橡胶原料。 这些新的加工助剂包括烷基烷氧基硅烷，氢化和非氢化的糖的脂肪酸酯及其聚氧乙烯衍生物，以及它们的组合，与或不同的各种非增强填料如矿物填料。 加工助剂不妨碍化合物的物理性能，并且已被发现是Si69的优良替代物。 加工助剂可以负载在二氧化硅填料或用于组合物中的任何其它填料以提高处理，安全性和性能。 提供用于制备二氧化硅填充的可硫化弹性体的方法以及使用包含新型可硫化弹性体的胎面胶料的充气轮胎。
-
公开(公告)号：US06384117B1
公开(公告)日：2002-05-07
申请号：US09203438
申请日：1998-12-01
IPC分类号： C08C524
CPC分类号： C08K5/5419 , B60C1/0016 , C08K3/36 , C08K5/0008 , C08K5/103 , C08K5/151 , C08K5/1535 , C08K9/12 , Y10T152/10855 , C08L21/00
摘要： The present invention provides silica-filled, vulcanized elastomeric compounds comprising an elastomer mixed with at least a silica filler, a processing aid, and a curing agent, and processes for the preparation of the same. Generally, the present invention provides processing aids which effectively reduce or replace the amount (i.e., about 10 percent by weight based upon the silica filler) of the processing aid bis[3-triethyoxysilyl)propyl]tetrasulfide (“Si69”) used in the production of silica-filled rubber stocks. These new processing aids include alkyl alkoxysilanes, fatty acid esters of hydrogenated and non-hydrogenated sugars and the polyoxyethylene derivatives thereof, and combinations thereof, with or without various non-reinforcing fillers such as mineral fillers. The processing aids do not hinder the physical properties of the compounds and have been found to be excellent substitutes for Si69. The processing aids may be supported on the silica filler or any of the other fillers employed in the composition for improved handling, safety and performance. Processes for the preparation of the silica filled vulcanizable elastomers are provided as well as pneumatic tires employing tread stock comprising the novel vulcanizable elastomers.
-
公开(公告)号：US06221943B1
公开(公告)日：2001-04-24
申请号：US08893864
申请日：1997-07-11
IPC分类号： C08L524
CPC分类号： C08K5/1535 , B60C1/0016 , C08K3/36 , C08K5/103 , C08K5/5419 , Y10T152/10855 , C08L21/00
摘要： A processable rubber stock is produced by the preparation of a silica-filled, vulcanized elastomeric compound comprising mixing an elastomer with an amorphous silica filler, from 0 to less than about 1% by weight based on said silica filler of bis[3-(triethoxysily)propyl]tetrasulfide, an alkylalkoxysilane and a cure agent. A further processing aid comprising at least one of an ester of a fatty acid or an ester of a polyol is preferred. The elastomer is preferably a diene monomer homopolymer or a copolymer of at least one diene and at least one monovinyl aromatic monomer. By effecting vulcanization, a vulcanized elastomeric compound is produced containing good physical properties for use as tread stock for a pneumatic tire.
摘要翻译： 通过制备二氧化硅填充的硫化弹性体化合物制备可加工的橡胶原料，其包括将弹性体与无定形二氧化硅填料混合，基于所述双[3-（三乙氧基硅烷基） ）丙基]四硫化物，烷基烷氧基硅烷和固化剂。 优选包含脂肪酸的酯或多元醇的酯中的至少一种的另外的加工助剂。 弹性体优选为二烯单体均聚物或至少一种二烯与至少一种单乙烯基芳族单体的共聚物。 通过进行硫化，产生含有用于充气轮胎的胎面胶料的良好物理性能的硫化弹性体化合物。
-
公开(公告)号：US06348531B1
公开(公告)日：2002-02-19
申请号：US09724130
申请日：2000-11-28
IPC分类号： C08K510
CPC分类号： C08K5/1535 , B60C1/0016 , C08K3/36 , C08K5/103 , C08K5/5419 , Y10T152/10855 , C08L21/00
摘要： A processable rubber stock is produced by the preparation of a silica-filled, vulcanized elastomeric compound comprising mixing an elastomer with an amorphous silica filler, from 0 to less than about 1% by weight based on said silica filter of bis[3-triethoxysilyl)propyl]tetrasulfide, an alkylalkoxysilane and a cure agent. A further processing aid comprising at least one of an ester of a fatty acid or an ester of a polyol is preferred. The elastomer is preferably a diene monomer homopolymer or a copolymer of at least one diene and at least one monovinyl aromatic monomer. By effecting vulcanization, a vulcanized elastomeric compound is produced containing good physical properties for use as tread stock for a pneumatic tire.
