摘要:
This invention relates to flame resistant moulding compounds produced from mixtures of styrene polymers halogenated organic compounds, special polyphosphonic acid amides and optionally conventional additives.
摘要:
The application relates to a process for the continuous production of phosgene from chlorine and CO with reduction of the carbon monoxide emission (CO emission).
摘要:
Thermotropic aromatic polyesters with high rigidity and favorable melt viscosity contain condensed radicals of (a) p-hydroxybenzoic acid, (b) hydroquinone and/or 4,4'-dihydroxydiphenyl, (c) isophthalic acid and optionally terephthalic acid and (d) benzophenone dicarboxylic acid in defined weight ratios.
摘要:
An improvement to the phase interface process of preparing aromatic polycarbonate is disclosed. The process is characterized in that the phosgenation is carried out at 0 to 40° C., and in that the temperature of the reaction mixture at the time of addition of the catalyst at 10 to 40° C., and in that the molar ratio of aromatic dihydroxy compounds to phosgene at 1:1.05 to 1:1.20. The polycarbonate thus produced is characterized in its low content of carbamates, making it particularly suitable for the preparation of optical storage media.
摘要:
A process for producing phosgene having low content of carbon tetrachloride is disclosed. The process entails reacting carbon monoxide with chlorine in the presence of elemental carbon, in a reactor. Critically the temperature of the gas stream emerging from the reactor is restricted to 30 to 80° C. and its pressure, measured directly downstream from said reactor is restricted to 120 to 400 kPaabs. The phosgene thus produced has a content of carbon tetrachloride that is less than 150 ppm.
摘要:
A process for the production of polycarbonate is disclosed. The process, representing an improvement over the known interfacial polycondensation process entails introducing into the loop of a circulating reactor that additionally contains, a residence tank, an optional mixer, a pump, and a heat exchanger (i) an organic phase that contains a solvent for polycarbonate and phosgene and (ii) an aqueous phase that contains an aqueous lye solution, a dihydroxy compound and an optional monophenol to form an emulsion. Maintaining specified temperature and process conditions results in polycarbonate resin having good properties and in waste water that are characterized by their purity.
摘要:
A process for the preparation of polycarbonate resins having a low yellowness index is described. The process involves converting phosgene with a sodium bisphenolate solution by means of a phase interface process performed with the exclusion of oxygen. The sodium bisphenolate solution used in the process has a dissolved oxygen content of
摘要:
An improvement in the continuous two-phase interfacial condensation process for preparing polycarbonate is disclosed. In the process that entails at least one diphenol, phosgene, at least one chain terminator, and optionally branching agents and is carried out in the presence of a catalyst the improvement comprising maintaining the concentration of the catalyst at a level of at least 0.012 mol per mol of diphenol.
摘要:
A container made of polycarbonate resin is disclosed. The container is characterized in that the polycarbonate is prepared by the phase interface process that is characterized in that the aqueous solution of an alkali salt of a bisphenol used, contains dissolved oxygen in an amount less than 150 ppb. The process for making the container is also disclosed.