摘要翻译： 通过制备二氧化硅填充的硫化弹性体化合物制备可加工的橡胶原料，其包括将弹性体与无定形二氧化硅填料混合，基于所述双[3-三乙氧基甲硅烷基）二氧化硅过滤器为0至小于约1重量％ 丙基]四硫化物，烷基烷氧基硅烷和固化剂。 优选包含脂肪酸的酯或多元醇的酯中的至少一种的另外的加工助剂。 弹性体优选为二烯单体均聚物或至少一种二烯与至少一种单乙烯基芳族单体的共聚物。 通过进行硫化，产生含有用于充气轮胎的胎面胶料的良好物理性能的硫化弹性体化合物。
-
15.发明授权Silica-reinforced rubber compounded with an organosilane tetrasulfide silica coupling agent at high mixing temperature 有权二氧化硅增强橡胶与有机硅烷四硫化硅偶联剂在高混合温度下配混公开(公告)号：US06608145B1
公开(公告)日：2003-08-19
申请号：US09687437
申请日：2000-10-13
IPC分类号： C08F834
摘要： Sulfur-vulcanizable elastomeric compounds and pneumatic tire components having improved tensile mechanical and dynamic viscoelastic properties are produced by compounding polymers with silica at a temperature of 165° C. to about 200° C., in the presence of a silica dispersing agent, and a very small amount (e.g., about 0.01% to about 1% by weight, based on the weight of the silica) of a bis(trialkoxysilylorgano) tetrasulfide silica coupling agent.
摘要翻译： 具有改进的拉伸机械和动态粘弹性的硫磺可硫化弹性体组合物和充气轮胎组分通过在二氧化硅分散剂存在下在165℃至约200℃的温度下与二氧化硅混合来制备， 非常少的量（例如，基于二氧化硅的重量计约0.01％至约1重量％）双（三烷氧基甲硅烷基有机基）四硫化硅偶联剂。
-
公开(公告)号：US06384118B1
公开(公告)日：2002-05-07
申请号：US09961710
申请日：2001-09-24
IPC分类号： C08L524
CPC分类号： C08K5/1535 , B60C1/0016 , C08K3/36 , C08K5/103 , C08K5/5419 , Y10T152/10855 , C08L21/00
摘要： A processable rubber stock is produced by the preparation of a silica-filled, vulcanized elastomeric compound comprising mixing an elastomer with an amorphous silica filler, from 0 to less than about 1% by weight based on said silica filler of bis[3-(triethoxysilyl)propyl]tetrasulfide, an alkylalloxysilane and a cure agent. A further processing aid comprising at least one of an ester of a fatty acid or an ester of a polyol is preferred. The elastomer is preferably a diene monomer homopolymer or a copolymer of at least one diene and at least one monovinyl aromatic monomer. By effecting vulcanization, a vulcanized elastomeric compound is produced containing good physical properties for use as tread stock for a pneumatic tire.
摘要翻译： 通过制备二氧化硅填充的硫化弹性体化合物制备可加工的橡胶原料，其包括将弹性体与无定形二氧化硅填料混合，其中所述二（3-（三乙氧基甲硅烷基） ）丙基]四硫化物，烷基氧基硅烷和固化剂。 优选包含脂肪酸的酯或多元醇的酯中的至少一种的另外的加工助剂。 弹性体优选为二烯单体均聚物或至少一种二烯与至少一种单乙烯基芳族单体的共聚物。 通过进行硫化，产生含有用于充气轮胎的胎面胶料的良好物理性能的硫化弹性体化合物。
-
17.发明授权
公开(公告)号：US4137330A
公开(公告)日：1979-01-30
申请号：US876385
申请日：1978-02-09
IPC分类号： C01B21/097 , C01B21/098 , C01B25/10
CPC分类号： C01B21/0986 , C01B21/097
摘要： A process for producing benzene-soluble substantially linear dichlorophosphazene polymer having the formula (NPCl.sub.2).sub.x, in which x is greater than 20 and may be as high as 50,000 or higher, from a cyclic oligomer having the formula (NPCl.sub.2).sub.n, in which n is from 3 to 9, particularly the trimer (NPCl.sub.2).sub.3 or tetramer (NPCl.sub.2).sub.4, in the presence of a small but significant amount of an inorganic salt, preferably a halide of a metal such as Cr, Ni, Co, Cu, Fe, Mn or Mg which affords control of the molecular weight and avoids the formation of large amounts of gel.
摘要翻译： 从具有式（NPCl2）n的环状低聚物生产具有式（NPCl2）x的苯可溶性基本线性二氯膦腈聚合物的方法，其中x大于20并可高达50,000或更高，其中 n为3至9，特别是三聚物（NPCl2）3或四聚体（NPCl2）4，在少量但显着量的无机盐存在下，优选金属如Cr，Ni，Co，Cu的卤化物 ，Fe，Mn或Mg，可以控制分子量，避免形成大量的凝胶。
-
18.发明授权Process to scavenge amines in polymeric compounds by treatment with triazine derivatives and compositions therefrom 失效通过用三嗪衍生物及其组合物处理来清除高分子化合物中的胺的方法公开(公告)号：US06235819B1
公开(公告)日：2001-05-22
申请号：US09002056
申请日：1997-12-31
IPC分类号： C08K534
CPC分类号： C08K5/3492
摘要： A method for scavenging amines within polymeric compositions of matter comprising the step of adding to a polymeric composition of matter at least one triazine compound, wherein said triazine compound is defined according to the formula: where X is selected from the group consisting of hydrogen, halides, amines, and organic groups having from 1 to about 20 carbon atoms, Y is selected from the group consisting of halides, alkoxy derivatives, amine derivatives, aryloxy derivatives, and urea derivatives, with the proviso that the substituent Y is displacable by a reaction with a secondary amine, and Z is selected from the group consisting of alkoxy derivatives, amino derivatives, aryloxy derivatives, and urea derivatives, with the proviso that the substituent Z is displacable by a reaction with a secondary amine.
摘要翻译： 一种用于清除物质的聚合物组合物中的胺的方法，其包括向物质的聚合物组合物中加入至少一种三嗪化合物的步骤，其中所述三嗪化合物根据下式定义：其中X选自氢，卤化物 ，具有1至约20个碳原子的胺和有机基团，Y选自卤化物，烷氧基衍生物，胺衍生物，芳氧基衍生物和脲衍生物，条件是取代基Y可通过反应置换 与仲胺，Z选自烷氧基衍生物，氨基衍生物，芳氧基衍生物和脲衍生物，条件是取代基Z可通过与仲胺的反应置换。
-
19.发明授权Process to scavenge amines in polymeric compounds by treatment with triazine derivatives, and compositions therefrom 失效通过用三嗪衍生物处理在高分子化合物中清除胺及其组合物的方法
公开(公告)号：US6063873A
公开(公告)日：2000-05-16
申请号：US2054
申请日：1997-12-31
IPC分类号： B60C1/00 , C07D251/34 , C07D251/50 , C08K5/29 , C08K5/3492 , C08L21/00 , C08C19/22
CPC分类号： C08K5/34922 , Y10T152/10495
摘要： A rubber tread stock comprising a vulcanizable composition of matter, and a triazine, wherein said triazine is defined by the formula ##STR1## where X is selected from the group consisting of hydrogen, halides, amines, and organic groups having from 1 to about 20 carbon atoms, Y is selected from the group consisting of halides, alkoxy derivatives, amine derivatives, aryloxy derivatives, and urea derivatives, with the proviso that the substituent Y is displacable by a reaction with a secondary amine, and Z is selected from the group consisting of alkoxy derivatives, amino derivatives, aryloxy derivatives, and urea derivatives, with the proviso that the substituent Z is displacable by a reaction with a secondary amine.
摘要翻译： 一种橡胶胎面料，其包含可硫化的物质组合物和三嗪，其中所述三嗪由下式定义：其中X选自氢，卤化物，胺和具有1至约20个碳原子的有机基团， Y选自卤化物，烷氧基衍生物，胺衍生物，芳氧基衍生物和脲衍生物，条件是取代基Y可以通过与仲胺的反应置换，并且Z选自烷氧基 衍生物，氨基衍生物，芳氧基衍生物和脲衍生物，条件是取代基Z可通过与仲胺的反应置换。
-
-
-
-
-
-
-
-
搜索结果
19 条记录 (耗时 0.025 秒)
